Tuning Electrical‐ and Photo‐Conductivity by Cation Exchange within a Redox‐Active Tetrathiafulvalene‐Based Metal–Organic Framework

• Published in: Angewandte Chemie International Edition Vol. 59; no. 42; pp. 18763 - 18767
• Main Authors: Zhou, Yan, Yu, Fei, Su, Jian, Kurmoo, Mohamedally, Zuo, Jing‐Lin
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 12.10.2020
• Edition: International ed. in English
• Subjects: Cation exchange; Cation exchanging; Cations; Charge transfer; Crystal structure; Crystallinity; Dimethylformamide; Electric bridges; Electrical conductivity; Electrical resistivity; Metal-organic frameworks; methylviologen; Photoelectric effect; Photoelectric emission; Photosensitivity; post-synthetic modification; redox-active species; single-crystal to single-crystal transformation; tetrathiafulvalene; post-synthetic modification; redox-active species; methylviologen; single-crystal to single-crystal transformation; tetrathiafulvalene

To activate electronic and optical functions of the redox‐active metal–organic framework, (Me2NH2)[InIII(TTFTB)]⋅0.7 C2H5OH⋅DMF (Me2NH2@1, TTFTB=tetrathiafulvalene‐tetrabenzoate, DMF=N,N‐dimethylformamide), has been exchanged by tetrathiafulvalenium (TTF.+) and N,N′‐dimethyl‐4,4′‐bipyridinium (MV2+)...