Three-Dimensional Hierarchical Porous Structure of PPy/Porous-Graphene to Encapsulate Polysulfides for Lithium/Sulfur Batteries

Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of pyrrole monomer on PG surface. The PPy/PG displays a 3D hierarchical porous structure and the resulting PPy/PG hybrid serves as a conductive trap...

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Published inNanomaterials (Basel, Switzerland) Vol. 8; no. 8; p. 606
Main Authors Zhang, Yongguang, Bakenov, Zhumabay, Tan, Taizhe, Huang, Jin
Format Journal Article
LanguageEnglish
Published Switzerland MDPI AG 09.08.2018
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Abstract Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of pyrrole monomer on PG surface. The PPy/PG displays a 3D hierarchical porous structure and the resulting PPy/PG hybrid serves as a conductive trap to lithium polysulfides enhancing the electrochemical performances. Owing to the superior conductivity and peculiar structure, a high initial discharge capacity of 1020 mAh g and the reversible capacity of 802 mAh g over 200 cycles are obtained for the S/PPy/PG cathode at 0.1 C, remaining the remarkable cyclic stability. In addition, the S/PPy/PG cathodes demonstrate an excellent rate performance exhibiting 477 mAh g at 2 C.
AbstractList Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of pyrrole monomer on PG surface. The PPy/PG displays a 3D hierarchical porous structure and the resulting PPy/PG hybrid serves as a conductive trap to lithium polysulfides enhancing the electrochemical performances. Owing to the superior conductivity and peculiar structure, a high initial discharge capacity of 1020 mAh g −1 and the reversible capacity of 802 mAh g −1 over 200 cycles are obtained for the S/PPy/PG cathode at 0.1 C, remaining the remarkable cyclic stability. In addition, the S/PPy/PG cathodes demonstrate an excellent rate performance exhibiting 477 mAh g −1 at 2 C.
Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of pyrrole monomer on PG surface. The PPy/PG displays a 3D hierarchical porous structure and the resulting PPy/PG hybrid serves as a conductive trap to lithium polysulfides enhancing the electrochemical performances. Owing to the superior conductivity and peculiar structure, a high initial discharge capacity of 1020 mAh g and the reversible capacity of 802 mAh g over 200 cycles are obtained for the S/PPy/PG cathode at 0.1 C, remaining the remarkable cyclic stability. In addition, the S/PPy/PG cathodes demonstrate an excellent rate performance exhibiting 477 mAh g at 2 C.
Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of pyrrole monomer on PG surface. The PPy/PG displays a 3D hierarchical porous structure and the resulting PPy/PG hybrid serves as a conductive trap to lithium polysulfides enhancing the electrochemical performances. Owing to the superior conductivity and peculiar structure, a high initial discharge capacity of 1020 mAh g−1 and the reversible capacity of 802 mAh g−1 over 200 cycles are obtained for the S/PPy/PG cathode at 0.1 C, remaining the remarkable cyclic stability. In addition, the S/PPy/PG cathodes demonstrate an excellent rate performance exhibiting 477 mAh g−1 at 2 C.
Author Tan, Taizhe
Bakenov, Zhumabay
Huang, Jin
Zhang, Yongguang
AuthorAffiliation 1 School of Materials and Energy, Synergy Innovation Institute of GDUT (Heyuan), Guangdong University of Technology, Guangzhou 510006, China; ygzhang126@126.com
2 Institute of Batteries LLC, National Laboratory Astana, School of Engineering, Nazarbayev University, 53 Kabanbay Batyr Avenue, Astana 010000, Kazakhstan; zbakenov@nu.edu.kz
AuthorAffiliation_xml – name: 1 School of Materials and Energy, Synergy Innovation Institute of GDUT (Heyuan), Guangdong University of Technology, Guangzhou 510006, China; ygzhang126@126.com
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BackLink https://www.ncbi.nlm.nih.gov/pubmed/30096884$$D View this record in MEDLINE/PubMed
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Keywords sulfur/polypyrrole/porous graphene composite
hierarchical 3D porous structure
lithium/sulfur battery
Language English
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Snippet Herein, we demonstrate the fabrication of a three-dimensional (3D) polypyrrole-coated-porous graphene (PPy/PG) composite through in-situ polymerization of...
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StartPage 606
SubjectTerms Batteries
Carbon
Cathodes
Electrochemistry
Electrodes
Energy
Fabrication
Fourier transforms
Graphene
hierarchical 3D porous structure
Lithium
Lithium sulfur batteries
lithium/sulfur battery
Microscopy
Nanocomposites
Polymerization
Polypyrroles
Polysulfides
Spectrum analysis
Structural hierarchy
Sulfur
sulfur/polypyrrole/porous graphene composite
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Title Three-Dimensional Hierarchical Porous Structure of PPy/Porous-Graphene to Encapsulate Polysulfides for Lithium/Sulfur Batteries
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