Solvent extraction of lithium from aqueous solution using non-fluorinated functionalized ionic liquids as extraction agents
The functionalized ionic liquid extractant diluted in methylbenzene is a much better solvent extraction system than the corresponding acidic extractant diluted in methylbenzene. [Display omitted] •Two novel functionalized ionic liquids were successfully synthesized and used for lithium extraction.•M...
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| Published in | Separation and purification technology Vol. 172; pp. 473 - 479 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier B.V
01.01.2017
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| Subjects | |
| Online Access | Get full text |
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| Abstract | The functionalized ionic liquid extractant diluted in methylbenzene is a much better solvent extraction system than the corresponding acidic extractant diluted in methylbenzene. [Display omitted]
•Two novel functionalized ionic liquids were successfully synthesized and used for lithium extraction.•Mechanistic pathway was different as compared to imidazolium ionic liquid diluents.•Nature of extracted species was found out to be 1:1.•Ionic liquid systems were reusable.
Two non-fluorinated ionic liquids (ILs), namely tetrabutylammonium bis(2-ethylhexyl)-phosphate, [N4444][DEHP], and tetraoctylammonium bis(2-ethylhexyl)-phosphate, [N8888][DEHP], were synthesized and fully characterized by 1H and 13C NMR spectroscopy. These functionalized ILs were subsequently evaluated in terms of their ability to extract lithium ions from aqueous solution. The extraction efficiencies of these functionalized ILs for lithium ions were measured as a function of various extraction parameters, including aqueous acidity, temperature and extractant concentration. The extracted species were determined using a slope analysis method, which indicated that the ILs formed a 1:1 (metal:ligand) complex. Fourier transform infrared spectroscopy studies were conducted to better understand the nature of the extracted species. We also investigated the stripping of the lithium ions from the organic phase and the re-use of the ionic liquid in a subsequent extraction step. |
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| AbstractList | Two non-fluorinated ionic liquids (ILs), namely tetrabutylammonium bis(2-ethylhexyl)-phosphate, [N4444][DEHP], and tetraoctylammonium bis(2-ethylhexyl)-phosphate, [N8888][DEHP], were synthesized and fully characterized by 1H and 13C NMR spectroscopy. These functionalized ILs were subsequently evaluated in terms of their ability to extract lithium ions from aqueous solution. The extraction efficiencies of these functionalized ILs for lithium ions were measured as a function of various extraction parameters, including aqueous acidity, temperature and extractant concentration. The extracted species were determined using a slope analysis method, which indicated that the ILs formed a 1:1 (metal:ligand) complex. Fourier transform infrared spectroscopy studies were conducted to better understand the nature of the extracted species. We also investigated the stripping of the lithium ions from the organic phase and the re-use of the ionic liquid in a subsequent extraction step. The functionalized ionic liquid extractant diluted in methylbenzene is a much better solvent extraction system than the corresponding acidic extractant diluted in methylbenzene. [Display omitted] •Two novel functionalized ionic liquids were successfully synthesized and used for lithium extraction.•Mechanistic pathway was different as compared to imidazolium ionic liquid diluents.•Nature of extracted species was found out to be 1:1.•Ionic liquid systems were reusable. Two non-fluorinated ionic liquids (ILs), namely tetrabutylammonium bis(2-ethylhexyl)-phosphate, [N4444][DEHP], and tetraoctylammonium bis(2-ethylhexyl)-phosphate, [N8888][DEHP], were synthesized and fully characterized by 1H and 13C NMR spectroscopy. These functionalized ILs were subsequently evaluated in terms of their ability to extract lithium ions from aqueous solution. The extraction efficiencies of these functionalized ILs for lithium ions were measured as a function of various extraction parameters, including aqueous acidity, temperature and extractant concentration. The extracted species were determined using a slope analysis method, which indicated that the ILs formed a 1:1 (metal:ligand) complex. Fourier transform infrared spectroscopy studies were conducted to better understand the nature of the extracted species. We also investigated the stripping of the lithium ions from the organic phase and the re-use of the ionic liquid in a subsequent extraction step. |
| Author | Jia, Yongzhong Jing, Yan Wang, Xingquan Shi, Chenglong Xiao, Jiang Yao, Ying |
| Author_xml | – sequence: 1 givenname: Chenglong surname: Shi fullname: Shi, Chenglong organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China – sequence: 2 givenname: Yan surname: Jing fullname: Jing, Yan organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China – sequence: 3 givenname: Jiang surname: Xiao fullname: Xiao, Jiang organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China – sequence: 4 givenname: Xingquan surname: Wang fullname: Wang, Xingquan organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China – sequence: 5 givenname: Ying surname: Yao fullname: Yao, Ying organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China – sequence: 6 givenname: Yongzhong surname: Jia fullname: Jia, Yongzhong email: qhislcas@126.com organization: Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, 810008 Xining, China |
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| Snippet | The functionalized ionic liquid extractant diluted in methylbenzene is a much better solvent extraction system than the corresponding acidic extractant diluted... Two non-fluorinated ionic liquids (ILs), namely tetrabutylammonium bis(2-ethylhexyl)-phosphate, [N4444][DEHP], and tetraoctylammonium... |
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| SubjectTerms | Aqueous solutions Fourier transforms Infrared spectroscopy Ionic liquids Lithium Lithium ions NMR spectroscopy Solvent extraction Stripping |
| Title | Solvent extraction of lithium from aqueous solution using non-fluorinated functionalized ionic liquids as extraction agents |
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