Temperature effect on mechanical properties of toughened silicone resins

The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable...

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Published inPolymer engineering and science Vol. 45; no. 11; pp. 1522 - 1531
Main Authors Wu, Yuhong, McGarry, Frederick J., Zhu, Bizhong, Keryk, John R., Katsoulis, Dimitris E.
Format Journal Article
LanguageEnglish
Published Hoboken Wiley Subscription Services, Inc., A Wiley Company 01.11.2005
Wiley Subscription Services
Society of Plastics Engineers, Inc
Blackwell Publishing Ltd
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ISSN0032-3888
1548-2634
DOI10.1002/pen.20423

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Abstract The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross‐linked with a variety of cross‐linkers, including 1,4‐bis(dimethylsilyl) benzene, 1,1,3,3,5,5,‐hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross‐linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness KIc. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross‐linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness KIc showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522–1531, 2005. © 2005 Society of Plastics Engineers
AbstractList The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross-linked with a variety of cross-linkers, including 1,4-bis(dimethylsilyl) benzene, 1,1,3,3,5,5,-hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross-linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness [K.sub.Ic]. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross-linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness [K.sub.Ic] showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522-1531, 2005. © 2005 Society of Plastics Engineers
The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross-linked with a variety of cross-linkers, including 1,4-bis(dimethylsilyl) benzene, 1,1,3,3,5,5,-hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross-linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness K^sub Ic^. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross-linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness K^sub Ic^ showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. [PUBLICATION ABSTRACT]
The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross‐linked with a variety of cross‐linkers, including 1,4‐bis(dimethylsilyl) benzene, 1,1,3,3,5,5,‐hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross‐linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness KIc. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross‐linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness KIc showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522–1531, 2005. © 2005 Society of Plastics Engineers
Audience Academic
Author McGarry, Frederick J.
Wu, Yuhong
Zhu, Bizhong
Keryk, John R.
Katsoulis, Dimitris E.
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CitedBy_id crossref_primary_10_1016_j_jrmge_2022_02_013
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10.1016/S0032-3861(97)00121-3
10.1016/0032-3861(83)90070-8
10.1016/S0032-3861(00)00027-6
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Issue 11
Keywords Strengthening
Condensation reaction
Temperature effect
Mechanical properties
Crosslinking
Hydrosilylation
Experimental study
Mechanism
Fracture toughness
Bending strength
Dynamic mechanical properties
Crosslinked polymer
Siloxane polymer
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– reference: B. Zhu, D.E. Katsoulis, G.A. Zank, and F.J. McGarry, Mater. Res. Soc. Symp. Proc., 594, 257 (2000).
– reference: E. Pink and J.D. Campbell, Mater. Sci. Eng., 15, 187 (1974).
– reference: J.G. Williams, Fracture Mechanics of Polymers, Ellis Horwood Ltd., Chichester (1984).
– reference: A.J. Kinloch, and R.J. Young, Fracture Behavior of Polymers, Applied Science Publishers Ltd., London (1983).
– reference: B.J. Cardwell, and A.F. Yee, Polymer, 34, 1695 (1993).
– reference: B. Zhu, D.E. Katsoulis, J.R. Keryk, and F.J. McGarry, Polymer, 41, 7559 (2000).
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Snippet The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of...
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SubjectTerms Applied sciences
Exact sciences and technology
Inorganic and organomineral polymers
Mechanical properties
Physicochemistry of polymers
Polymers
Properties and characterization
Resins
Silicon polymers
Silicones
Temperature effects
Thermal properties
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Title Temperature effect on mechanical properties of toughened silicone resins
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