Temperature effect on mechanical properties of toughened silicone resins
The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable...
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Published in | Polymer engineering and science Vol. 45; no. 11; pp. 1522 - 1531 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Hoboken
Wiley Subscription Services, Inc., A Wiley Company
01.11.2005
Wiley Subscription Services Society of Plastics Engineers, Inc Blackwell Publishing Ltd |
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Online Access | Get full text |
ISSN | 0032-3888 1548-2634 |
DOI | 10.1002/pen.20423 |
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Abstract | The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross‐linked with a variety of cross‐linkers, including 1,4‐bis(dimethylsilyl) benzene, 1,1,3,3,5,5,‐hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross‐linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness KIc. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross‐linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness KIc showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522–1531, 2005. © 2005 Society of Plastics Engineers |
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AbstractList | The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross-linked with a variety of cross-linkers, including 1,4-bis(dimethylsilyl) benzene, 1,1,3,3,5,5,-hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross-linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness [K.sub.Ic]. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross-linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness [K.sub.Ic] showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522-1531, 2005. © 2005 Society of Plastics Engineers The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross-linked with a variety of cross-linkers, including 1,4-bis(dimethylsilyl) benzene, 1,1,3,3,5,5,-hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross-linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness K^sub Ic^. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross-linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness K^sub Ic^ showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. [PUBLICATION ABSTRACT] The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of hydrosilylation reaction curable silicone resins, and the second representative of condensation reaction curable ones. The hydrosilylation curable resin was cross‐linked with a variety of cross‐linkers, including 1,4‐bis(dimethylsilyl) benzene, 1,1,3,3,5,5,‐hexamethyltrisiloxane, diphenylsilane, and their mixtures. The condensation reaction curable resin and its toughened versions were cross‐linked by silanol condensation. Properties studied included flexural strength, flexural modulus, and fracture toughness KIc. Temperature effect on these properties of the first family of resins was substantial and varied strongly with the type of cross‐linkers. For this family of resins the flexural strength and modulus decreased with a rising temperature. Fracture toughness KIc showed a peaking behavior with the peak appearing at approximately 62°C below the α transition peak. This was explained by the effect of the plastic zone size, and the effect of the network resistance to plastic deformation. The second family of resins also showed decreases in modulus and strength with a higher testing temperature, but the fracture toughness changed little with temperature. POLYM. ENG. SCI., 45:1522–1531, 2005. © 2005 Society of Plastics Engineers |
Audience | Academic |
Author | McGarry, Frederick J. Wu, Yuhong Zhu, Bizhong Keryk, John R. Katsoulis, Dimitris E. |
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Cites_doi | 10.4028/www.scientific.net/MSF.423-425.509 10.1557/PROC-594-257 10.1016/0032-3861(93)90329-9 10.1016/0032-3861(83)90071-X 10.1016/0025-5416(74)90051-2 10.1021/ma0353843 10.1016/S0032-3861(97)00121-3 10.1016/0032-3861(83)90070-8 10.1016/S0032-3861(00)00027-6 |
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Keywords | Strengthening Condensation reaction Temperature effect Mechanical properties Crosslinking Hydrosilylation Experimental study Mechanism Fracture toughness Bending strength Dynamic mechanical properties Crosslinked polymer Siloxane polymer |
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Snippet | The temperature dependence of mechanical properties of two families of toughened silicone resins was investigated. The first family was representative of... |
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SubjectTerms | Applied sciences Exact sciences and technology Inorganic and organomineral polymers Mechanical properties Physicochemistry of polymers Polymers Properties and characterization Resins Silicon polymers Silicones Temperature effects Thermal properties |
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Title | Temperature effect on mechanical properties of toughened silicone resins |
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