Electric Field-Modulated Surface Enhanced Raman Spectroscopy by PVDF/Ag Hybrid
Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potentia...
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Published in | Scientific reports Vol. 10; no. 1; p. 5269 |
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Main Authors | , , , , , , , , , |
Format | Journal Article |
Language | English |
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24.03.2020
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Abstract | Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potential, and most of them are non-flexible structure, which limits the application of E-SERS in the portable,
in-situ
and fast detection area. Here, we developed an electric field-modulated SERS substrate based on the piezoelectric effect by combining the PVDF (piezoelectric-modulated layer) and Ag nanowires (AgNWs) (SERS active layer) and investigated the SERS activity in experiment and theory. The enhanced electric field and the tunable plasmon resonance induced by the piezoelectric effect provide the additional enhancement for the SERS signal. Furthermore, we fabricated a SERS active ring with a piezoelectric field-modulated substrate and achieved the
in-situ
detection of glucose with a non-invasive method. This work provided innovation for the E-SERS and could greatly promote the development of the
in-situ
, wearable and intelligent sensors. |
---|---|
AbstractList | Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potential, and most of them are non-flexible structure, which limits the application of E-SERS in the portable, in-situ and fast detection area. Here, we developed an electric field-modulated SERS substrate based on the piezoelectric effect by combining the PVDF (piezoelectric-modulated layer) and Ag nanowires (AgNWs) (SERS active layer) and investigated the SERS activity in experiment and theory. The enhanced electric field and the tunable plasmon resonance induced by the piezoelectric effect provide the additional enhancement for the SERS signal. Furthermore, we fabricated a SERS active ring with a piezoelectric field-modulated substrate and achieved the in-situ detection of glucose with a non-invasive method. This work provided innovation for the E-SERS and could greatly promote the development of the in-situ, wearable and intelligent sensors. Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potential, and most of them are non-flexible structure, which limits the application of E-SERS in the portable, in-situ and fast detection area. Here, we developed an electric field-modulated SERS substrate based on the piezoelectric effect by combining the PVDF (piezoelectric-modulated layer) and Ag nanowires (AgNWs) (SERS active layer) and investigated the SERS activity in experiment and theory. The enhanced electric field and the tunable plasmon resonance induced by the piezoelectric effect provide the additional enhancement for the SERS signal. Furthermore, we fabricated a SERS active ring with a piezoelectric field-modulated substrate and achieved the in-situ detection of glucose with a non-invasive method. This work provided innovation for the E-SERS and could greatly promote the development of the in-situ , wearable and intelligent sensors. Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potential, and most of them are non-flexible structure, which limits the application of E-SERS in the portable, in-situ and fast detection area. Here, we developed an electric field-modulated SERS substrate based on the piezoelectric effect by combining the PVDF (piezoelectric-modulated layer) and Ag nanowires (AgNWs) (SERS active layer) and investigated the SERS activity in experiment and theory. The enhanced electric field and the tunable plasmon resonance induced by the piezoelectric effect provide the additional enhancement for the SERS signal. Furthermore, we fabricated a SERS active ring with a piezoelectric field-modulated substrate and achieved the in-situ detection of glucose with a non-invasive method. This work provided innovation for the E-SERS and could greatly promote the development of the in-situ, wearable and intelligent sensors.Electrically modulated surface enhanced Raman scattering (E-SERS) can be able to regulate the plasmon resonance peak of metal nanostructures, further improve the detection sensitivity of the SERS substrate. However, the E-SERS substrates require auxiliary equipment to provide the electrical potential, and most of them are non-flexible structure, which limits the application of E-SERS in the portable, in-situ and fast detection area. Here, we developed an electric field-modulated SERS substrate based on the piezoelectric effect by combining the PVDF (piezoelectric-modulated layer) and Ag nanowires (AgNWs) (SERS active layer) and investigated the SERS activity in experiment and theory. The enhanced electric field and the tunable plasmon resonance induced by the piezoelectric effect provide the additional enhancement for the SERS signal. Furthermore, we fabricated a SERS active ring with a piezoelectric field-modulated substrate and achieved the in-situ detection of glucose with a non-invasive method. This work provided innovation for the E-SERS and could greatly promote the development of the in-situ, wearable and intelligent sensors. |
ArticleNumber | 5269 |
Author | Ning, Tingyin Huo, Yanyan Lei, Fengcai Lu, Jiajun Xu, Shicai Yu, Jing Zhang, Chao Du, Xuejian Li, Chonghui Song, Yuzhi |
Author_xml | – sequence: 1 givenname: Jiajun surname: Lu fullname: Lu, Jiajun organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 2 givenname: Yuzhi surname: Song fullname: Song, Yuzhi email: yzsong@sdnu.edu.cn organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 3 givenname: Fengcai surname: Lei fullname: Lei, Fengcai organization: College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University – sequence: 4 givenname: Xuejian surname: Du fullname: Du, Xuejian organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 5 givenname: Yanyan surname: Huo fullname: Huo, Yanyan organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 6 givenname: Shicai surname: Xu fullname: Xu, Shicai organization: Shandong Key Laboratory of Biophysics, College of Physics and Electronic Information, Institute of Biophysics, Dezhou University – sequence: 7 givenname: Chonghui surname: Li fullname: Li, Chonghui organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 8 givenname: Tingyin surname: Ning fullname: Ning, Tingyin organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 9 givenname: Jing surname: Yu fullname: Yu, Jing email: yujing1608@sdnu.edu.cn organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University – sequence: 10 givenname: Chao surname: Zhang fullname: Zhang, Chao email: czsdnu@126.com organization: Collaborative Innovation Center of Light Manipulations and Applications & Institute of Materials and Clean Energy, School of Physics and Electronics, Shandong Normal University |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32210311$$D View this record in MEDLINE/PubMed |
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Title | Electric Field-Modulated Surface Enhanced Raman Spectroscopy by PVDF/Ag Hybrid |
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