Post-tilleyite, a dense calcium silicate-carbonate phase

Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behav...

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Published inScientific reports Vol. 9; no. 1; p. 7898
Main Authors Santamaria-Perez, David, Ruiz-Fuertes, Javier, Peña-Alvarez, Miriam, Chulia-Jordan, Raquel, Marqueño, Tomas, Zimmer, Dominik, Gutiérrez-Cano, Vanessa, MacLeod, Simon, Gregoryanz, Eugene, Popescu, Catalin, Rodríguez-Hernández, Plácida, Muñoz, Alfonso
Format Journal Article
LanguageEnglish
Published London Nature Publishing Group UK 27.05.2019
Nature Publishing Group
Subjects
119/118
140/133
639/301/119
704/2151/330
Aluminum oxide
Calcium carbonate
Carbon
Cations
Compression
High temperature
Humanities and Social Sciences
Minerals
multidisciplinary
Powder
Raman spectroscopy
Science
Science (multidisciplinary)
Silica
Silicates
Spectrum analysis
Structural behavior
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Abstract Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca 5 (Si 2 O 7 )(CO 3 ) 2 tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.
AbstractList Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca 5 (Si 2 O 7 )(CO 3 ) 2 tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.
Calcium carbonate is a relevant constituent of the Earth's crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca5(Si2O7)(CO3)2 tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6-9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.Calcium carbonate is a relevant constituent of the Earth's crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca5(Si2O7)(CO3)2 tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6-9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.
Calcium carbonate is a relevant constituent of the Earth's crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca (Si O )(CO ) tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6-9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.
Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical interaction with calcium-rich silicates at high temperatures give rise to the formation of mixed silicate-carbonate minerals, but the structural behavior of these phases under compression is not known. Here we report the existence of a dense polymorph of Ca5(Si2O7)(CO3)2 tilleyite above 8 GPa. We have structurally characterized the two phases at high pressures and temperatures, determined their equations of state and analyzed the evolution of the polyhedral units under compression. This has been possible thanks to the agreement between our powder and single-crystal XRD experiments, Raman spectroscopy measurements and ab-initio simulations. The presence of multiple cation sites, with variable volume and coordination number (6–9) and different polyhedral compressibilities, together with the observation of significant amounts of alumina in compositions of some natural tilleyite assemblages, suggests that post-tilleyite structure has the potential to accommodate cations with different sizes and valencies.
ArticleNumber 7898
Author Popescu, Catalin
Peña-Alvarez, Miriam
Marqueño, Tomas
Rodríguez-Hernández, Plácida
Muñoz, Alfonso
Gutiérrez-Cano, Vanessa
Santamaria-Perez, David
Chulia-Jordan, Raquel
Gregoryanz, Eugene
Zimmer, Dominik
MacLeod, Simon
Ruiz-Fuertes, Javier
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Cites_doi 10.1021/acs.inorgchem.8b00523
10.1103/PhysRevB.81.214101
10.1107/S0021889812029111
10.1103/PhysRevB.59.1758
10.1038/nature16174
10.1180/minmag.2011.075.5.2631
10.1103/PhysRevB.39.11820
10.1016/j.epsl.2008.12.022
10.1038/nature11679
10.1180/minmag.1985.049.350.09
10.1103/PhysRev.136.B864
10.1103/PhysRevB.49.14251
10.1016/j.gsf.2015.02.001
10.2113/gsecongeo.3.8.688
10.1103/PhysRevB.47.558
10.2465/minerj.9.106
10.2138/am-2016-5425
10.2138/am-2015-5246
10.2475/ajs.257.9.656
10.1088/0022-3727/42/7/075413
10.1080/08893110412331323170
10.2138/rmg.2013.75.7
10.1180/minmag.1976.040.314.16
10.1146/annurev.earth.36.031207.124322
10.1016/j.saa.2015.04.015
10.1103/PhysRevB.50.17953
10.1107/S2053229614024218
10.1103/PhysRevB.13.5188
10.1103/RevModPhys.75.863
10.1021/acs.inorgchem.7b02101
10.1016/j.epsl.2012.04.036
10.1029/JB091iB05p04673
10.1103/PhysRev.71.809
10.1016/j.epsl.2010.06.039
10.1103/PhysRevLett.100.136406
10.1524/zkri.1970.132.1-6.288
10.1080/08957950701659700
10.2113/gscanmin.43.5.1489
10.1016/0927-0256(96)00008-0
10.1179/cmq.1981.20.1.51
10.1016/j.epsl.2005.04.033
10.1021/acs.chemmater.7b01158
10.1080/08957959.2015.1059835
10.1107/S0365110X53000028
10.1016/0012-821X(95)00130-5
10.1107/S2053273314026370
10.2138/am-2016-5389CCBY
10.1038/nature16164
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References Kresse, Joubert (CR60) 1999; 59
Dorogokupets, Dewaele (CR41) 2007; 27
Monkhorst, Pack (CR61) 1976; 13
Blöchl (CR59) 1994; 50
Blatov (CR23) 2004; 10
Poli, Franzolin, Fumagalli, Crottini (CR3) 2009; 278
Santamaria-Perez (CR18) 2018; 57
Klotz, Chervin, Munsch, Le Marchand (CR43) 2009; 42
Larsen, Dunham (CR11) 1933; 18
Rubenach, Cuff (CR13) 1985; 49
Holland, Redfern (CR49) 1997; 61
Connolly (CR4) 2005; 236
Santamaria-Perez (CR29) 2016; 101
Prescher, Prakapenka (CR47) 2015; 35
Harker (CR12) 1959; 257
Henmi, Henmi (CR17) 1978; 9
Sheldrick (CR25) 2015; 71
Cazorla (CR40) 2016; 28
Mao, Xu, Bell (CR44) 1986; 91
Grice (CR22) 2005; 43
Birch (CR33) 1947; 71
CR48
Hohenberg, Kohn (CR57) 1964; 136
Kubicky, Hemley, Hofmeister (CR31) 1992; 77
Tracy, Frost (CR14) 2019; 26
Marqueño (CR36) 2018; 57
Serghiou, Hammack (CR32) 1993; 88
Fauth, Peral, Popescu, Knapp (CR46) 2013; 28
Frost, Lopez, Scholz, de Oliveira (CR28) 2015; 149
Gao, Wu, Qin (CR34) 2015; 6
Kresse, Furthmuller (CR54) 1996; 6
Santamaria-Perez, Mukherjee, Schwager, Boehler (CR42) 2010; 85
Kresse, Hafner (CR55) 1994; 49
Thomson, Walter, Kohn, Brooker (CR5) 2016; 529
Nolze, Kraus (CR50) 1998; 13
Smith (CR20) 1953; 6
Liu, Lin (CR16) 1995; 134
Xiong (CR38) 2016; 101
CR19
Dasgupta, Hirchmann (CR2) 2010; 298
Kresse, Hafner (CR56) 1993; 47
Farrugia (CR52) 2012; 45
CR53
CR51
Perdew (CR58) 2008; 100
Sheldrick (CR24) 2015; 71
Louisnathan, Smith (CR21) 1970; 132
Li (CR37) 2015; 100
Mujica, Rubio, Munoz, Needs (CR62) 2013; 75
Spurr, Garrey (CR10) 1908; 3
Weston, Rogers (CR39) 1976; 40
Rohrbach, Schmidt (CR6) 2011; 339
Frost, McCammon (CR8) 2008; 36
Treiman, Essene (CR15) 1983; 283-A
Stagno, Ojwang, McCammon, Frost (CR7) 2013; 493
Santamaria-Perez (CR35) 2017; 29
Merlini, Hanfland, Crichton (CR26) 2012; 333–334
Lazic (CR9) 2011; 75
Iguchi, Kashio, Goto, Nishina, Fuwa (CR30) 1981; 20
Hemley, Zha, Jephcoat, Mao, Finger (CR45) 1989; 39
De Villiers (CR27) 1971; 56
Dasgupta (CR1) 2013; 75
G Kresse (44326_CR55) 1994; 49
L-G Liu (44326_CR16) 1995; 134
HJ Monkhorst (44326_CR61) 1976; 13
JE Spurr (44326_CR10) 1908; 3
S Poli (44326_CR3) 2009; 278
PI Dorogokupets (44326_CR41) 2007; 27
F Fauth (44326_CR46) 2013; 28
I Harker (44326_CR12) 1959; 257
GM Sheldrick (44326_CR25) 2015; 71
PE Blöchl (44326_CR59) 1994; 50
JD Kubicky (44326_CR31) 1992; 77
TJB Holland (44326_CR49) 1997; 61
MJ Rubenach (44326_CR13) 1985; 49
JV Smith (44326_CR20) 1953; 6
JD Grice (44326_CR22) 2005; 43
Y Iguchi (44326_CR30) 1981; 20
G Kresse (44326_CR56) 1993; 47
JPR De Villiers (44326_CR27) 1971; 56
VA Blatov (44326_CR23) 2004; 10
44326_CR48
LJ Farrugia (44326_CR52) 2012; 45
R Dasgupta (44326_CR1) 2013; 75
C Prescher (44326_CR47) 2015; 35
G Nolze (44326_CR50) 1998; 13
B Lazic (44326_CR9) 2011; 75
GC Serghiou (44326_CR32) 1993; 88
D Santamaria-Perez (44326_CR42) 2010; 85
RJ Hemley (44326_CR45) 1989; 39
RJ Tracy (44326_CR14) 2019; 26
Z Xiong (44326_CR38) 2016; 101
D Santamaria-Perez (44326_CR29) 2016; 101
KK Mao (44326_CR44) 1986; 91
T Marqueño (44326_CR36) 2018; 57
G Kresse (44326_CR60) 1999; 59
A Rohrbach (44326_CR6) 2011; 339
D Santamaria-Perez (44326_CR35) 2017; 29
G Kresse (44326_CR54) 1996; 6
DJ Frost (44326_CR8) 2008; 36
ES Larsen (44326_CR11) 1933; 18
M Merlini (44326_CR26) 2012; 333–334
J Gao (44326_CR34) 2015; 6
RM Weston (44326_CR39) 1976; 40
RL Frost (44326_CR28) 2015; 149
R Dasgupta (44326_CR2) 2010; 298
SJ Louisnathan (44326_CR21) 1970; 132
V Stagno (44326_CR7) 2013; 493
Y Li (44326_CR37) 2015; 100
AR Thomson (44326_CR5) 2016; 529
AH Treiman (44326_CR15) 1983; 283-A
D Santamaria-Perez (44326_CR18) 2018; 57
F Birch (44326_CR33) 1947; 71
A Mujica (44326_CR62) 2013; 75
S Klotz (44326_CR43) 2009; 42
JAD Connolly (44326_CR4) 2005; 236
C Cazorla (44326_CR40) 2016; 28
44326_CR53
C Henmi (44326_CR17) 1978; 9
GM Sheldrick (44326_CR24) 2015; 71
44326_CR51
JP Perdew (44326_CR58) 2008; 100
44326_CR19
P Hohenberg (44326_CR57) 1964; 136
References_xml – volume: 57
  start-page: 6447
  year: 2018
  end-page: 6455
  ident: CR36
  article-title: An ultrahigh CO -loaded silicalite zeolite: Structural stability and physical properties at high pressures and temperatures
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.8b00523
– volume: 26
  start-page: 207
  year: 2019
  end-page: 289
  ident: CR14
  article-title: Phase equilibria and thermobarometry of calcareous, ultramafic and mafic rocks, and iron formations
  publication-title: Rev. Mineral.
– volume: 85
  start-page: 214101
  year: 2010
  ident: CR42
  article-title: High-pressure melting curve of helium and neon: Deviations from corresponding states theory
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.81.214101
– volume: 45
  start-page: 849
  year: 2012
  end-page: 854
  ident: CR52
  publication-title: J. Appl. Cryst.
  doi: 10.1107/S0021889812029111
– volume: 59
  start-page: 1758
  year: 1999
  end-page: 1775
  ident: CR60
  article-title: From ultrasoft pseudopotentials to the projector augmented-wave method
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.59.1758
– volume: 529
  start-page: 76
  year: 2016
  ident: CR5
  article-title: Slab melting as a barrier to deep carbon subduction
  publication-title: Nature
  doi: 10.1038/nature16174
– volume: 75
  start-page: 2631
  year: 2011
  end-page: 2648
  ident: CR9
  article-title: Galuskinite, Ca (SiO ) (CO ), a new skarn mineral from the Birkhin gabbro massif, Eastern Siberia, Russia
  publication-title: Mineral. Mag.
  doi: 10.1180/minmag.2011.075.5.2631
– volume: 39
  start-page: 11820
  year: 1989
  end-page: 11827
  ident: CR45
  article-title: X-Ray Diffraction and Equation of State of Solid Neon to 110 GPa
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.39.11820
– volume: 278
  start-page: 350
  year: 2009
  ident: CR3
  article-title: The transport of carbon and hydrogen in subducted oceanic crust: An experimental study to 5 GPa
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2008.12.022
– volume: 493
  start-page: 84
  year: 2013
  ident: CR7
  article-title: The oxidation state of the mantle and the extraction of carbon from Earth’s interior
  publication-title: Nature
  doi: 10.1038/nature11679
– ident: CR51
– volume: 49
  start-page: 71
  year: 1985
  end-page: 75
  ident: CR13
  article-title: The occurrence of coarse-grained massive tilleyite in the Redcap Creek magmatic skarn, North Queensland
  publication-title: Mineral. Magaz.
  doi: 10.1180/minmag.1985.049.350.09
– volume: 136
  start-page: 864
  year: 1964
  end-page: 871
  ident: CR57
  article-title: Inhomogeneous Electron Gas
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.136.B864
– volume: 18
  start-page: 469
  year: 1933
  end-page: 473
  ident: CR11
  article-title: Tilleyite, a new mineral from the contact zone at Crestmore, California
  publication-title: Amer. Mineral.
– volume: 49
  start-page: 14251
  year: 1994
  end-page: 14269
  ident: CR55
  article-title: molecular-dynamics simulation of the liquid-metal amorphous-semiconductor transition in germanium
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.49.14251
– volume: 6
  start-page: 771
  year: 2015
  end-page: 777
  ident: CR34
  article-title: The crystal chemistry and the compressibility of silicate-carbonate minerals: Spurrite, galuskinite and tilleyite
  publication-title: Geosci. Frontiers
  doi: 10.1016/j.gsf.2015.02.001
– volume: 3
  start-page: 688
  year: 1908
  end-page: 725
  ident: CR10
  article-title: Ore-deposits of the Velardeña district, Mexico
  publication-title: Econ. Geol.
  doi: 10.2113/gsecongeo.3.8.688
– volume: 47
  start-page: 558
  year: 1993
  end-page: 561
  ident: CR56
  article-title: molecular-dynamics for liquid-metals
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.47.558
– volume: 9
  start-page: 106
  year: 1978
  end-page: 110
  ident: CR17
  article-title: Synthesis of spurrite and tilleyite at low CO partial pressure
  publication-title: Mineral. J.
  doi: 10.2465/minerj.9.106
– volume: 101
  start-page: 277
  year: 2016
  end-page: 288
  ident: CR38
  article-title: Some thermodynamic properties of larnite (β-Ca SiO ) constrained by T/P experiment and/or theoretical simulation
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2016-5425
– volume: 100
  start-page: 2323
  year: 2015
  end-page: 2329
  ident: CR37
  article-title: P-V-T equation of state and high-pressure behavior of CaCO aragonite
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2015-5246
– volume: 257
  start-page: 656
  year: 1959
  end-page: 667
  ident: CR12
  article-title: The synthesis and stability of tilleyite, Ca Si O (CO )
  publication-title: Amer. J. Sci.
  doi: 10.2475/ajs.257.9.656
– volume: 283-A
  start-page: 97
  year: 1983
  end-page: 120
  ident: CR15
  article-title: Phase equilibria in the system CaO-SiO -CO
  publication-title: Amer. J. Sci.
– ident: CR19
– volume: 42
  start-page: 075413
  year: 2009
  ident: CR43
  article-title: Hydrostatic limits of 11 pressure transmitting media
  publication-title: J. Phys. D: Appl. Phys.
  doi: 10.1088/0022-3727/42/7/075413
– volume: 10
  start-page: 249
  year: 2004
  end-page: 318
  ident: CR23
  article-title: Voronoi-Dirichlet polyhedral in crystal chemistry: theory and applications
  publication-title: Crystal. Rev.
  doi: 10.1080/08893110412331323170
– volume: 75
  start-page: 183
  year: 2013
  ident: CR1
  article-title: Ingassing, storage, and outgassing of terrestrial carbon through geologic time
  publication-title: Rev. Mineral. Geochem.
  doi: 10.2138/rmg.2013.75.7
– volume: 40
  start-page: 649
  year: 1976
  end-page: 651
  ident: CR39
  article-title: Anisotropic thermal expansion characteristics of wollastonite
  publication-title: Mineral. Mag.
  doi: 10.1180/minmag.1976.040.314.16
– volume: 28
  start-page: 445401
  year: 2016
  ident: CR40
  article-title: Thallium under extreme compression
  publication-title: J. Phys.: Condens. Matter
– volume: 36
  start-page: 389
  year: 2008
  ident: CR8
  article-title: The redox state of the Earth’s mantle
  publication-title: Ann. Rev. Earth Planet. Sci.
  doi: 10.1146/annurev.earth.36.031207.124322
– volume: 56
  start-page: 159
  year: 1971
  end-page: 167
  ident: CR27
  article-title: Crystal structures of aragonite, strontianite, and witherite
  publication-title: Amer. Mineral.
– volume: 149
  start-page: 333
  year: 2015
  end-page: 337
  ident: CR28
  article-title: Scanning electron microscopy with energy dispersive spectroscopy and Raman and infrared spectroscopy study of tilleyite Ca Si O (CO ) -Y
  publication-title: Spectrochim. Acta A
  doi: 10.1016/j.saa.2015.04.015
– volume: 50
  start-page: 17953
  year: 1994
  end-page: 17979
  ident: CR59
  article-title: Projector augmented-wave method
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.50.17953
– volume: 71
  start-page: 3
  year: 2015
  end-page: 8
  ident: CR25
  article-title: Crystal structure refinement with SHELXL
  publication-title: Acta Cryst. C
  doi: 10.1107/S2053229614024218
– volume: 13
  start-page: 5188
  year: 1976
  end-page: 5192
  ident: CR61
  article-title: Special points for Brillouin-zone integrations
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.13.5188
– volume: 75
  start-page: 863
  year: 2013
  end-page: 912
  ident: CR62
  article-title: High-pressure phases of group-IV, III-V, and II-VI compounds
  publication-title: Rev. Mod. Phys.
  doi: 10.1103/RevModPhys.75.863
– volume: 57
  start-page: 98
  year: 2018
  end-page: 104
  ident: CR18
  article-title: Structural behavior of natural silicate-carbonate spurrite mineral, Ca (SiO ) (CO ), under high-pressure high-temperature conditions
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.7b02101
– volume: 333–334
  start-page: 265
  year: 2012
  end-page: 271
  ident: CR26
  article-title: CaCO -III and CaCO -IV, high-pressure polymorphs of calcite: Possible host structures for carbon in the Earth’s mantle
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2012.04.036
– volume: 91
  start-page: 4673
  year: 1986
  end-page: 4676
  ident: CR44
  article-title: Calibration of the Ruby Pressure Gauge to 800-Kbar under Quasi-Hydrostatic Conditions
  publication-title: J. Geophys. Res.-Solid Earth Planets
  doi: 10.1029/JB091iB05p04673
– volume: 13
  start-page: 256
  year: 1998
  end-page: 259
  ident: CR50
  article-title: Powdercell 2.0 for Windows
  publication-title: Powd. Diffract.
– volume: 71
  start-page: 809
  year: 1947
  end-page: 824
  ident: CR33
  article-title: Finite elastic strain of cubic crystals
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.71.809
– ident: CR53
– volume: 298
  start-page: 1
  year: 2010
  ident: CR2
  article-title: The deep carbon cycle and melting in Earth’s interior
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2010.06.039
– volume: 61
  start-page: 65
  year: 1997
  end-page: 77
  ident: CR49
  article-title: Unit cell refinement from powder diffraction data: the use of regression diagnostics”. Mineral
  publication-title: Magaz.
– volume: 100
  start-page: 136406
  year: 2008
  ident: CR58
  article-title: Restoring the density-gradient expansion for exchange in solids and surfaces
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.100.136406
– volume: 132
  start-page: 288
  year: 1970
  end-page: 306
  ident: CR21
  article-title: Crystal structure of tilleyite: Refinement and coordination
  publication-title: Zeits. Kristallogr.
  doi: 10.1524/zkri.1970.132.1-6.288
– volume: 27
  start-page: 431
  year: 2007
  end-page: 446
  ident: CR41
  article-title: Equations of state of MgO, Au, Pt, NaCl-B1, and NaCl-B2: Internally consistent high-temperature pressure scales
  publication-title: High Press. Res.
  doi: 10.1080/08957950701659700
– volume: 28
  start-page: 5360
  year: 2013
  end-page: 5370
  ident: CR46
  article-title: The new material science powder diffraction beamline at ALBA synchrotron
  publication-title: Powd. Diffract.
– volume: 43
  start-page: 1489
  year: 2005
  end-page: 1500
  ident: CR22
  article-title: The structure of spurrite, tileyite and scawtite, and relationships to other silicate-carbonate minerals
  publication-title: Can. Mineral.
  doi: 10.2113/gscanmin.43.5.1489
– volume: 6
  start-page: 15
  year: 1996
  end-page: 50
  ident: CR54
  article-title: Efficiency of total energy calculations for metals and semiconductors using a plane-wave basis set
  publication-title: Comput. Mater. Sci.
  doi: 10.1016/0927-0256(96)00008-0
– volume: 20
  start-page: 51
  year: 1981
  end-page: 56
  ident: CR30
  article-title: Raman spectroscopic study on the structure of silicate slags
  publication-title: Can. Metall. Q.
  doi: 10.1179/cmq.1981.20.1.51
– volume: 236
  start-page: 524
  year: 2005
  ident: CR4
  article-title: Computation of phase equilibria by linear programming: A tool for geodynamic modelling and its application to subduction zone decarbonation
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2005.04.033
– volume: 29
  start-page: 4502
  year: 2017
  end-page: 4510
  ident: CR35
  article-title: Structural evolution of the CO -filled pure silica LTA zeolite under high-pressure high-temperature conditions
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.7b01158
– ident: CR48
– volume: 35
  start-page: 223
  year: 2015
  end-page: 230
  ident: CR47
  article-title: DIOPTAS: A Program for Reduction of Two-Dimensional X-Ray Diffraction Data and Data Exploration
  publication-title: High Press. Res.
  doi: 10.1080/08957959.2015.1059835
– volume: 339
  start-page: 456
  year: 2011
  ident: CR6
  article-title: Redox freezing and melting in the Earth’s deep mantle resulting from carbon-iron redox coupling
  publication-title: Nature
– volume: 88
  start-page: 9831
  year: 1993
  end-page: 9834
  ident: CR32
  article-title: Pressure-induced amorphization of wollastonite CaSiO at room temperature
  publication-title: J. Chem. Phys.
– volume: 6
  start-page: 9
  year: 1953
  end-page: 18
  ident: CR20
  article-title: The crystal structure of tilleyite
  publication-title: Acta Cryst.
  doi: 10.1107/S0365110X53000028
– volume: 77
  start-page: 258
  year: 1992
  end-page: 269
  ident: CR31
  article-title: Raman and infrared study of pressure-induced structural changes in MgSiO , CaMgSi O and CaSiO glasses
  publication-title: Am. Mineral.
– volume: 134
  start-page: 297
  year: 1995
  end-page: 305
  ident: CR16
  article-title: High-pressure phase transformations of carbonates in the system CaO-MgO-SiO -CO
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/0012-821X(95)00130-5
– volume: 71
  start-page: 3
  year: 2015
  end-page: 8
  ident: CR24
  article-title: SHELXT - Integrated space-group and crystal-structure determination
  publication-title: Acta Cryst. A
  doi: 10.1107/S2053273314026370
– volume: 101
  start-page: 1642
  year: 2016
  end-page: 1650
  ident: CR29
  article-title: Metastable structural transformations and pressure-induced amorphization in natural (Mg,Fe) SiO olivine under static compression: A Raman spectroscopic study
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2016-5389CCBY
– volume: 28
  start-page: 445401
  year: 2016
  ident: 44326_CR40
  publication-title: J. Phys.: Condens. Matter
– volume: 49
  start-page: 71
  year: 1985
  ident: 44326_CR13
  publication-title: Mineral. Magaz.
  doi: 10.1180/minmag.1985.049.350.09
– volume: 43
  start-page: 1489
  year: 2005
  ident: 44326_CR22
  publication-title: Can. Mineral.
  doi: 10.2113/gscanmin.43.5.1489
– volume: 149
  start-page: 333
  year: 2015
  ident: 44326_CR28
  publication-title: Spectrochim. Acta A
  doi: 10.1016/j.saa.2015.04.015
– volume: 283-A
  start-page: 97
  year: 1983
  ident: 44326_CR15
  publication-title: Amer. J. Sci.
– volume: 57
  start-page: 98
  year: 2018
  ident: 44326_CR18
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.7b02101
– volume: 132
  start-page: 288
  year: 1970
  ident: 44326_CR21
  publication-title: Zeits. Kristallogr.
  doi: 10.1524/zkri.1970.132.1-6.288
– volume: 9
  start-page: 106
  year: 1978
  ident: 44326_CR17
  publication-title: Mineral. J.
  doi: 10.2465/minerj.9.106
– ident: 44326_CR51
– volume: 13
  start-page: 5188
  year: 1976
  ident: 44326_CR61
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.13.5188
– volume: 27
  start-page: 431
  year: 2007
  ident: 44326_CR41
  publication-title: High Press. Res.
  doi: 10.1080/08957950701659700
– volume: 339
  start-page: 456
  year: 2011
  ident: 44326_CR6
  publication-title: Nature
– volume: 29
  start-page: 4502
  year: 2017
  ident: 44326_CR35
  publication-title: Chem. Mater.
  doi: 10.1021/acs.chemmater.7b01158
– volume: 3
  start-page: 688
  year: 1908
  ident: 44326_CR10
  publication-title: Econ. Geol.
  doi: 10.2113/gsecongeo.3.8.688
– volume: 529
  start-page: 76
  year: 2016
  ident: 44326_CR5
  publication-title: Nature
  doi: 10.1038/nature16174
– volume: 61
  start-page: 65
  year: 1997
  ident: 44326_CR49
  publication-title: Magaz.
– volume: 39
  start-page: 11820
  year: 1989
  ident: 44326_CR45
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.39.11820
– volume: 75
  start-page: 2631
  year: 2011
  ident: 44326_CR9
  publication-title: Mineral. Mag.
  doi: 10.1180/minmag.2011.075.5.2631
– volume: 236
  start-page: 524
  year: 2005
  ident: 44326_CR4
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2005.04.033
– volume: 47
  start-page: 558
  year: 1993
  ident: 44326_CR56
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.47.558
– volume: 278
  start-page: 350
  year: 2009
  ident: 44326_CR3
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2008.12.022
– volume: 20
  start-page: 51
  year: 1981
  ident: 44326_CR30
  publication-title: Can. Metall. Q.
  doi: 10.1179/cmq.1981.20.1.51
– volume: 42
  start-page: 075413
  year: 2009
  ident: 44326_CR43
  publication-title: J. Phys. D: Appl. Phys.
  doi: 10.1088/0022-3727/42/7/075413
– volume: 6
  start-page: 771
  year: 2015
  ident: 44326_CR34
  publication-title: Geosci. Frontiers
  doi: 10.1016/j.gsf.2015.02.001
– volume: 134
  start-page: 297
  year: 1995
  ident: 44326_CR16
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/0012-821X(95)00130-5
– volume: 91
  start-page: 4673
  year: 1986
  ident: 44326_CR44
  publication-title: J. Geophys. Res.-Solid Earth Planets
  doi: 10.1029/JB091iB05p04673
– volume: 75
  start-page: 863
  year: 2013
  ident: 44326_CR62
  publication-title: Rev. Mod. Phys.
  doi: 10.1103/RevModPhys.75.863
– volume: 136
  start-page: 864
  year: 1964
  ident: 44326_CR57
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.136.B864
– volume: 26
  start-page: 207
  year: 2019
  ident: 44326_CR14
  publication-title: Rev. Mineral.
– volume: 333–334
  start-page: 265
  year: 2012
  ident: 44326_CR26
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2012.04.036
– volume: 71
  start-page: 809
  year: 1947
  ident: 44326_CR33
  publication-title: Phys. Rev.
  doi: 10.1103/PhysRev.71.809
– volume: 35
  start-page: 223
  year: 2015
  ident: 44326_CR47
  publication-title: High Press. Res.
  doi: 10.1080/08957959.2015.1059835
– volume: 13
  start-page: 256
  year: 1998
  ident: 44326_CR50
  publication-title: Powd. Diffract.
– volume: 28
  start-page: 5360
  year: 2013
  ident: 44326_CR46
  publication-title: Powd. Diffract.
– volume: 101
  start-page: 1642
  year: 2016
  ident: 44326_CR29
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2016-5389CCBY
– volume: 71
  start-page: 3
  year: 2015
  ident: 44326_CR24
  publication-title: Acta Cryst. A
  doi: 10.1107/S2053273314026370
– volume: 49
  start-page: 14251
  year: 1994
  ident: 44326_CR55
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.49.14251
– volume: 59
  start-page: 1758
  year: 1999
  ident: 44326_CR60
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.59.1758
– volume: 36
  start-page: 389
  year: 2008
  ident: 44326_CR8
  publication-title: Ann. Rev. Earth Planet. Sci.
  doi: 10.1146/annurev.earth.36.031207.124322
– volume: 298
  start-page: 1
  year: 2010
  ident: 44326_CR2
  publication-title: Earth Planet. Sci. Lett.
  doi: 10.1016/j.epsl.2010.06.039
– volume: 10
  start-page: 249
  year: 2004
  ident: 44326_CR23
  publication-title: Crystal. Rev.
  doi: 10.1080/08893110412331323170
– volume: 75
  start-page: 183
  year: 2013
  ident: 44326_CR1
  publication-title: Rev. Mineral. Geochem.
  doi: 10.2138/rmg.2013.75.7
– ident: 44326_CR48
– volume: 50
  start-page: 17953
  year: 1994
  ident: 44326_CR59
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.50.17953
– volume: 493
  start-page: 84
  year: 2013
  ident: 44326_CR7
  publication-title: Nature
  doi: 10.1038/nature11679
– ident: 44326_CR19
– volume: 45
  start-page: 849
  year: 2012
  ident: 44326_CR52
  publication-title: J. Appl. Cryst.
  doi: 10.1107/S0021889812029111
– volume: 257
  start-page: 656
  year: 1959
  ident: 44326_CR12
  publication-title: Amer. J. Sci.
  doi: 10.2475/ajs.257.9.656
– volume: 6
  start-page: 15
  year: 1996
  ident: 44326_CR54
  publication-title: Comput. Mater. Sci.
  doi: 10.1016/0927-0256(96)00008-0
– volume: 56
  start-page: 159
  year: 1971
  ident: 44326_CR27
  publication-title: Amer. Mineral.
– ident: 44326_CR53
  doi: 10.1038/nature16164
– volume: 100
  start-page: 2323
  year: 2015
  ident: 44326_CR37
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2015-5246
– volume: 101
  start-page: 277
  year: 2016
  ident: 44326_CR38
  publication-title: Amer. Mineral.
  doi: 10.2138/am-2016-5425
– volume: 40
  start-page: 649
  year: 1976
  ident: 44326_CR39
  publication-title: Mineral. Mag.
  doi: 10.1180/minmag.1976.040.314.16
– volume: 88
  start-page: 9831
  year: 1993
  ident: 44326_CR32
  publication-title: J. Chem. Phys.
– volume: 6
  start-page: 9
  year: 1953
  ident: 44326_CR20
  publication-title: Acta Cryst.
  doi: 10.1107/S0365110X53000028
– volume: 77
  start-page: 258
  year: 1992
  ident: 44326_CR31
  publication-title: Am. Mineral.
– volume: 57
  start-page: 6447
  year: 2018
  ident: 44326_CR36
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.8b00523
– volume: 100
  start-page: 136406
  year: 2008
  ident: 44326_CR58
  publication-title: Phys. Rev. Lett.
  doi: 10.1103/PhysRevLett.100.136406
– volume: 85
  start-page: 214101
  year: 2010
  ident: 44326_CR42
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.81.214101
– volume: 18
  start-page: 469
  year: 1933
  ident: 44326_CR11
  publication-title: Amer. Mineral.
– volume: 71
  start-page: 3
  year: 2015
  ident: 44326_CR25
  publication-title: Acta Cryst. C
  doi: 10.1107/S2053229614024218
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Snippet Calcium carbonate is a relevant constituent of the Earth’s crust that is transferred into the deep Earth through the subduction process. Its chemical...
Calcium carbonate is a relevant constituent of the Earth's crust that is transferred into the deep Earth through the subduction process. Its chemical...
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SubjectTerms 119/118
140/133
639/301/119
704/2151/330
Aluminum oxide
Calcium carbonate
Carbon
Cations
Compression
High temperature
Humanities and Social Sciences
Minerals
multidisciplinary
Powder
Raman spectroscopy
Science
Science (multidisciplinary)
Silica
Silicates
Spectrum analysis
Structural behavior
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Title Post-tilleyite, a dense calcium silicate-carbonate phase
URI https://link.springer.com/article/10.1038/s41598-019-44326-9
https://www.ncbi.nlm.nih.gov/pubmed/31133679
https://www.proquest.com/docview/2230626003
https://www.proquest.com/docview/2232107309
https://pubmed.ncbi.nlm.nih.gov/PMC6536543
Volume 9
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