A review on carboxylic acid cross‐linked polyvinyl alcohol: Properties and applications

Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of PVA such as its film‐forming ability, high tensile strength and flexibility, high viscosity, solvent tolerance ability, thermostable nature h...

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Published inPolymer engineering and science Vol. 62; no. 2; pp. 225 - 246
Main Authors Gautam, Leela, Warkar, Sudhir G., Ahmad, Syed Ishraque, Kant, Ravi, Jain, Manish
Format Journal Article
LanguageEnglish
Published Hoboken, USA John Wiley & Sons, Inc 01.02.2022
Society of Plastics Engineers, Inc
Blackwell Publishing Ltd
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Abstract Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of PVA such as its film‐forming ability, high tensile strength and flexibility, high viscosity, solvent tolerance ability, thermostable nature have made it vital and drawn the attention of scientific community. However, being a water‐soluble polymer, some chemical modifications are required to alter this property of PVA. Cross‐linking is the most attractive and widely used method to change the properties of PVA to make it more valuable material. Different carboxylic acids have already been used for PVA cross‐linking in various applications such as pervaporation, reverse osmosis (RO), wound dressing, drug delivery, and fuel cells. However, a comprehensive study on structure–property correlation of carboxylic acids as PVA cross‐linker is not available. In this review, different available studies on carboxylic acid cross‐linked PVA are summarized and are used to develop structure–property correlations of carboxylic acids as cross‐linker on the properties of cross‐linked PVA. Advantages and limitations of different carboxylic acids as PVA cross‐linker are also summarized for various fields such as tissue engineering, wound dressing, drug delivery, fuel cell/solid polymer electrolyte, pervaporation, desalination and RO solid polymer electrolytes, and food packaging.
AbstractList Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of PVA such as its film‐forming ability, high tensile strength and flexibility, high viscosity, solvent tolerance ability, thermostable nature have made it vital and drawn the attention of scientific community. However, being a water‐soluble polymer, some chemical modifications are required to alter this property of PVA. Cross‐linking is the most attractive and widely used method to change the properties of PVA to make it more valuable material. Different carboxylic acids have already been used for PVA cross‐linking in various applications such as pervaporation, reverse osmosis (RO), wound dressing, drug delivery, and fuel cells. However, a comprehensive study on structure–property correlation of carboxylic acids as PVA cross‐linker is not available. In this review, different available studies on carboxylic acid cross‐linked PVA are summarized and are used to develop structure–property correlations of carboxylic acids as cross‐linker on the properties of cross‐linked PVA. Advantages and limitations of different carboxylic acids as PVA cross‐linker are also summarized for various fields such as tissue engineering, wound dressing, drug delivery, fuel cell/solid polymer electrolyte, pervaporation, desalination and RO solid polymer electrolytes, and food packaging.
Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of PVA such as its film-forming ability, high tensile strength and flexibility, high viscosity, solvent tolerance ability, thermostable nature have made it vital and drawn the attention of scientific community. However, being a watersoluble polymer, some chemical modifications are required to alter this property of PVA. Cross-linking is the most attractive and widely used method to change the properties of PVA to make it more valuable material. Different carboxylic acids have already been used for PVA cross-linking in various applications such as pervaporation, reverse osmosis (RO), wound dressing, drug delivery, and fuel cells. However, a comprehensive study on structure-property correlation of carboxylic acids as PVA cross-linker is not available. In this review, different available studies on carboxylic acid cross-linked PVA are summarized and are used to develop structure-property correlations of carboxylic acids as cross-linker on the properties of cross-linked PVA. Advantages and limitations of different carboxylic acids as PVA cross-linker are also summarized for various fields such as tissue engineering, wound dressing, drug delivery, fuel cell/ solid polymer electrolyte, pervaporation, desalination and RO solid polymer electrolytes, and food packaging.
Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of PVA such as its film-forming ability, high tensile strength and flexibility, high viscosity, solvent tolerance ability, thermostable nature have made it vital and drawn the attention of scientific community. However, being a watersoluble polymer, some chemical modifications are required to alter this property of PVA. Cross-linking is the most attractive and widely used method to change the properties of PVA to make it more valuable material. Different carboxylic acids have already been used for PVA cross-linking in various applications such as pervaporation, reverse osmosis (RO), wound dressing, drug delivery, and fuel cells. However, a comprehensive study on structure-property correlation of carboxylic acids as PVA cross-linker is not available. In this review, different available studies on carboxylic acid cross-linked PVA are summarized and are used to develop structure-property correlations of carboxylic acids as cross-linker on the properties of cross-linked PVA. Advantages and limitations of different carboxylic acids as PVA cross-linker are also summarized for various fields such as tissue engineering, wound dressing, drug delivery, fuel cell/ solid polymer electrolyte, pervaporation, desalination and RO solid polymer electrolytes, and food packaging. KEYWORDS carboxylic acids, cross-linked PVA, cross-linking, films, membranes, water- soluble polymers
Audience Academic
Author Warkar, Sudhir G.
Gautam, Leela
Kant, Ravi
Jain, Manish
Ahmad, Syed Ishraque
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  surname: Warkar
  fullname: Warkar, Sudhir G.
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  surname: Ahmad
  fullname: Ahmad, Syed Ishraque
  organization: Zakir Husain Delhi College (University of Delhi)
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  surname: Jain
  fullname: Jain, Manish
  email: manishjain@dtu.ac.in
  organization: Delhi Technological University
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Blackwell Publishing Ltd
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Snippet Polyvinyl alcohol (PVA) is a nontoxic, biodegradable, and biocompatible polymer and has been used extensively in various fields. Indeed, important features of...
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SubjectTerms Acids
Biocompatibility
Biodegradability
Carboxylic acids
cross‐linked PVA
cross‐linking
Desalination
Electrolytes
Electrolytic cells
Food packaging
Fuel cells
membranes
Molten salt electrolytes
Pervaporation
Polymers
Polyvinyl alcohol
Properties
Reverse osmosis
Solid electrolytes
Tensile strength
Tissue engineering
water‐soluble polymers
Wound healing
Title A review on carboxylic acid cross‐linked polyvinyl alcohol: Properties and applications
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fpen.25849
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Volume 62
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