Spin-Crossover Cluster of Iron(II) Exhibiting a Mixed-Spin Structure and Synergy between Spin Transition and Magnetic Interaction
How low can you go? An FeII ₄ square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the...
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Published in | Angewandte Chemie (International ed.) Vol. 48; no. 8; pp. 1475 - 1478 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Weinheim
Wiley-VCH Verlag
01.01.2009
WILEY‐VCH Verlag |
Subjects | |
Online Access | Get full text |
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Summary: | How low can you go? An FeII ₄ square was prepared by self-assembly and exhibits both thermally induced and photoinduced spin crossover from a system with four high-spin (HS) centers to one with two high-spin and two low-spin (LS) centers. The spin-crossover sites are located on the same side of the square, and the spin transition and magnetic interactions (see picture) are synergistically coupled. |
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Bibliography: | http://dx.doi.org/10.1002/anie.200804529 This work was supported by Grants‐in‐Aid for Scientific Research on Priority Areas (No. 20036040, “Synergy of Elements”) from the Ministry of Education, Culture, Sports, Science, and Technology (Japan) ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.200804529 |