The concept of entropic rectifier facing experiments
The transport of molecules in confined media is subject to entropic barriers. So theoretically, asymmetry of the confinement length may lead to molecular ratchets with entropy as the only driving force for the biased transport. We address experimentally this question by performing alternative ionic...
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| Published in | Scientific reports Vol. 6; no. 1; p. 38966 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
| Published |
London
Nature Publishing Group UK
12.12.2016
Nature Publishing Group |
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| Abstract | The transport of molecules in confined media is subject to entropic barriers. So theoretically, asymmetry of the confinement length may lead to molecular ratchets with entropy as the only driving force for the biased transport. We address experimentally this question by performing alternative ionic current measurements on electrolytes confined in neutral conical nanopores. In case anions and cations widely differ in size, we show that rectification of ionic current can be obtained that depends on ions size and cycle frequency, consistently with the entropic ratchet mechanism. |
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| AbstractList | The transport of molecules in confined media is subject to entropic barriers. So theoretically, asymmetry of the confinement length may lead to molecular ratchets with entropy as the only driving force for the biased transport. We address experimentally this question by performing alternative ionic current measurements on electrolytes confined in neutral conical nanopores. In case anions and cations widely differ in size, we show that rectification of ionic current can be obtained that depends on ions size and cycle frequency, consistently with the entropic ratchet mechanism. |
| ArticleNumber | 38966 |
| Author | Wegrowe, J.-E. Lairez, D. Clochard, M.-C. |
| Author_xml | – sequence: 1 givenname: D. surname: Lairez fullname: Lairez, D. organization: Laboratoire Léon Brillouin, CNRS, CEA, Université Paris-Saclay – sequence: 2 givenname: M.-C. surname: Clochard fullname: Clochard, M.-C. organization: Laboratoire des Solides Irradiés, École polytechnique, CNRS, CEA, Université Paris-Saclay – sequence: 3 givenname: J.-E. surname: Wegrowe fullname: Wegrowe, J.-E. organization: Laboratoire des Solides Irradiés, École polytechnique, CNRS, CEA, Université Paris-Saclay |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27941925$$D View this record in MEDLINE/PubMed https://hal.science/hal-02507121$$DView record in HAL |
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| CitedBy_id | crossref_primary_10_1016_j_physa_2023_129155 crossref_primary_10_1140_epje_s10189_024_00408_9 crossref_primary_10_1103_PhysRevE_96_022152 crossref_primary_10_1063_1_5110349 crossref_primary_10_1063_1_5048343 crossref_primary_10_1063_1_5141040 crossref_primary_10_1063_1_4979984 crossref_primary_10_1063_1_4982884 crossref_primary_10_1140_epje_i2018_11686_7 crossref_primary_10_1103_PhysRevE_99_032102 crossref_primary_10_1209_0295_5075_127_10001 crossref_primary_10_1021_acs_macromol_0c02413 crossref_primary_10_1088_1361_648X_aac0c0 |
| Cites_doi | 10.1039/C5SM02693H 10.1126/science.276.5314.917 10.1063/1.4892615 10.1063/1.4961505 10.1039/C6NR01445C 10.1103/PhysRevLett.72.1766 10.1021/j100189a004 10.1039/C5TA04092B 10.1016/S0370-1573(01)00081-3 10.1103/RevModPhys.81.387 10.1063/1.4896474 10.1103/PhysRevE.77.031131 10.1103/PhysRevLett.111.028102 10.1103/PhysRevLett.105.260602 10.1103/PhysRevLett.89.198103 10.1103/PhysRevLett.96.130603 10.1016/0378-4371(95)00206-5 10.1007/s003390201407 10.1002/adfm.200500471 10.1021/jacs.5b09918 10.1016/j.chemphys.2010.04.029 10.1016/0065-227X(90)90009-I 10.1103/PhysRevLett.108.020604 10.1103/PhysRev.31.101 10.1103/PhysRev.78.627.2 10.1063/1.2179797 10.1021/acs.jpcc.5b11522 10.1002/anie.201104904 |
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| Title | The concept of entropic rectifier facing experiments |
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