Real-time monitoring of scale formation in reverse osmosis using electrical impedance spectroscopy
Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently sensitive to detect the subtle changes occurring across the membrane. Electrical impedance spectroscopy (EIS) was investigated as a tool for measur...
Saved in:
| Published in | Journal of membrane science Vol. 453; pp. 320 - 327 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
01.03.2014
Elsevier |
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently sensitive to detect the subtle changes occurring across the membrane. Electrical impedance spectroscopy (EIS) was investigated as a tool for measuring the electrical properties in real time and to identify changes that occur during calcium sulfate scaling in a reverse osmosis system. EIS signals were obtained across a frequency range of 10−1–105Hz during the filtration of calcium sulfate scale forming constituents in recirculation and batch modes. The measured capacitance and conductance of various electrically distinct layers were compared against the flux measurements, in order to assess their significance to indicate the scale formation. The rate of change in conductance was higher than the flux decline. Change in the conductance value around 38Hz, corresponding to the coating layer on the active membrane surface was most suitable. From the suggested approach of monitoring the changes in conductance at 10–100Hz, scale formation can be detected prior to observing any significant permeate flux decline.
•Electrical properties of RO system were monitored real time, in-situ.•EIS was investigated as a tool for early detection of scale formation.•Protocol developed to assess the impedance signal during CaSO4 scaling.•Compared signal intensities of flux and conductance at specific frequencies. |
|---|---|
| AbstractList | Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently sensitive to detect the subtle changes occurring across the membrane. Electrical impedance spectroscopy (EIS) was investigated as a tool for measuring the electrical properties in real time and to identify changes that occur during calcium sulfate scaling in a reverse osmosis system. EIS signals were obtained across a frequency range of 10-1-105 Hz during the filtration of calcium sulfate scale forming constituents in recirculation and batch modes. The measured capacitance and conductance of various electrically distinct layers were compared against the flux measurements, in order to assess their significance to indicate the scale formation. The rate of change in conductance was higher than the flux decline. Change in the conductance value around 38 Hz, corresponding to the coating layer on the active membrane surface was most suitable. From the suggested approach of monitoring the changes in conductance at 10-100 Hz, scale formation can be detected prior to observing any significant permeate flux decline. Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently sensitive to detect the subtle changes occurring across the membrane. Electrical impedance spectroscopy (EIS) was investigated as a tool for measuring the electrical properties in real time and to identify changes that occur during calcium sulfate scaling in a reverse osmosis system. EIS signals were obtained across a frequency range of 10−1–105Hz during the filtration of calcium sulfate scale forming constituents in recirculation and batch modes. The measured capacitance and conductance of various electrically distinct layers were compared against the flux measurements, in order to assess their significance to indicate the scale formation. The rate of change in conductance was higher than the flux decline. Change in the conductance value around 38Hz, corresponding to the coating layer on the active membrane surface was most suitable. From the suggested approach of monitoring the changes in conductance at 10–100Hz, scale formation can be detected prior to observing any significant permeate flux decline. •Electrical properties of RO system were monitored real time, in-situ.•EIS was investigated as a tool for early detection of scale formation.•Protocol developed to assess the impedance signal during CaSO4 scaling.•Compared signal intensities of flux and conductance at specific frequencies. Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently sensitive to detect the subtle changes occurring across the membrane. Electrical impedance spectroscopy (EIS) was investigated as a tool for measuring the electrical properties in real time and to identify changes that occur during calcium sulfate scaling in a reverse osmosis system. EIS signals were obtained across a frequency range of 10⁻¹–10⁵Hz during the filtration of calcium sulfate scale forming constituents in recirculation and batch modes. The measured capacitance and conductance of various electrically distinct layers were compared against the flux measurements, in order to assess their significance to indicate the scale formation. The rate of change in conductance was higher than the flux decline. Change in the conductance value around 38Hz, corresponding to the coating layer on the active membrane surface was most suitable. From the suggested approach of monitoring the changes in conductance at 10–100Hz, scale formation can be detected prior to observing any significant permeate flux decline. |
| Author | Leslie, Greg Hu, Zhixin Antony, Alice Le-Clech, Pierre |
| Author_xml | – sequence: 1 givenname: Zhixin surname: Hu fullname: Hu, Zhixin – sequence: 2 givenname: Alice orcidid: 0000-0002-2195-8387 surname: Antony fullname: Antony, Alice email: alicea@unsw.edu.au – sequence: 3 givenname: Greg surname: Leslie fullname: Leslie, Greg – sequence: 4 givenname: Pierre surname: Le-Clech fullname: Le-Clech, Pierre |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=28352174$$DView record in Pascal Francis |
| BookMark | eNqFkU1r3DAURbVIIV_9B11oU-jGrp4kS3YXhRKaJhAolGYtNPJT0WBZruQJ5N9X7qSbLjIrwePci7jnkpzNaUZC3gFrgYH6uG8jxuJCyxmIFqBlIM_IBRNaNVr0_Tm5LGXPGGjWDxdk9wPt1KwhIo1pDmvKYf5Fk6fF2QmpTznaNaSZhplmfMJckKYSUwmFHsrG4oRuzaHiNMQFRzs7pGXZjqm4tDxfkzfeTgXfvrxX5PH268-bu-bh-7f7my8PjZOarw10uH0K2M5yJQZQQgslrfBMMi5H2PVMCD44KQarx84xL_qx077nuFODF-KKfDj2Ljn9PmBZTQzF4TTZGdOhGF73EaC07E6i0DMmuVJMnUZ1B5wNUm3o-xfUbuv5XKcIxSw5RJufDe9Fx0HLyn06cq4uVDJ648L6d-U12zAZYGZTafbmqNJsKg2AqSprWP4X_td_Ivb5GMNq4ClgNpXAqmoMuaoyYwqvF_wBtM-9tQ |
| CODEN | JMESDO |
| CitedBy_id | crossref_primary_10_1016_j_watres_2018_08_019 crossref_primary_10_1016_j_colsurfa_2016_02_004 crossref_primary_10_1016_j_memsci_2015_03_014 crossref_primary_10_1021_acs_est_6b00418 crossref_primary_10_1016_j_desal_2016_03_014 crossref_primary_10_1016_j_ijhydene_2014_10_003 crossref_primary_10_1021_acs_est_0c03826 crossref_primary_10_1016_j_desal_2020_114857 crossref_primary_10_1016_j_renene_2018_11_065 crossref_primary_10_1016_j_memsci_2015_09_042 crossref_primary_10_1016_j_memsci_2019_117603 crossref_primary_10_1016_j_memsci_2014_11_007 crossref_primary_10_1016_j_desal_2019_114193 crossref_primary_10_1016_j_scitotenv_2017_03_235 crossref_primary_10_1016_j_cis_2023_102834 crossref_primary_10_1016_j_jece_2023_110317 crossref_primary_10_1016_j_desal_2019_02_008 crossref_primary_10_1016_j_memsci_2024_123253 crossref_primary_10_1016_j_memsci_2016_06_043 crossref_primary_10_1016_j_desal_2017_09_013 crossref_primary_10_1016_j_cherd_2020_03_018 crossref_primary_10_2139_ssrn_4124149 crossref_primary_10_3390_membranes12090894 crossref_primary_10_5004_dwt_2020_26448 crossref_primary_10_1016_j_memsci_2020_118680 crossref_primary_10_1016_j_desal_2019_01_027 crossref_primary_10_1016_j_jwpe_2024_106430 crossref_primary_10_1016_j_seppur_2021_119615 crossref_primary_10_1016_j_memsci_2017_01_027 crossref_primary_10_1016_j_jtice_2017_11_027 crossref_primary_10_1021_acs_iecr_8b01272 crossref_primary_10_1016_j_desal_2023_116851 crossref_primary_10_1016_j_watres_2019_03_021 crossref_primary_10_1016_j_jiec_2021_11_019 crossref_primary_10_1039_C5RA17221G crossref_primary_10_5004_dwt_2017_20391 crossref_primary_10_1016_j_cis_2024_103179 crossref_primary_10_1016_j_jtice_2021_104197 crossref_primary_10_1016_j_memsci_2014_05_035 crossref_primary_10_1016_j_memsci_2015_11_006 crossref_primary_10_3390_w11040695 crossref_primary_10_1016_j_jwpe_2022_103295 crossref_primary_10_1016_j_desal_2017_12_009 crossref_primary_10_1016_j_memsci_2019_04_010 crossref_primary_10_1016_j_envadv_2022_100281 crossref_primary_10_1021_acs_est_7b02775 crossref_primary_10_1016_j_memsci_2017_10_043 crossref_primary_10_1016_j_desal_2015_11_006 crossref_primary_10_1016_j_watres_2024_121340 crossref_primary_10_3390_membranes10090220 crossref_primary_10_1016_j_memsci_2020_118527 crossref_primary_10_1021_acsomega_4c04912 crossref_primary_10_1016_j_desal_2020_114323 |
| Cites_doi | 10.1016/j.memsci.2012.09.028 10.1088/1742-6596/434/1/012089 10.1016/j.desal.2009.02.056 10.1016/j.memsci.2004.12.023 10.1016/j.desal.2004.11.017 10.1016/j.memsci.2006.12.038 10.1016/j.memsci.2013.04.047 10.1016/0011-9164(91)85087-B 10.1016/j.desal.2007.10.066 10.1080/19443994.2012.714657 10.1016/j.memsci.2009.05.039 10.1016/j.memsci.2008.01.030 10.1016/S0376-7388(99)00156-8 10.1016/j.memsci.2013.03.022 10.1252/jcej.17.145 10.1016/0376-7388(92)80087-Z 10.1016/0011-9164(96)00012-4 10.1016/j.desal.2010.10.021 10.1016/j.desal.2008.10.005 10.1016/j.desal.2011.04.053 10.1016/S0009-2509(96)00505-2 10.1016/j.memsci.2004.07.022 10.1016/j.memsci.2011.08.054 10.1021/ie051040k 10.1016/j.ijheatmasstransfer.2012.07.006 10.1179/ida.2011.3.3.12 |
| ContentType | Journal Article |
| Copyright | 2013 Elsevier B.V. 2015 INIST-CNRS |
| Copyright_xml | – notice: 2013 Elsevier B.V. – notice: 2015 INIST-CNRS |
| DBID | AAYXX CITATION IQODW 7QH 7UA C1K F1W H97 L.G 7SR 8BQ 8FD JG9 7S9 L.6 |
| DOI | 10.1016/j.memsci.2013.11.014 |
| DatabaseName | CrossRef Pascal-Francis Aqualine Water Resources Abstracts Environmental Sciences and Pollution Management ASFA: Aquatic Sciences and Fisheries Abstracts Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality Aquatic Science & Fisheries Abstracts (ASFA) Professional Engineered Materials Abstracts METADEX Technology Research Database Materials Research Database AGRICOLA AGRICOLA - Academic |
| DatabaseTitle | CrossRef Aquatic Science & Fisheries Abstracts (ASFA) Professional Aqualine Aquatic Science & Fisheries Abstracts (ASFA) 3: Aquatic Pollution & Environmental Quality ASFA: Aquatic Sciences and Fisheries Abstracts Water Resources Abstracts Environmental Sciences and Pollution Management Materials Research Database Engineered Materials Abstracts Technology Research Database METADEX AGRICOLA AGRICOLA - Academic |
| DatabaseTitleList | Aquatic Science & Fisheries Abstracts (ASFA) Professional Materials Research Database AGRICOLA |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Engineering Chemistry |
| EndPage | 327 |
| ExternalDocumentID | 28352174 10_1016_j_memsci_2013_11_014 S0376738813008995 |
| GroupedDBID | --- --K --M -~X .~1 0R~ 1B1 1~. 1~5 4.4 457 4G. 53G 5GY 5VS 7-5 71M 8P~ 9JN AABNK AABXZ AAEDT AAEDW AAEPC AAHBH AAIKJ AAKOC AALRI AAOAW AAQFI AATTM AAXKI AAXUO AAYWO ABFNM ABJNI ABMAC ABNUV ABXDB ABXRA ACDAQ ACGFS ACRLP ACVFH ADBBV ADCNI ADEWK ADEZE AEBSH AEIPS AEKER AENEX AEUPX AEZYN AFPUW AFRZQ AFTJW AFXIZ AGCQF AGHFR AGRNS AGUBO AGYEJ AHHHB AHPOS AIEXJ AIIUN AIKHN AITUG AKBMS AKRWK AKURH AKYEP ALMA_UNASSIGNED_HOLDINGS AMRAJ ANKPU AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFKBS ENUVR EO8 EO9 EP2 EP3 F5P FDB FIRID FNPLU FYGXN G-Q GBLVA IHE J1W KOM LX7 M41 MAGPM MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SCC SDF SDG SDP SES SPC SPCBC SSG SSH SSM SSZ T5K XPP Y6R ZMT ~G- 29L AAQXK AAYXX ABWVN ACNNM ACRPL ADMUD ADNMO AFJKZ AGQPQ AI. AIGII APXCP ASPBG AVWKF AZFZN BBWZM BNPGV CITATION EJD FEDTE FGOYB HLY HVGLF HZ~ NDZJH R2- SCE SEW VH1 WUQ AACTN IQODW 7QH 7UA C1K F1W H97 L.G 7SR 8BQ 8FD JG9 7S9 L.6 |
| ID | FETCH-LOGICAL-c472t-15e017010ba26391637364a3f04024d1b803329c439a7d5c0f38d57f82eb69f33 |
| IEDL.DBID | .~1 |
| ISSN | 0376-7388 |
| IngestDate | Fri Jul 11 00:59:27 EDT 2025 Fri Jul 11 08:45:57 EDT 2025 Fri Jul 11 12:19:11 EDT 2025 Wed Apr 02 07:26:29 EDT 2025 Tue Jul 01 03:37:55 EDT 2025 Thu Apr 24 23:10:41 EDT 2025 Thu Jul 17 02:00:42 EDT 2025 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Keywords | Reverse osmosis Real time monitoring Electrical impedance spectroscopy Calcium sulfate Membrane separation Membrane Electrical impedance |
| Language | English |
| License | CC BY 4.0 |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c472t-15e017010ba26391637364a3f04024d1b803329c439a7d5c0f38d57f82eb69f33 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| ORCID | 0000-0002-2195-8387 |
| PQID | 1751209466 |
| PQPubID | 23462 |
| PageCount | 8 |
| ParticipantIDs | proquest_miscellaneous_2101316745 proquest_miscellaneous_1800426606 proquest_miscellaneous_1751209466 pascalfrancis_primary_28352174 crossref_citationtrail_10_1016_j_memsci_2013_11_014 crossref_primary_10_1016_j_memsci_2013_11_014 elsevier_sciencedirect_doi_10_1016_j_memsci_2013_11_014 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 2014-03-01 |
| PublicationDateYYYYMMDD | 2014-03-01 |
| PublicationDate_xml | – month: 03 year: 2014 text: 2014-03-01 day: 01 |
| PublicationDecade | 2010 |
| PublicationPlace | Amsterdam |
| PublicationPlace_xml | – name: Amsterdam |
| PublicationTitle | Journal of membrane science |
| PublicationYear | 2014 |
| Publisher | Elsevier B.V Elsevier |
| Publisher_xml | – name: Elsevier B.V – name: Elsevier |
| References | Shih, Rahardianto, Lee, Cohen (bib21) 2005; 252 Pääkkönen, Riihimäki, Simonson, Muurinen, Keiski (bib20) 2012; 55 Cobry, Yuan, Gilron, Bright, Krantz, Greenberg (bib6) 2011; 283 Chilcott (bib26) 2013; 438 Antony, Low, Gray, Childress, Le-Clech, Leslie (bib2) 2011; 383 Uchymiak, Bartman, Daltrophe, Weissman, Gilron, Christofides, Kaiser, Cohen (bib4) 2009; 341 Najibi, Müller-Steinhagen, Jamialahmadi (bib22) 1997; 52 Bramson, Hasson, Semiat (bib23) 1995; 100 Okazaki, Kimura (bib25) 1984; 17 Chilcott, Antony, Coster, Leslie (bib27) 2013; 434 Park, Chilcott, Coster, Moon (bib9) 2005; 246 Coster, Chilcott (bib12) 1999; 79 Pomerantz, Ladizhansky, Korin, Waisman, Daltrophe, Gilron (bib17) 2006; 45 Pervov (bib24) 1991; 83 Chong, Wong, Fane (bib16) 2008; 314 Shirazi, Lin, Chen (bib1) 2010; 250 Coster, Kim, Dahlan, Smith, Fell (bib11) 1992; 66 Cen, Kavanagh, Coster, Barton (bib13) 2012; 51 T. Knoell, M. Patel, The Challenges of Identifying, Evaluating and Implementing Antiscalants in RO Reuse Applications: So Many Choices—So Few Winners, AWWA Membrane Technology Conference, Long Beach, California, 2011. Sim, Wang, Gu, Coster, Fane (bib15) 2013; 443 Oh, Choung, Lee, Choi, Hwang, Kim (bib19) 2009; 238 Tay, Song (bib7) 2005; 177 Kavanagh, Hussain, Chilcott, Coster (bib10) 2009; 236 Lee, Kim, Lee (bib18) 1999; 163 Uchymiak, Rahardianto, Lyster, Glater, Cohen (bib5) 2007; 291 Bartman, Lyster, Rallo, Christofides, Cohen (bib8) 2011; 273 Antony, Chilcott, Coster, Leslie (bib14) 2013; 425–426 Bramson (10.1016/j.memsci.2013.11.014_bib23) 1995; 100 Antony (10.1016/j.memsci.2013.11.014_bib2) 2011; 383 Uchymiak (10.1016/j.memsci.2013.11.014_bib5) 2007; 291 Tay (10.1016/j.memsci.2013.11.014_bib7) 2005; 177 Pomerantz (10.1016/j.memsci.2013.11.014_bib17) 2006; 45 Coster (10.1016/j.memsci.2013.11.014_bib11) 1992; 66 Shih (10.1016/j.memsci.2013.11.014_bib21) 2005; 252 Cobry (10.1016/j.memsci.2013.11.014_bib6) 2011; 283 Bartman (10.1016/j.memsci.2013.11.014_bib8) 2011; 273 Cen (10.1016/j.memsci.2013.11.014_bib13) 2012; 51 Najibi (10.1016/j.memsci.2013.11.014_bib22) 1997; 52 Lee (10.1016/j.memsci.2013.11.014_bib18) 1999; 163 Kavanagh (10.1016/j.memsci.2013.11.014_bib10) 2009; 236 Chilcott (10.1016/j.memsci.2013.11.014_bib27) 2013; 434 Pääkkönen (10.1016/j.memsci.2013.11.014_bib20) 2012; 55 Sim (10.1016/j.memsci.2013.11.014_bib15) 2013; 443 Pervov (10.1016/j.memsci.2013.11.014_bib24) 1991; 83 Shirazi (10.1016/j.memsci.2013.11.014_bib1) 2010; 250 Chong (10.1016/j.memsci.2013.11.014_bib16) 2008; 314 Park (10.1016/j.memsci.2013.11.014_bib9) 2005; 246 10.1016/j.memsci.2013.11.014_bib3 Uchymiak (10.1016/j.memsci.2013.11.014_bib4) 2009; 341 Okazaki (10.1016/j.memsci.2013.11.014_bib25) 1984; 17 Coster (10.1016/j.memsci.2013.11.014_bib12) 1999; 79 Chilcott (10.1016/j.memsci.2013.11.014_bib26) 2013; 438 Antony (10.1016/j.memsci.2013.11.014_bib14) 2013; 425–426 Oh (10.1016/j.memsci.2013.11.014_bib19) 2009; 238 |
| References_xml | – volume: 438 start-page: 65 year: 2013 end-page: 76 ident: bib26 article-title: Origin of resonant electrical impedances in membranes induced by osmosis: analytical solutions of the AC Nernst–Planck, Poisson and continuity equations as functions of water velocity publication-title: J. Membr. Sci. – volume: 246 start-page: 137 year: 2005 end-page: 144 ident: bib9 article-title: Characterization of BSA-fouling of ion-exchange membrane systems using a subtraction technique for lumped data publication-title: J. Membr. Sci. – volume: 236 start-page: 187 year: 2009 end-page: 193 ident: bib10 article-title: Fouling of reverse osmosis membranes using electrical impedance spectroscopy: measurements and simulations publication-title: Desalination – volume: 17 start-page: 145 year: 1984 end-page: 151 ident: bib25 article-title: Scale formation on reverse osmosis membranes publication-title: J. Chem. Eng. Jpn. – volume: 100 start-page: 105 year: 1995 end-page: 113 ident: bib23 article-title: The roles of gas bubbling, wall crystallization and particulate deposition in CaSO publication-title: Desalination – reference: T. Knoell, M. Patel, The Challenges of Identifying, Evaluating and Implementing Antiscalants in RO Reuse Applications: So Many Choices—So Few Winners, AWWA Membrane Technology Conference, Long Beach, California, 2011. – volume: 79 start-page: 749 year: 1999 end-page: 792 ident: bib12 article-title: The characterization of membranes and membrane surfaces using impedance spectroscopy publication-title: Surfactant Sci. Ser. – volume: 163 start-page: 63 year: 1999 end-page: 74 ident: bib18 article-title: Analysis of CaSO publication-title: J. Membr. Sci. – volume: 238 start-page: 333 year: 2009 end-page: 346 ident: bib19 article-title: Scale formation in reverse osmosis desalination: model development publication-title: Desalination – volume: 434 year: 2013 ident: bib27 article-title: characterization of fouling in reverse osmosis membranes using electrical impedance spectroscopy publication-title: J. Phys. Conf. Ser. – volume: 283 start-page: 40 year: 2011 end-page: 51 ident: bib6 article-title: Comprehensive experimental studies of early-stage membrane scaling during nanofiltration publication-title: Desalination – volume: 45 start-page: 2008 year: 2006 end-page: 2016 ident: bib17 article-title: Prevention of scaling of reverse osmosis membranes by “zeroing” the elapsed nucleation time. Part I. Calcium sulfate publication-title: Ind. Eng. Chem. Res. – volume: 291 start-page: 86 year: 2007 end-page: 95 ident: bib5 article-title: A novel RO ex situ scale observation detector (EXSOD) for mineral scale characterization and early detection publication-title: J. Membr. Sci. – volume: 250 start-page: 236 year: 2010 end-page: 248 ident: bib1 article-title: Inorganic fouling of pressure-driven membrane processes—a critical review publication-title: Desalination – volume: 314 start-page: 101 year: 2008 end-page: 111 ident: bib16 article-title: Implications of critical flux and cake enhanced osmotic pressure (CEOP) on colloidal fouling in reverse osmosis: experimental observations publication-title: J. Membr. Sci. – volume: 273 start-page: 64 year: 2011 end-page: 71 ident: bib8 article-title: Mineral scale monitoring for reverse osmosis desalination via real-time membrane surface image analysis publication-title: Desalination – volume: 52 start-page: 1265 year: 1997 end-page: 1284 ident: bib22 article-title: Calcium sulfate scale formation during subcooled flow boiling publication-title: Chem. Eng. Sci. – volume: 51 start-page: 969 year: 2012 end-page: 975 ident: bib13 article-title: Fouling of reverse osmosis membranes by cane molasses fermentation wastewater: detection by electrical impedance spectroscopy techniques publication-title: Desalination Water Treat. – volume: 252 start-page: 253 year: 2005 end-page: 263 ident: bib21 article-title: Morphometric characterization of calcium sulfate dihydrate (gypsum) scale on reverse osmosis membranes publication-title: J. Membr. Sci. – volume: 383 start-page: 1 year: 2011 end-page: 16 ident: bib2 article-title: Scale formation and control in high pressure membrane water treatment systems: a review publication-title: J. Membr. Sci. – volume: 55 start-page: 6927 year: 2012 end-page: 6937 ident: bib20 article-title: Crystallization fouling of CaCO publication-title: Int. J. Heat Mass Transfer – volume: 66 start-page: 19 year: 1992 end-page: 26 ident: bib11 article-title: Characterisation of ultrafiltration membranes by impedance spectroscopy. I. Determination of the separate electrical parameters and porosity of the skin and sublayers publication-title: J. Membr. Sci. – volume: 83 start-page: 77 year: 1991 end-page: 118 ident: bib24 article-title: Scale formation prognosis and cleaning procedure schedules in reverse osmosis systems operation publication-title: Desalination – volume: 425–426 start-page: 89 year: 2013 end-page: 97 ident: bib14 article-title: structural and functional characterization of reverse osmosis membranes using electrical impedance spectroscopy publication-title: J. Membr. Sci. – volume: 177 start-page: 95 year: 2005 end-page: 107 ident: bib7 article-title: A more effective method for fouling characterization in a full-scale reverse osmosis process publication-title: Desalination – volume: 341 start-page: 60 year: 2009 end-page: 66 ident: bib4 article-title: Brackish water reverse osmosis (BWRO) operation in feed flow reversal mode using an ex situ scale observation detector (EXSOD) publication-title: J. Membr. Sci. – volume: 443 start-page: 45 year: 2013 end-page: 53 ident: bib15 article-title: Detection of reverse osmosis membrane fouling with silica, bovine serum albumin and their mixture using publication-title: J. Membr. Sci. – volume: 425–426 start-page: 89 year: 2013 ident: 10.1016/j.memsci.2013.11.014_bib14 article-title: In situ structural and functional characterization of reverse osmosis membranes using electrical impedance spectroscopy publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2012.09.028 – volume: 434 year: 2013 ident: 10.1016/j.memsci.2013.11.014_bib27 article-title: In situ characterization of fouling in reverse osmosis membranes using electrical impedance spectroscopy publication-title: J. Phys. Conf. Ser. doi: 10.1088/1742-6596/434/1/012089 – volume: 250 start-page: 236 year: 2010 ident: 10.1016/j.memsci.2013.11.014_bib1 article-title: Inorganic fouling of pressure-driven membrane processes—a critical review publication-title: Desalination doi: 10.1016/j.desal.2009.02.056 – volume: 252 start-page: 253 year: 2005 ident: 10.1016/j.memsci.2013.11.014_bib21 article-title: Morphometric characterization of calcium sulfate dihydrate (gypsum) scale on reverse osmosis membranes publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2004.12.023 – volume: 177 start-page: 95 year: 2005 ident: 10.1016/j.memsci.2013.11.014_bib7 article-title: A more effective method for fouling characterization in a full-scale reverse osmosis process publication-title: Desalination doi: 10.1016/j.desal.2004.11.017 – volume: 291 start-page: 86 year: 2007 ident: 10.1016/j.memsci.2013.11.014_bib5 article-title: A novel RO ex situ scale observation detector (EXSOD) for mineral scale characterization and early detection publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2006.12.038 – volume: 443 start-page: 45 year: 2013 ident: 10.1016/j.memsci.2013.11.014_bib15 article-title: Detection of reverse osmosis membrane fouling with silica, bovine serum albumin and their mixture using in-situ electrical impedance spectroscopy publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2013.04.047 – volume: 83 start-page: 77 year: 1991 ident: 10.1016/j.memsci.2013.11.014_bib24 article-title: Scale formation prognosis and cleaning procedure schedules in reverse osmosis systems operation publication-title: Desalination doi: 10.1016/0011-9164(91)85087-B – volume: 236 start-page: 187 year: 2009 ident: 10.1016/j.memsci.2013.11.014_bib10 article-title: Fouling of reverse osmosis membranes using electrical impedance spectroscopy: measurements and simulations publication-title: Desalination doi: 10.1016/j.desal.2007.10.066 – volume: 51 start-page: 969 year: 2012 ident: 10.1016/j.memsci.2013.11.014_bib13 article-title: Fouling of reverse osmosis membranes by cane molasses fermentation wastewater: detection by electrical impedance spectroscopy techniques publication-title: Desalination Water Treat. doi: 10.1080/19443994.2012.714657 – volume: 341 start-page: 60 year: 2009 ident: 10.1016/j.memsci.2013.11.014_bib4 article-title: Brackish water reverse osmosis (BWRO) operation in feed flow reversal mode using an ex situ scale observation detector (EXSOD) publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2009.05.039 – volume: 79 start-page: 749 year: 1999 ident: 10.1016/j.memsci.2013.11.014_bib12 article-title: The characterization of membranes and membrane surfaces using impedance spectroscopy publication-title: Surfactant Sci. Ser. – volume: 314 start-page: 101 year: 2008 ident: 10.1016/j.memsci.2013.11.014_bib16 article-title: Implications of critical flux and cake enhanced osmotic pressure (CEOP) on colloidal fouling in reverse osmosis: experimental observations publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2008.01.030 – volume: 163 start-page: 63 year: 1999 ident: 10.1016/j.memsci.2013.11.014_bib18 article-title: Analysis of CaSO4 scale formation mechanism in various nanofiltration modules publication-title: J. Membr. Sci. doi: 10.1016/S0376-7388(99)00156-8 – volume: 438 start-page: 65 year: 2013 ident: 10.1016/j.memsci.2013.11.014_bib26 article-title: Origin of resonant electrical impedances in membranes induced by osmosis: analytical solutions of the AC Nernst–Planck, Poisson and continuity equations as functions of water velocity publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2013.03.022 – volume: 17 start-page: 145 year: 1984 ident: 10.1016/j.memsci.2013.11.014_bib25 article-title: Scale formation on reverse osmosis membranes publication-title: J. Chem. Eng. Jpn. doi: 10.1252/jcej.17.145 – volume: 66 start-page: 19 year: 1992 ident: 10.1016/j.memsci.2013.11.014_bib11 article-title: Characterisation of ultrafiltration membranes by impedance spectroscopy. I. Determination of the separate electrical parameters and porosity of the skin and sublayers publication-title: J. Membr. Sci. doi: 10.1016/0376-7388(92)80087-Z – volume: 100 start-page: 105 year: 1995 ident: 10.1016/j.memsci.2013.11.014_bib23 article-title: The roles of gas bubbling, wall crystallization and particulate deposition in CaSO4 scale formation publication-title: Desalination doi: 10.1016/0011-9164(96)00012-4 – volume: 273 start-page: 64 year: 2011 ident: 10.1016/j.memsci.2013.11.014_bib8 article-title: Mineral scale monitoring for reverse osmosis desalination via real-time membrane surface image analysis publication-title: Desalination doi: 10.1016/j.desal.2010.10.021 – volume: 238 start-page: 333 year: 2009 ident: 10.1016/j.memsci.2013.11.014_bib19 article-title: Scale formation in reverse osmosis desalination: model development publication-title: Desalination doi: 10.1016/j.desal.2008.10.005 – volume: 283 start-page: 40 year: 2011 ident: 10.1016/j.memsci.2013.11.014_bib6 article-title: Comprehensive experimental studies of early-stage membrane scaling during nanofiltration publication-title: Desalination doi: 10.1016/j.desal.2011.04.053 – volume: 52 start-page: 1265 year: 1997 ident: 10.1016/j.memsci.2013.11.014_bib22 article-title: Calcium sulfate scale formation during subcooled flow boiling publication-title: Chem. Eng. Sci. doi: 10.1016/S0009-2509(96)00505-2 – volume: 246 start-page: 137 year: 2005 ident: 10.1016/j.memsci.2013.11.014_bib9 article-title: Characterization of BSA-fouling of ion-exchange membrane systems using a subtraction technique for lumped data publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2004.07.022 – volume: 383 start-page: 1 year: 2011 ident: 10.1016/j.memsci.2013.11.014_bib2 article-title: Scale formation and control in high pressure membrane water treatment systems: a review publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2011.08.054 – volume: 45 start-page: 2008 year: 2006 ident: 10.1016/j.memsci.2013.11.014_bib17 article-title: Prevention of scaling of reverse osmosis membranes by “zeroing” the elapsed nucleation time. Part I. Calcium sulfate publication-title: Ind. Eng. Chem. Res. doi: 10.1021/ie051040k – volume: 55 start-page: 6927 year: 2012 ident: 10.1016/j.memsci.2013.11.014_bib20 article-title: Crystallization fouling of CaCO3—analysis of experimental thermal resistance and its uncertainty publication-title: Int. J. Heat Mass Transfer doi: 10.1016/j.ijheatmasstransfer.2012.07.006 – ident: 10.1016/j.memsci.2013.11.014_bib3 doi: 10.1179/ida.2011.3.3.12 |
| SSID | ssj0017089 |
| Score | 2.3560336 |
| Snippet | Early detection of scale formation in reverse osmosis systems remains challenging since the bulk measurements of the operating data are not sufficiently... |
| SourceID | proquest pascalfrancis crossref elsevier |
| SourceType | Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 320 |
| SubjectTerms | artificial membranes Calcium sulfate capacitance Chemistry Colloidal state and disperse state Conductance dielectric spectroscopy Electrical impedance spectroscopy Exact sciences and technology filtration Flux General and physical chemistry Membranes Monitoring Real time monitoring Reverse osmosis Scale formation Spectroscopy |
| Title | Real-time monitoring of scale formation in reverse osmosis using electrical impedance spectroscopy |
| URI | https://dx.doi.org/10.1016/j.memsci.2013.11.014 https://www.proquest.com/docview/1751209466 https://www.proquest.com/docview/1800426606 https://www.proquest.com/docview/2101316745 |
| Volume | 453 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1La9wwEBZLekkopXmR7WNRIVdlbUm25WMIDZuW7iEPyE1YlhQcsvYSbw655Ld3RraXhpAEerQYWfaMZjSDZr4h5JCnVtpcGsYT7pj0QjLlQd09uObc-7woQ-e5P_N0diV_XSfXI3Iy1MJgWmVv-zubHqx1PzLtuTldVtX0IkIgEqEUXshA1ICF5lJmuMuPntZpHnEWhTZ4SMyQeiifCzleC7eAV2OClzhCLM9YvnY8fVwWLTDNd90uXhjucBqdfiafejeSHndfuk1Grt4hW_-AC-4Scw4-IMPe8XQRFBeHaeMpruDoumqRVjVFHKf71tGmXTRt1VLMhr-hXYsclCKtwLu2uEFoKM1ECMxm-bhHrk5_Xp7MWN9RgZUy4ysWJw45Ekem4CmW3IpMpLIQHlSZSxsbFQnB8xK8lCKzSRl5oWySecWdSXMvxD7ZqJvaHRAaGetdybENXg5OnVM-lZE1Bg88Kwo1JmJgpC57uHHsenGnh7yyW92xXyP7IRLRwP4xYetZyw5u4x36bJCRfrZtNJwI78ycPBPpejkEoMM4bUx-DDLWoHJ4j1LUrnloNXhcWHEs0_QNGhWiUwgPX6eBaDtGIAKZfPnv3_hKNuFJdllx38jG6v7BfQc3aWUmQQ8m5MPx2e_Z_C9LIBJz |
| linkProvider | Elsevier |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1LT9wwEB7R5dBWFepT3bZQV-rV3cR2EueIUNFSYA8tSNysOLarVN1kRZYD_56ZPFZFFSBxdew4mfG85JlvAL6K1CmXK8tFIjxXQSquA4p7QNdchJAXZdd57nSRzs_Vj4vkYgsOxloYSqscdH-v0zttPYzMBmrOVlU1-xUREInUmi5kMGpInsA2oVMlE9jePzqeLzaXCVnUdcKj-ZwWjBV0XZrX0i_x7ZTjJb8RnGes7rJQL1ZFi3QLfcOL_3R3Z5AOX8LO4Emy_f5jX8GWr1_D83_wBd-A_YluIKf28WzZyS4NsyYw2sGzTeEiq2pGUE6XrWdNu2zaqmWUEP-b9V1yiJGsQgfb0RlhXXUmoWA2q-u3cH74_exgzoemCrxUmVjzOPFEkTiyhUip6lZmMlWFDCjNQrnY6khKkZfoqBSZS8ooSO2SLGjhbZoHKd_BpG5q_x5YZF3wpaBOeDn6dV6HVEXOWrJ5ThZ6CnIkpCkHxHFqfPHXjKllf0xPfkPkx2DEIPmnwDerVj3ixgPzs5FH5tbJMWgUHli5d4ulm-0Ig45CtSl8GXlsUOroKqWofXPVGnS6qOhYpek9c3QXoGKEePccDLhjwiJQyYdH_8ZneDo_Oz0xJ0eL44_wDJ-oPknuE0zWl1d-F72mtd0bpOIGoxwVJA |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Real-time+monitoring+of+scale+formation+in+reverse+osmosis+using+electrical+impedance+spectroscopy&rft.jtitle=Journal+of+membrane+science&rft.au=ZHIXIN+HU&rft.au=ANTONY%2C+Alice&rft.au=LESLIE%2C+Greg&rft.au=LE-CLECH%2C+Pierre&rft.date=2014-03-01&rft.pub=Elsevier&rft.issn=0376-7388&rft.volume=453&rft.spage=320&rft.epage=327&rft_id=info:doi/10.1016%2Fj.memsci.2013.11.014&rft.externalDBID=n%2Fa&rft.externalDocID=28352174 |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0376-7388&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0376-7388&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0376-7388&client=summon |