Enzymatic reactions towards aldehydes: An overview

Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task....

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Published inFlavour and fragrance journal Vol. 38; no. 4; pp. 221 - 242
Main Authors Schober, Lukas, Dobiašová, Hana, Jurkaš, Valentina, Parmeggiani, Fabio, Rudroff, Florian, Winkler, Margit
Format Journal Article
LanguageEnglish
Published England Wiley Subscription Services, Inc 01.07.2023
John Wiley and Sons Inc
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Abstract Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond.
AbstractList Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond.
Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.
Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.
Author Jurkaš, Valentina
Winkler, Margit
Rudroff, Florian
Parmeggiani, Fabio
Schober, Lukas
Dobiašová, Hana
AuthorAffiliation 2 Institute of Chemical and Environmental Engineering Slovak University of Technology Bratislava Slovakia
5 Area Biotransformations Austrian Center of Industrial Biotechnology Graz Austria
3 Dipartimento di Chimica, Materiali ed Ingegneria Chimica “Giulio Natta” Politecnico di Milano Milan Italy
4 Institute of Applied Synthetic Chemistry TU Wien Vienna Austria
1 Institute of Molecular Biotechnology Graz University of Technology Graz Austria
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Issue 4
Keywords green leaf volatiles
aromatic aldehydes
aryl‐aliphatic aldehydes
aldehyde
enzymes
vanillin
aliphatic aldehydes
biocatalysis
Language English
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PublicationDate July 2023
PublicationDateYYYYMMDD 2023-07-01
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  year: 2023
  text: July 2023
PublicationDecade 2020
PublicationPlace England
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PublicationTitle Flavour and fragrance journal
PublicationTitleAlternate Flavour Fragr J
PublicationYear 2023
Publisher Wiley Subscription Services, Inc
John Wiley and Sons Inc
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Snippet Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an...
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SubjectTerms aldehyde
Aldehydes
aliphatic aldehydes
aromatic aldehydes
aryl‐aliphatic aldehydes
biocatalysis
Biocatalysts
Biotransformation
enzymatic reactions
enzymes
flavor
flavorings
Functional groups
green leaf volatiles
odors
Olfactory properties
Review
sorting
vanillin
Volatile compounds
Title Enzymatic reactions towards aldehydes: An overview
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fffj.3739
https://www.ncbi.nlm.nih.gov/pubmed/38505272
https://www.proquest.com/docview/2824659681
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https://pubmed.ncbi.nlm.nih.gov/PMC10947199
Volume 38
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