Enzymatic reactions towards aldehydes: An overview
Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task....
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Published in | Flavour and fragrance journal Vol. 38; no. 4; pp. 221 - 242 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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01.07.2023
John Wiley and Sons Inc |
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Abstract | Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.
Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. |
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AbstractList | Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi‐tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.
Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde‐forming reactions in biological systems and beyond. Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts.Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts. Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an invaluable chemical multi-tool to make all sorts of products. Owing to the reactivity, the selective synthesis of aldehydic is a challenging task. Nature has evolved a number of enzymatic reactions to produce aldehydes, and this review provides an overview of aldehyde-forming reactions in biological systems and beyond. Whereas some of these biotransformations are still in their infancy in terms of synthetic applicability, others are developed to an extent that allows their implementation as industrial biocatalysts. |
Author | Jurkaš, Valentina Winkler, Margit Rudroff, Florian Parmeggiani, Fabio Schober, Lukas Dobiašová, Hana |
AuthorAffiliation | 2 Institute of Chemical and Environmental Engineering Slovak University of Technology Bratislava Slovakia 5 Area Biotransformations Austrian Center of Industrial Biotechnology Graz Austria 3 Dipartimento di Chimica, Materiali ed Ingegneria Chimica “Giulio Natta” Politecnico di Milano Milan Italy 4 Institute of Applied Synthetic Chemistry TU Wien Vienna Austria 1 Institute of Molecular Biotechnology Graz University of Technology Graz Austria |
AuthorAffiliation_xml | – name: 1 Institute of Molecular Biotechnology Graz University of Technology Graz Austria – name: 3 Dipartimento di Chimica, Materiali ed Ingegneria Chimica “Giulio Natta” Politecnico di Milano Milan Italy – name: 4 Institute of Applied Synthetic Chemistry TU Wien Vienna Austria – name: 5 Area Biotransformations Austrian Center of Industrial Biotechnology Graz Austria – name: 2 Institute of Chemical and Environmental Engineering Slovak University of Technology Bratislava Slovakia |
Author_xml | – sequence: 1 givenname: Lukas surname: Schober fullname: Schober, Lukas organization: Graz University of Technology – sequence: 2 givenname: Hana orcidid: 0000-0003-0764-192X surname: Dobiašová fullname: Dobiašová, Hana organization: Slovak University of Technology – sequence: 3 givenname: Valentina orcidid: 0000-0001-7464-240X surname: Jurkaš fullname: Jurkaš, Valentina organization: Graz University of Technology – sequence: 4 givenname: Fabio orcidid: 0000-0001-5861-9269 surname: Parmeggiani fullname: Parmeggiani, Fabio organization: Politecnico di Milano – sequence: 5 givenname: Florian orcidid: 0000-0002-6680-8200 surname: Rudroff fullname: Rudroff, Florian organization: TU Wien – sequence: 6 givenname: Margit orcidid: 0000-0002-0754-9704 surname: Winkler fullname: Winkler, Margit email: margitwinkler@acib.at organization: Austrian Center of Industrial Biotechnology |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38505272$$D View this record in MEDLINE/PubMed |
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CitedBy_id | crossref_primary_10_1016_j_jbiotec_2024_04_004 crossref_primary_10_2174_0113892002325954240903062440 crossref_primary_10_1016_j_biotechadv_2025_108531 crossref_primary_10_1021_acs_energyfuels_4c00277 crossref_primary_10_1021_acs_jafc_3c04530 crossref_primary_10_3390_molecules29204878 crossref_primary_10_3390_ijms26052373 crossref_primary_10_3390_catal14110767 crossref_primary_10_1002_chem_202402469 crossref_primary_10_1080_07391102_2024_2424946 crossref_primary_10_1039_D3GC04191C crossref_primary_10_1021_acssuschemeng_4c07133 crossref_primary_10_1111_asj_70045 crossref_primary_10_3390_org5040021 |
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Keywords | green leaf volatiles aromatic aldehydes aryl‐aliphatic aldehydes aldehyde enzymes vanillin aliphatic aldehydes biocatalysis |
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Snippet | Many aldehydes are volatile compounds with distinct and characteristic olfactory properties. The aldehydic functional group is reactive and, as such, an... |
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SubjectTerms | aldehyde Aldehydes aliphatic aldehydes aromatic aldehydes aryl‐aliphatic aldehydes biocatalysis Biocatalysts Biotransformation enzymatic reactions enzymes flavor flavorings Functional groups green leaf volatiles odors Olfactory properties Review sorting vanillin Volatile compounds |
Title | Enzymatic reactions towards aldehydes: An overview |
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