A low trans margarine fat analog to beef tallow for healthier formulations: Optimization of enzymatic interesterification using soybean oil and fully hydrogenated palm oil

•Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils. The health hazard of tallow and partial h...

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Published inFood chemistry Vol. 255; pp. 405 - 413
Main Authors Li, Ying, Zhao, Jinli, Xie, Xiaodong, Zhang, Zhen, Zhang, Ning, Wang, Yong
Format Journal Article
LanguageEnglish
Published England Elsevier Ltd 30.07.2018
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Abstract •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils. The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs.
AbstractList •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils. The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs.
The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs.
Author Zhao, Jinli
Li, Ying
Xie, Xiaodong
Wang, Yong
Zhang, Zhen
Zhang, Ning
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  givenname: Zhen
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  email: twyong@jnu.edu.cn
  organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China
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Keywords Characterization
Low trans margarine fat analog
Enzymatic interesterification
Beef tallow
Box-Behnken design
Language English
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Snippet •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken...
The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel...
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StartPage 405
SubjectTerms Beef tallow
Box-Behnken design
Characterization
Enzymatic interesterification
Esterification
Fats - chemistry
Hydrogenation
Lipase - metabolism
Low trans margarine fat analog
Margarine - analysis
Palm Oil - chemistry
Soybean Oil - chemistry
Trans Fatty Acids - chemistry
Triglycerides
Title A low trans margarine fat analog to beef tallow for healthier formulations: Optimization of enzymatic interesterification using soybean oil and fully hydrogenated palm oil
URI https://dx.doi.org/10.1016/j.foodchem.2018.02.086
https://www.ncbi.nlm.nih.gov/pubmed/29571493
https://search.proquest.com/docview/2018024825
Volume 255
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