A low trans margarine fat analog to beef tallow for healthier formulations: Optimization of enzymatic interesterification using soybean oil and fully hydrogenated palm oil
•Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils. The health hazard of tallow and partial h...
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Published in | Food chemistry Vol. 255; pp. 405 - 413 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
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England
Elsevier Ltd
30.07.2018
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Abstract | •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils.
The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs. |
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AbstractList | •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken design.•The interesterified oil was characterized as an alternative to beef tallow and hydrogenated oils.
The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs. The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel alternatives for healthier margarine formulations. The highest interesterification degree acquired with lipase Lipozyme 435 standing out from other catalysts (solid acid, sodium hydroxide and methoxide) was applied to produce low trans margarine fat analogs to beef tallow (BT) with the blend of soybean oil (SO) and fully hydrogenated palm oil (FHPO) in a mass ratio of 4:3. Reaction parameters like enzyme dosage (4.2 wt%), temperature (95 °C) and time (245 min) were optimized using the Box-Behnken design. Regarding fatty acid profiles, triacylglycerol species, solid fat content, polymorphism, melting and crystallization behaviors, the resulting interesterified oil was characterized in comparison with BT, FHPO and the SO-FHPO blend so as to prove its potential in formulating low trans fat margarines because of desirable physicochemical properties and polymorphs. |
Author | Zhao, Jinli Li, Ying Xie, Xiaodong Wang, Yong Zhang, Zhen Zhang, Ning |
Author_xml | – sequence: 1 givenname: Ying surname: Li fullname: Li, Ying organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China – sequence: 2 givenname: Jinli surname: Zhao fullname: Zhao, Jinli organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China – sequence: 3 givenname: Xiaodong surname: Xie fullname: Xie, Xiaodong organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China – sequence: 4 givenname: Zhen surname: Zhang fullname: Zhang, Zhen organization: Guangdong Engineering Technology Research Center for Oils and Fats Biorefinery, Guangdong Engineering Technology Research Center for Cereals and Oils Byproducts Biorefinery, Guangzhou 510632, China – sequence: 5 givenname: Ning surname: Zhang fullname: Zhang, Ning email: tzhning@jnu.edu.cn organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China – sequence: 6 givenname: Yong surname: Wang fullname: Wang, Yong email: twyong@jnu.edu.cn organization: Department of Food Science and Engineering, College of Science and Engineering, Jinan University, Guangzhou 510632, China |
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Keywords | Characterization Low trans margarine fat analog Enzymatic interesterification Beef tallow Box-Behnken design |
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Snippet | •Soybean oil and fully hydrogenated palm oil synthesized low trans margarine fat analogs.•The enzymatic interesterification was optimized by Box-Behnken... The health hazard of tallow and partial hydrogenated oils is well known in margarine productions. For this, food manufactures are urged to develop novel... |
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SubjectTerms | Beef tallow Box-Behnken design Characterization Enzymatic interesterification Esterification Fats - chemistry Hydrogenation Lipase - metabolism Low trans margarine fat analog Margarine - analysis Palm Oil - chemistry Soybean Oil - chemistry Trans Fatty Acids - chemistry Triglycerides |
Title | A low trans margarine fat analog to beef tallow for healthier formulations: Optimization of enzymatic interesterification using soybean oil and fully hydrogenated palm oil |
URI | https://dx.doi.org/10.1016/j.foodchem.2018.02.086 https://www.ncbi.nlm.nih.gov/pubmed/29571493 https://search.proquest.com/docview/2018024825 |
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