Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra

Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4]...

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Published inMolecules (Basel, Switzerland) Vol. 28; no. 13; p. 5068
Main Authors Li, Jing-Jing, Chen, Wei-Feng, Lan, You-Zhao, Cheng, Jian-Wen
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 28.06.2023
MDPI
Subjects
borate
Boron
edge-sharing
fundamental building blocks
Review
structural chemistry
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Abstract Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4] tetrahedra, while the KZnB3O6 is the first ambient pressure borate with the edge-sharing [BO4] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO4] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.
AbstractList Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is considered a basic rule in borate structural chemistry. The Dy 4 B 6 O 15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO 4 ] tetrahedra, while the KZnB 3 O 6 is the first ambient pressure borate with the edge-sharing [BO 4 ] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO 4 ] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.
Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4] tetrahedra, while the KZnB3O6 is the first ambient pressure borate with the edge-sharing [BO4] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO4] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.
Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B-O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4] tetrahedra, while the KZnB3O6 is the first ambient pressure borate with the edge-sharing [BO4] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO4] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B-O unit is considered a basic rule in borate structural chemistry. The Dy4B6O15 synthesized under high-pressure is the first oxoborate with edge-sharing [BO4] tetrahedra, while the KZnB3O6 is the first ambient pressure borate with the edge-sharing [BO4] tetrahedra. The edge-sharing connection modes greatly enrich the structural chemistry of borates and are expected to expand new applications in the future. In this review, we summarize the recent progress in crystalline borates with edge-sharing [BO4] tetrahedra. We discuss the synthesis, fundamental building blocks, structural features, and possible applications of these edge-sharing borates. Finally, we also discuss the future perspectives in this field.
Author Lan, You-Zhao
Cheng, Jian-Wen
Li, Jing-Jing
Chen, Wei-Feng
AuthorAffiliation Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China
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SecondaryResourceType review_article
Snippet Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B–O unit is...
Crystalline borates have received great attention due to their various structures and wide applications. For a long time, the corner-sharing B-O unit is...
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SubjectTerms borate
Boron
edge-sharing
fundamental building blocks
Review
structural chemistry
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Title Recent Progress in Crystalline Borates with Edge-Sharing BO4 Tetrahedra
URI https://www.proquest.com/docview/2836363724
https://www.proquest.com/docview/2838246167
https://pubmed.ncbi.nlm.nih.gov/PMC10343378
https://doaj.org/article/2b666f86232140708b7f53797299a22c
Volume 28
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