Boosting the Activation of Molecular Oxygen and the Degradation of Rhodamine B in Polar-Functional-Group-Modified g-C3N4
Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C3N4) with abundant hydroxyl groups (HCN) was s...
Saved in:
| Published in | Molecules (Basel, Switzerland) Vol. 29; no. 16; p. 3836 |
|---|---|
| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Basel
MDPI AG
13.08.2024
MDPI |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1420-3049 1420-3049 |
| DOI | 10.3390/molecules29163836 |
Cover
Loading…
| Abstract | Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C3N4) with abundant hydroxyl groups (HCN) was synthesized to investigate the relationship between these polar groups and molecular oxygen activation. The advantage of the hydroxyl group modification of g-C3N4 included narrower interlayer distances, a larger specific surface area and improved hydrophilicity. Various photoelectronic measurements revealed that the introduced hydroxyl groups reduced the charge transfer resistance of HCN, resulting in accelerated charge separation and migration kinetics. Therefore, the optimal HCN-90 showed the highest activity for Rhodamine B photodegradation with a reaction time of 30 min and an apparent rate constant of 0.125 min−1, surpassing most other g-C3N4 composites. This enhanced activity was attributed to the adjusted band structure achieved through polar functional group modification. The modification of polar functional groups could alter the energy band structure of photocatalysts, narrow band gap, enhance visible-light absorption, and improve photogenerated carrier separation efficiency. This work highlights the significant potential of polar functional groups in tuning the structure of g-C3N4 to enhance efficient molecular oxygen activation. |
|---|---|
| AbstractList | Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C3N4) with abundant hydroxyl groups (HCN) was synthesized to investigate the relationship between these polar groups and molecular oxygen activation. The advantage of the hydroxyl group modification of g-C3N4 included narrower interlayer distances, a larger specific surface area and improved hydrophilicity. Various photoelectronic measurements revealed that the introduced hydroxyl groups reduced the charge transfer resistance of HCN, resulting in accelerated charge separation and migration kinetics. Therefore, the optimal HCN-90 showed the highest activity for Rhodamine B photodegradation with a reaction time of 30 min and an apparent rate constant of 0.125 min−1, surpassing most other g-C3N4 composites. This enhanced activity was attributed to the adjusted band structure achieved through polar functional group modification. The modification of polar functional groups could alter the energy band structure of photocatalysts, narrow band gap, enhance visible-light absorption, and improve photogenerated carrier separation efficiency. This work highlights the significant potential of polar functional groups in tuning the structure of g-C3N4 to enhance efficient molecular oxygen activation. Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C 3 N 4 ) with abundant hydroxyl groups (HCN) was synthesized to investigate the relationship between these polar groups and molecular oxygen activation. The advantage of the hydroxyl group modification of g-C 3 N 4 included narrower interlayer distances, a larger specific surface area and improved hydrophilicity. Various photoelectronic measurements revealed that the introduced hydroxyl groups reduced the charge transfer resistance of HCN, resulting in accelerated charge separation and migration kinetics. Therefore, the optimal HCN-90 showed the highest activity for Rhodamine B photodegradation with a reaction time of 30 min and an apparent rate constant of 0.125 min −1 , surpassing most other g-C 3 N 4 composites. This enhanced activity was attributed to the adjusted band structure achieved through polar functional group modification. The modification of polar functional groups could alter the energy band structure of photocatalysts, narrow band gap, enhance visible-light absorption, and improve photogenerated carrier separation efficiency. This work highlights the significant potential of polar functional groups in tuning the structure of g-C 3 N 4 to enhance efficient molecular oxygen activation. Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C3N4) with abundant hydroxyl groups (HCN) was synthesized to investigate the relationship between these polar groups and molecular oxygen activation. The advantage of the hydroxyl group modification of g-C3N4 included narrower interlayer distances, a larger specific surface area and improved hydrophilicity. Various photoelectronic measurements revealed that the introduced hydroxyl groups reduced the charge transfer resistance of HCN, resulting in accelerated charge separation and migration kinetics. Therefore, the optimal HCN-90 showed the highest activity for Rhodamine B photodegradation with a reaction time of 30 min and an apparent rate constant of 0.125 min-1, surpassing most other g-C3N4 composites. This enhanced activity was attributed to the adjusted band structure achieved through polar functional group modification. The modification of polar functional groups could alter the energy band structure of photocatalysts, narrow band gap, enhance visible-light absorption, and improve photogenerated carrier separation efficiency. This work highlights the significant potential of polar functional groups in tuning the structure of g-C3N4 to enhance efficient molecular oxygen activation.Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key challenge for advancing green molecular oxygen activation. Herein, graphitic carbon nitride (g-C3N4) with abundant hydroxyl groups (HCN) was synthesized to investigate the relationship between these polar groups and molecular oxygen activation. The advantage of the hydroxyl group modification of g-C3N4 included narrower interlayer distances, a larger specific surface area and improved hydrophilicity. Various photoelectronic measurements revealed that the introduced hydroxyl groups reduced the charge transfer resistance of HCN, resulting in accelerated charge separation and migration kinetics. Therefore, the optimal HCN-90 showed the highest activity for Rhodamine B photodegradation with a reaction time of 30 min and an apparent rate constant of 0.125 min-1, surpassing most other g-C3N4 composites. This enhanced activity was attributed to the adjusted band structure achieved through polar functional group modification. The modification of polar functional groups could alter the energy band structure of photocatalysts, narrow band gap, enhance visible-light absorption, and improve photogenerated carrier separation efficiency. This work highlights the significant potential of polar functional groups in tuning the structure of g-C3N4 to enhance efficient molecular oxygen activation. |
| Author | Liu, Zhenguo Chen, Yuxin Yu, Ruohan Yang, Minghua Ji, Yujie Zhang, Hongjiao Chen, Jing |
| AuthorAffiliation | 4 School of Flexible Electronics and Henan Institute of Flexible Electronics, Henan University, Zhengzhou 450046, China 1 Key Laboratory of Flexible Electronics of Zhejiang Province, Ningbo Institute of Northwestern Polytechnical University, Ningbo 315103, China 3 Department of Chemistry, Lishui University, 1 Xueyuan Road, Lishui 323000, China; chenyuxin@lsu.edu.cn (Y.C.); jiyujie@lsu.edu.cn (Y.J.); yuruohan@lsu.edu.cn (R.Y.) 2 Department of Chemical and Material Engineering, Quzhou College of Technology, Quzhou 324002, China; yangmh@qzct.edu.cn (M.Y.); zhanghongjiao@qzct.edu.cn (H.Z.) |
| AuthorAffiliation_xml | – name: 3 Department of Chemistry, Lishui University, 1 Xueyuan Road, Lishui 323000, China; chenyuxin@lsu.edu.cn (Y.C.); jiyujie@lsu.edu.cn (Y.J.); yuruohan@lsu.edu.cn (R.Y.) – name: 1 Key Laboratory of Flexible Electronics of Zhejiang Province, Ningbo Institute of Northwestern Polytechnical University, Ningbo 315103, China – name: 2 Department of Chemical and Material Engineering, Quzhou College of Technology, Quzhou 324002, China; yangmh@qzct.edu.cn (M.Y.); zhanghongjiao@qzct.edu.cn (H.Z.) – name: 4 School of Flexible Electronics and Henan Institute of Flexible Electronics, Henan University, Zhengzhou 450046, China |
| Author_xml | – sequence: 1 givenname: Jing surname: Chen fullname: Chen, Jing – sequence: 2 givenname: Minghua orcidid: 0009-0007-9734-4780 surname: Yang fullname: Yang, Minghua – sequence: 3 givenname: Hongjiao surname: Zhang fullname: Zhang, Hongjiao – sequence: 4 givenname: Yuxin surname: Chen fullname: Chen, Yuxin – sequence: 5 givenname: Yujie surname: Ji fullname: Ji, Yujie – sequence: 6 givenname: Ruohan surname: Yu fullname: Yu, Ruohan – sequence: 7 givenname: Zhenguo surname: Liu fullname: Liu, Zhenguo |
| BookMark | eNp1kktv3CAURq0qlZqk_QHdIXXTjRPggm1WVTJtHlLSVFWyRpiHh5ENU7Cj5N_HM5NWTaquQHC-A1zuQbEXYrBF8ZHgIwCBj4fYWz31NlNBKmigelPsE0ZxCZiJvb_m74qDnFcYU8II3y8eTmPMow8dGpcWnejR36vRx4CiQ9c7p0ro5uGxswGpYLbYV9slZf5wP5fRqMEHi06RD-hHnCPl2RT0BlB9eZ7itC6vo_HOW4O6cgHf2fvirVN9th-ex8Pi7uzb7eKivLo5v1ycXJWa1WQsuW4qbRnmlcMtGNpQV_HaEi0IIUpZ4WpemxaAcAYYHChnWsxaYJqaijVwWFzuvCaqlVwnP6j0KKPycrsQUydVGr3urayVozVlHABvTmyEc5hRMDAXTwtTz64vO9d6agdrtA1jUv0L6cud4Jeyi_eSEOBVI-hs-PxsSPHXZPMoB5-17XsVbJyyBCxELRghfEY_vUJXcUpzPbdUgznlFGaq3lE6xZyTdVL7cfsz8wV8LwmWm_6Q__THnCSvkr_f8f_MEwhfwqE |
| CitedBy_id | crossref_primary_10_1016_j_greeac_2025_100230 |
| Cites_doi | 10.1021/acscatal.6b03334 10.1016/j.apcatb.2017.02.083 10.1021/acsami.2c19906 10.1016/j.apsusc.2017.07.282 10.1016/j.envres.2024.119484 10.1016/j.cej.2020.126978 10.1016/j.chemosphere.2020.127675 10.1002/adma.202107668 10.1016/j.jcis.2013.03.034 10.1016/j.apcatb.2015.08.002 10.1016/j.apsusc.2021.151140 10.1016/j.cej.2021.133927 10.1016/j.wri.2023.100220 10.1016/j.apsusc.2020.148132 10.1039/c1jm12620b 10.1016/j.cej.2019.05.175 10.1016/j.jelechem.2024.118072 10.1007/s43630-021-00019-9 10.1016/j.clay.2022.106432 10.1016/j.bios.2013.12.039 10.1016/j.jpcs.2020.109900 10.1007/s10876-022-02402-7 10.1016/j.apcatb.2022.121329 10.1002/adma.201503448 10.1016/j.apsusc.2015.03.086 10.1039/C5TA05128B 10.1016/j.nanoen.2018.05.053 10.1021/acsami.6b10516 10.1002/adfm.202001502 10.1016/j.seppur.2020.116618 10.1016/j.nanoen.2021.105869 10.1002/adfm.201503221 10.1039/C4CP05020G 10.1016/j.apcatb.2019.118581 10.1016/j.jece.2024.112547 10.1016/j.jclepro.2021.130039 10.1039/D3GC04163H 10.1016/j.apcatb.2018.10.057 10.1021/ja4092903 10.1021/la900923z 10.1016/j.cej.2021.129915 10.1016/j.solener.2024.112316 10.1016/j.cej.2023.144521 10.3390/polym12091963 10.1016/j.apcatb.2012.09.031 10.1016/j.colsurfa.2023.132624 10.1002/anie.202111769 10.1016/j.apcatb.2022.121611 10.1021/ar500412p 10.1016/j.flatc.2021.100277 10.1016/j.apcatb.2020.119637 10.1039/C4TA04041D 10.1002/smll.202300109 10.1038/s41467-020-20521-5 10.1016/j.electacta.2016.12.077 10.1039/D1CS00242B 10.1002/adfm.202102315 10.1016/j.cej.2022.139191 10.1016/j.apcatb.2020.119742 10.1002/smll.201603938 10.1021/jp200953k 10.1007/s10311-018-0814-8 |
| ContentType | Journal Article |
| Copyright | 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. 2024 by the authors. 2024 |
| Copyright_xml | – notice: 2024 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: 2024 by the authors. 2024 |
| DBID | AAYXX CITATION 3V. 7X7 7XB 88E 8FI 8FJ 8FK ABUWG AFKRA AZQEC BENPR CCPQU DWQXO FYUFA GHDGH K9. M0S M1P PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQQKQ PQUKI PRINS 7X8 5PM DOA |
| DOI | 10.3390/molecules29163836 |
| DatabaseName | CrossRef ProQuest Central (Corporate) Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni Edition) ProQuest Central UK/Ireland ProQuest Central Essentials ProQuest Central ProQuest One Community College ProQuest Central Korea Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Health & Medical Complete (Alumni) Health & Medical Collection (Alumni Edition) Medical Database ProQuest Central Premium ProQuest One Academic (New) Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) ProQuest One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central China MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef Publicly Available Content Database ProQuest One Academic Middle East (New) ProQuest Central Essentials ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest One Health & Nursing ProQuest Central China ProQuest Central Health Research Premium Collection Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Health & Medical Research Collection ProQuest Central (New) ProQuest Medical Library (Alumni) ProQuest One Academic Eastern Edition ProQuest Hospital Collection Health Research Premium Collection (Alumni) ProQuest Hospital Collection (Alumni) ProQuest Health & Medical Complete ProQuest Medical Library ProQuest One Academic UKI Edition ProQuest One Academic ProQuest One Academic (New) ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | Publicly Available Content Database MEDLINE - Academic CrossRef |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: BENPR name: ProQuest Central - New (Subscription) url: https://www.proquest.com/central sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1420-3049 |
| ExternalDocumentID | oai_doaj_org_article_7af27245330e40589ff0423d3142c9d7 PMC11356892 10_3390_molecules29163836 |
| GrantInformation_xml | – fundername: Fundamental Research Funds of Lishui grantid: 2023GYX46 – fundername: Key Research and Development Projects of Quzhou grantid: 2023K259 – fundername: “Pioneer” and “Leading Goose” R&D programs of Zhejiang grantid: 2024C01251(SD2) – fundername: Key R&D Special Project of He’nan grantid: 231111232500 – fundername: MIIT Dedicated Program grantid: TC220A04A-206 |
| GroupedDBID | --- 0R~ 123 2WC 53G 5VS 7X7 88E 8FE 8FG 8FH 8FI 8FJ A8Z AADQD AAFWJ AAHBH AAYXX ABDBF ABUWG ACGFO ACIWK ACPRK ACUHS AEGXH AENEX AFKRA AFPKN AFRAH AFZYC AIAGR ALIPV ALMA_UNASSIGNED_HOLDINGS BENPR BPHCQ BVXVI CCPQU CITATION CS3 D1I DIK DU5 E3Z EBD EMOBN ESX FYUFA GROUPED_DOAJ GX1 HH5 HMCUK HYE HZ~ I09 IAO IHR ITC KQ8 LK8 M1P MODMG O-U O9- OK1 P2P PHGZM PHGZT PIMPY PQQKQ PROAC PSQYO RPM SV3 TR2 TUS UKHRP ~8M 3V. 7XB 8FK AZQEC DWQXO K9. PJZUB PKEHL PPXIY PQEST PQUKI PRINS 7X8 5PM PUEGO |
| ID | FETCH-LOGICAL-c471t-5c86ce4056f0b3d282f657e1c9111aae9f757db33154303f3afdb04b34c2d6483 |
| IEDL.DBID | 7X7 |
| ISSN | 1420-3049 |
| IngestDate | Wed Aug 27 01:10:20 EDT 2025 Thu Aug 21 18:32:10 EDT 2025 Fri Jul 11 11:34:52 EDT 2025 Sat Jul 26 02:35:50 EDT 2025 Thu Apr 24 22:57:45 EDT 2025 Tue Jul 01 03:59:59 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 16 |
| Language | English |
| License | https://creativecommons.org/licenses/by/4.0 Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c471t-5c86ce4056f0b3d282f657e1c9111aae9f757db33154303f3afdb04b34c2d6483 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| ORCID | 0009-0007-9734-4780 |
| OpenAccessLink | https://www.proquest.com/docview/3098052523?pq-origsite=%requestingapplication% |
| PQID | 3098052523 |
| PQPubID | 2032355 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_7af27245330e40589ff0423d3142c9d7 pubmedcentral_primary_oai_pubmedcentral_nih_gov_11356892 proquest_miscellaneous_3099794115 proquest_journals_3098052523 crossref_citationtrail_10_3390_molecules29163836 crossref_primary_10_3390_molecules29163836 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 20240813 |
| PublicationDateYYYYMMDD | 2024-08-13 |
| PublicationDate_xml | – month: 8 year: 2024 text: 20240813 day: 13 |
| PublicationDecade | 2020 |
| PublicationPlace | Basel |
| PublicationPlace_xml | – name: Basel |
| PublicationTitle | Molecules (Basel, Switzerland) |
| PublicationYear | 2024 |
| Publisher | MDPI AG MDPI |
| Publisher_xml | – name: MDPI AG – name: MDPI |
| References | Yu (ref_9) 2023; 25 Ali (ref_61) 2021; 570 Chen (ref_60) 2022; 218 Sun (ref_20) 2023; 15 ref_58 Yan (ref_40) 2009; 25 (ref_4) 2021; 405 Liu (ref_41) 2011; 21 Liu (ref_53) 2020; 244 Sharmoukh (ref_5) 2023; 34 Li (ref_15) 2021; 421 Tan (ref_22) 2021; 262 Yu (ref_27) 2018; 50 Xie (ref_45) 2020; 265 Zhao (ref_12) 2013; 135 Li (ref_32) 2014; 55 Ming (ref_34) 2014; 2 Wang (ref_33) 2017; 224 Zhang (ref_48) 2022; 34 Mohod (ref_1) 2023; 30 Johnson (ref_51) 2016; 181 Liang (ref_47) 2015; 25 Huang (ref_57) 2021; 538 Huang (ref_50) 2019; 374 Li (ref_19) 2021; 283 Luo (ref_37) 2021; 284 Zanaty (ref_7) 2024; 12 Xiang (ref_43) 2011; 115 Wang (ref_6) 2024; 956 You (ref_36) 2022; 431 Anglada (ref_13) 2015; 48 Ma (ref_55) 2018; 430 Dong (ref_42) 2013; 401 Kumar (ref_17) 2018; 17 Wang (ref_24) 2023; 19 Tran (ref_56) 2021; 151 Bu (ref_30) 2016; 8 Moon (ref_35) 2017; 7 Merschjann (ref_38) 2015; 27 Zhan (ref_11) 2022; 310 Meng (ref_54) 2017; 210 Wang (ref_21) 2023; 471 Li (ref_26) 2016; 4 Teo (ref_2) 2022; 332 Feng (ref_44) 2020; 30 Ghanbari (ref_62) 2024; 268 Zhang (ref_16) 2024; 680 Che (ref_25) 2021; 60 Zhu (ref_39) 2015; 344 Ben (ref_14) 2021; 31 Che (ref_18) 2022; 316 Li (ref_28) 2023; 452 Yang (ref_49) 2019; 243 She (ref_29) 2021; 84 Li (ref_31) 2015; 17 Shi (ref_52) 2021; 20 Fu (ref_46) 2017; 13 Li (ref_8) 2013; 129 Ajiboye (ref_3) 2021; 29 Tang (ref_10) 2021; 50 Huang (ref_23) 2021; 12 Dharani (ref_59) 2024; 258 |
| References_xml | – volume: 7 start-page: 2886 year: 2017 ident: ref_35 article-title: Eco-Friendly Photochemical Production of H2O2 through O2 Reduction over Carbon Nitride Frameworks Incorporated with Multiple Heteroelements publication-title: ACS Catal. doi: 10.1021/acscatal.6b03334 – volume: 210 start-page: 160 year: 2017 ident: ref_54 article-title: MoS2 quantum dots-interspersed Bi2WO6 heterostructures for visible light-induced detoxification and disinfection publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2017.02.083 – volume: 15 start-page: 12957 year: 2023 ident: ref_20 article-title: Engineering Z-Scheme FeOOH/PCN with Fast Photoelectron Transfer and Surface Redox Kinetics for Efficient Solar-Driven CO2 Reduction publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.2c19906 – volume: 430 start-page: 263 year: 2018 ident: ref_55 article-title: Synthesis of core-shell TiO2@g-C3N4 hollow microspheres for efficient photocatalytic degradation of rhodamine B under visible light publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2017.07.282 – volume: 258 start-page: 119484 year: 2024 ident: ref_59 article-title: Photodegrading rhodamine B dye with cobalt ferrite-graphitic carbon nitride (CoFe2O4/g-C3N4) composite publication-title: Environ. Res. doi: 10.1016/j.envres.2024.119484 – volume: 405 start-page: 126978 year: 2021 ident: ref_4 article-title: Use of modified flotation cell as ozonation reactor to minimize mass transfer limitations publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2020.126978 – volume: 262 start-page: 127675 year: 2021 ident: ref_22 article-title: Graphitic carbon nitride-based materials in activating persulfate for aqueous organic pollutants degradation: A review on materials design and mechanisms publication-title: Chemosphere doi: 10.1016/j.chemosphere.2020.127675 – volume: 34 start-page: e2107668 year: 2022 ident: ref_48 article-title: Emerging S-Scheme Photocatalyst publication-title: Adv. Mater. doi: 10.1002/adma.202107668 – volume: 401 start-page: 70 year: 2013 ident: ref_42 article-title: Engineering the nanoarchitecture and texture of polymeric carbon nitride semiconductor for enhanced visible light photocatalytic activity publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2013.03.034 – volume: 181 start-page: 517 year: 2016 ident: ref_51 article-title: Comparing the degradation of acetochlor to RhB using BiOBr under visible light: A significantly different rate-catalyst dose relationship publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2015.08.002 – volume: 570 start-page: 151140 year: 2021 ident: ref_61 article-title: Synergetic performance of systematically designed g-C3N4/rGO/SnO2 nanocomposite for photodegradation of Rhodamine-B dye publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2021.151140 – volume: 431 start-page: 133927 year: 2022 ident: ref_36 article-title: Self-assembled graphitic carbon nitride regulated by carbon quantum dots with optimized electronic band structure for enhanced photocatalytic degradation of diclofenac publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.133927 – volume: 30 start-page: 100220 year: 2023 ident: ref_1 article-title: Degradation of Rhodamine dyes by Advanced Oxidation Processes (AOPs)—Focus on cavitation and photocatalysis—A critical review publication-title: Water Resour. Ind. doi: 10.1016/j.wri.2023.100220 – volume: 538 start-page: 148132 year: 2021 ident: ref_57 article-title: In situ fabrication of ultrathin-g-C3N4/AgI heterojunctions with improved catalytic performance for photodegrading rhodamine B solution publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2020.148132 – volume: 21 start-page: 14398 year: 2011 ident: ref_41 article-title: Simple pyrolysis of urea into graphitic carbon nitride with recyclable adsorption and photocatalytic activity publication-title: J. Mater. Chem. doi: 10.1039/c1jm12620b – volume: 374 start-page: 242 year: 2019 ident: ref_50 article-title: An efficient metal-free phosphorus and oxygen co-doped g-C3N4 photocatalyst with enhanced visible light photocatalytic activity for the degradation of fluoroquinolone antibiotics publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2019.05.175 – volume: 956 start-page: 118072 year: 2024 ident: ref_6 article-title: CuCO2O4/CF cathode with bifunctional and dual reaction centers exhibits high RhB degradation in electro-Fenton systems publication-title: J. Electroanal. Chem. doi: 10.1016/j.jelechem.2024.118072 – volume: 20 start-page: 303 year: 2021 ident: ref_52 article-title: pH-controlled mechanism of photocatalytic RhB degradation over g-C3N4 under sunlight irradiation publication-title: Photochem. Photobiol. Sci. doi: 10.1007/s43630-021-00019-9 – volume: 218 start-page: 106432 year: 2022 ident: ref_60 article-title: Montmorillonite induced assembly of multi-element doped g-C3N4 nanosheets with enhanced activity for Rhodamine B photodegradation publication-title: Appl. Clay Sci. doi: 10.1016/j.clay.2022.106432 – volume: 55 start-page: 330 year: 2014 ident: ref_32 article-title: Cathodic electrochemiluminescence immunosensor based on nanocomposites of semiconductor carboxylated g-C3N4 and graphene for the ultrasensitive detection of squamous cell carcinoma antigen publication-title: Biosens. Bioelectron. doi: 10.1016/j.bios.2013.12.039 – volume: 151 start-page: 109900 year: 2021 ident: ref_56 article-title: One-step synthesis of oxygen doped g-C3N4 for enhanced visible-light photodegradation of Rhodamine B publication-title: J. Phys. Chem. Solids doi: 10.1016/j.jpcs.2020.109900 – volume: 34 start-page: 2509 year: 2023 ident: ref_5 article-title: Fenton-like Cerium Metal—Organic Frameworks (Ce-MOFs) for Catalytic Oxidation of Olefins, Alcohol, and Dyes Degradation publication-title: J. Clust. Sci. doi: 10.1007/s10876-022-02402-7 – volume: 310 start-page: 121329 year: 2022 ident: ref_11 article-title: Photocatalytic O2 activation and reactive oxygen species evolution by surface B-N bond for organic pollutants degradation publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2022.121329 – volume: 27 start-page: 7993 year: 2015 ident: ref_38 article-title: Complementing Graphenes: 1D Interplanar Charge Transport in Polymeric Graphitic Carbon Nitrides publication-title: Adv. Mater. doi: 10.1002/adma.201503448 – volume: 344 start-page: 188 year: 2015 ident: ref_39 article-title: Isoelectric point and adsorption activity of porous g-C3N4 publication-title: Appl. Surf. Sci. doi: 10.1016/j.apsusc.2015.03.086 – volume: 4 start-page: 2943 year: 2016 ident: ref_26 article-title: In situ surface alkalinized g-C3N4 toward enhancement of photocatalytic H2 evolution under visible-light irradiation publication-title: J. Mater. Chem. A doi: 10.1039/C5TA05128B – volume: 50 start-page: 383 year: 2018 ident: ref_27 article-title: Local spatial charge separation and proton activation induced by surface hydroxylation promoting photocatalytic hydrogen evolution of polymeric carbon nitride publication-title: Nano Energy doi: 10.1016/j.nanoen.2018.05.053 – volume: 8 start-page: 31419 year: 2016 ident: ref_30 article-title: Surface Modification of C3N4 through Oxygen-Plasma Treatment: A Simple Way toward Excellent Hydrophilicity publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.6b10516 – volume: 30 start-page: 2001502 year: 2020 ident: ref_44 article-title: Large-Scale Synthesis of a New Polymeric Carbon Nitride—C3N3 with Good Photoelectrochemical Performance publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.202001502 – volume: 244 start-page: 116618 year: 2020 ident: ref_53 article-title: Enhanced photodegradation performance of Rhodamine B with g-C3N4 modified by carbon nanotubes publication-title: Sep. Purif. Technol. doi: 10.1016/j.seppur.2020.116618 – volume: 84 start-page: 105869 year: 2021 ident: ref_29 article-title: Grain-boundary surface terminations incorporating oxygen vacancies for selectively boosting CO2 photoreduction activity publication-title: Nano Energy doi: 10.1016/j.nanoen.2021.105869 – volume: 25 start-page: 6885 year: 2015 ident: ref_47 article-title: Holey Graphitic Carbon Nitride Nanosheets with Carbon Vacancies for Highly Improved Photocatalytic Hydrogen Production publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201503221 – volume: 17 start-page: 3309 year: 2015 ident: ref_31 article-title: Preparation of water-dispersible porous g-C3N4 with improved photocatalytic activity by chemical oxidation publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/C4CP05020G – volume: 265 start-page: 118581 year: 2020 ident: ref_45 article-title: Two types of cooperative nitrogen vacancies in polymeric carbon nitride for efficient solar-driven H2O2 evolution publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2019.118581 – volume: 12 start-page: 112547 year: 2024 ident: ref_7 article-title: Zeolitic imidazolate framework@hydrogen titanate nanotubes for efficient adsorption and catalytic oxidation of organic dyes and microplastics publication-title: J. Environ. Chem. Eng. doi: 10.1016/j.jece.2024.112547 – volume: 332 start-page: 130039 year: 2022 ident: ref_2 article-title: Sustainable toxic dyes removal with advanced materials for clean water production: A comprehensive review publication-title: J. Clean. Prod. doi: 10.1016/j.jclepro.2021.130039 – volume: 25 start-page: 10530 year: 2023 ident: ref_9 article-title: Cu and Ni dual-doped ZnO nanostructures templated by cellulose nanofibrils for the boosted visible-light photocatalytic degradation of wastewater pollutants publication-title: Green Chem. doi: 10.1039/D3GC04163H – volume: 243 start-page: 513 year: 2019 ident: ref_49 article-title: Synthesis of Y-doped CeO2/PCN nanocomposited photocatalyst with promoted photoredox performance publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2018.10.057 – volume: 135 start-page: 15750 year: 2013 ident: ref_12 article-title: Surface Structure-Dependent Molecular Oxygen Activation of BiOCl Single-Crystalline Nanosheets publication-title: J. Am. Chem. Soc. doi: 10.1021/ja4092903 – volume: 25 start-page: 10397 year: 2009 ident: ref_40 article-title: Photodegradation Performance of g-C3N4 Fabricated by Directly Heating Melamine publication-title: Langmuir doi: 10.1021/la900923z – volume: 421 start-page: 129915 year: 2021 ident: ref_15 article-title: Recent advances in molecular oxygen activation via photocatalysis and its application in oxidation reactions publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2021.129915 – volume: 268 start-page: 112316 year: 2024 ident: ref_62 article-title: Facile preparation and characterization of Zn2Ti3O8/g-C3N4 nanocomposites for degradation of rhodamine B under simulated sunlight publication-title: Sol. Energy doi: 10.1016/j.solener.2024.112316 – volume: 471 start-page: 144521 year: 2023 ident: ref_21 article-title: Mechanism insights into visible light-induced crystalline carbon nitride activating periodate for highly efficient ciprofloxacin removal publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2023.144521 – ident: ref_58 doi: 10.3390/polym12091963 – volume: 129 start-page: 255 year: 2013 ident: ref_8 article-title: Synthesis of g-C3N4/SmVO4 composite photocatalyst with improved visible light photocatalytic activities in RhB degradation publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2012.09.031 – volume: 680 start-page: 132624 year: 2024 ident: ref_16 article-title: Defect engineering in 0D/2D TiO2/g-C3N4 heterojunction for boosting photocatalytic degradation of tetracycline in a tetracycline/Cu2+ combined system publication-title: Colloids Surf. A Physicochem. Eng. Asp. doi: 10.1016/j.colsurfa.2023.132624 – volume: 60 start-page: 25546 year: 2021 ident: ref_25 article-title: Iodide-Induced Fragmentation of Polymerized Hydrophilic Carbon Nitride for High-Performance Quasi-Homogeneous Photocatalytic H2O2 Production publication-title: Angew. Chem. Int. Ed. doi: 10.1002/anie.202111769 – volume: 316 start-page: 121611 year: 2022 ident: ref_18 article-title: Rational design of donor-acceptor conjugated polymers with high performance on peroxydisulfate activation for pollutants degradation publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2022.121611 – volume: 48 start-page: 575 year: 2015 ident: ref_13 article-title: Interconnection of reactive oxygen species chemistry across the interfaces of atmospheric, environmental, and biological processes publication-title: Acc. Chem. Res. doi: 10.1021/ar500412p – volume: 29 start-page: 100277 year: 2021 ident: ref_3 article-title: Adsorption and photocatalytic removal of Rhodamine B from wastewater using carbon-based materials publication-title: FlatChem doi: 10.1016/j.flatc.2021.100277 – volume: 283 start-page: 119637 year: 2021 ident: ref_19 article-title: A facile one-step fabrication of holey carbon nitride nanosheets for visible-light-driven hydrogen evolution publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2020.119637 – volume: 2 start-page: 19145 year: 2014 ident: ref_34 article-title: Hydrothermal synthesis of oxidized g-C3N4 and its regulation of photocatalytic activity publication-title: J. Mater. Chem. A doi: 10.1039/C4TA04041D – volume: 19 start-page: e2300109 year: 2023 ident: ref_24 article-title: Effect of Functional Group Modifications on the Photocatalytic Performance of g-C3N4 publication-title: Small doi: 10.1002/smll.202300109 – volume: 12 start-page: 320 year: 2021 ident: ref_23 article-title: Unraveling fundamental active units in carbon nitride for photocatalytic oxidation reactions publication-title: Nat. Commun. doi: 10.1038/s41467-020-20521-5 – volume: 224 start-page: 194 year: 2017 ident: ref_33 article-title: Ultrasensitive electrochemiluminescence biosensor for organophosphate pesticides detection based on carboxylated graphitic carbon nitride-poly(ethylenimine) and acetylcholinesterase publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2016.12.077 – volume: 50 start-page: 8067 year: 2021 ident: ref_10 article-title: Molecular oxygen-mediated oxygenation reactions involving radicals publication-title: Chem. Soc. Rev. doi: 10.1039/D1CS00242B – volume: 31 start-page: 202102315 year: 2021 ident: ref_14 article-title: Diffusion-Controlled Z-Scheme-Steered Charge Separation across PDI/BiOI Heterointerface for Ultraviolet, Visible, and Infrared Light-Driven Photocatalysis publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.202102315 – volume: 452 start-page: 139191 year: 2023 ident: ref_28 article-title: Interfacial bonding of hydroxyl-modified g-C3N4 and Bi2O2CO3 toward boosted CO2 photoreduction: Insights into the key role of OH groups publication-title: Chem. Eng. J. doi: 10.1016/j.cej.2022.139191 – volume: 284 start-page: 119742 year: 2021 ident: ref_37 article-title: Ultrathin sulfur-doped holey carbon nitride nanosheets with superior photocatalytic hydrogen production from water publication-title: Appl. Catal. B Environ. doi: 10.1016/j.apcatb.2020.119742 – volume: 13 start-page: 1603938 year: 2017 ident: ref_46 article-title: Hierarchical Porous O-Doped g-C3N4 with Enhanced Photocatalytic CO2 Reduction Activity publication-title: Small doi: 10.1002/smll.201603938 – volume: 115 start-page: 7355 year: 2011 ident: ref_43 article-title: Preparation and Enhanced Visible-Light Photocatalytic H2-Production Activity of Graphene/C3N4 Composites publication-title: J. Phys. Chem. C doi: 10.1021/jp200953k – volume: 17 start-page: 655 year: 2018 ident: ref_17 article-title: Carbon nitride, metal nitrides, phosphides, chalcogenides, perovskites and carbides nanophotocatalysts for environmental applications publication-title: Environ. Chem. Lett. doi: 10.1007/s10311-018-0814-8 |
| SSID | ssj0021415 |
| Score | 2.4251552 |
| Snippet | Molecular oxygen activation often suffers from high energy consumption and low efficiency. Developing eco-friendly and effective photocatalysts remains a key... |
| SourceID | doaj pubmedcentral proquest crossref |
| SourceType | Open Website Open Access Repository Aggregation Database Enrichment Source Index Database |
| StartPage | 3836 |
| SubjectTerms | Adsorption Contact angle degradation Efficiency Energy consumption g-C3N4 Oxidation Photocatalysis polar functional group Pollutants Spectrum analysis visible-light photocatalysis |
| SummonAdditionalLinks | – databaseName: DOAJ Directory of Open Access Journals dbid: DOA link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV3fa9RAEF5KX-yLWKsY28oKfRKWJtnNJnnsXT2KcFXEQt_C_pr2oE3Eu0L9753ZJGeDoC--Ziew2ZnsfN9mMh9jJ9KaNBRIUy0OC5UZLwxmIuFrwCspVKmjA_3lpb64Up-ui-snUl9UE9a3B-4X7rQ0kJe5oiLIoEgDD4BKObzMVO5qH_8jx5w3kqmBamWYl_pvmBJJ_el9LzUb1nlN-CP2Y_6dhWKz_gnCnNZHPkk4ixfs-YAU-Vk_w322E9qX7Nl8FGg7YI-zrltT1TJHEMfP3ChUxjvgy1H1ln9-_Ikxwk3ro9k5NYfwW7uvt50394g0-YyvWv6FiK5YYK7rjwhFPJoSy86vALEqvxFzealesavFx2_zCzEIKQiHuWcjCldpR6unIbXSI8sCXZQhc7TTGRNqKIvSWykRT2FKA2nA21RZqVzutarka7bbdm14w3hpwanaGkAapcDoCgpT6uCBUqDXIWHpuLCNG7qMk9jFXYNsg3zR_OGLhH3Y3vK9b7HxN-MZeWtrSN2x4wWMmWaImeZfMZOwo9HXzfDKrhuZ1iTvgMQ8Ye-3w-hS-oJi2tA9RJsaNzBE0QmrJjEymdB0pF3dxrbdWSYLXdX52__xCIdsL0d4RafbmTxiu5sfD-EY4dHGvotvwi-TGxCI priority: 102 providerName: Directory of Open Access Journals |
| Title | Boosting the Activation of Molecular Oxygen and the Degradation of Rhodamine B in Polar-Functional-Group-Modified g-C3N4 |
| URI | https://www.proquest.com/docview/3098052523 https://www.proquest.com/docview/3099794115 https://pubmed.ncbi.nlm.nih.gov/PMC11356892 https://doaj.org/article/7af27245330e40589ff0423d3142c9d7 |
| Volume | 29 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV1La9wwEBZtcmgvJX1RN8miQk8FEduSX6eS3WYTArsNoYG9GT2ThcZKsxtI_n1nZHu3ppCLD9YYP0bWfN9o-IaQr1zJ2GZAUxUMM5FIwyREImYqB2diV8YaE_qzeX52Jc4X2aJLuK26ssp-TQwLtfEac-RHPK5QfR940_e7Pwy7RuHuatdC4yXZRekyJF_FYku4EohO7U4mB2p_dNs2nLWrtEIUElSZt7EoSPYPcOawSvKfsDPdI286vEiPWwe_JS9s8468mvRt2t6Tx7H3K6xdpgDl6LHu25VR7-is731Lfz4-wUyhsjHB7AdKRJiN3eWNN_IW8CYd02VDL5DusilEvDZRyEKCis28WTpArPSaTfhcfCBX05NfkzPWtVNgGiLQmmW6zLUFgJa7WHEDXMvlWWETjeudlLZyRVYYxTmgKghsjktnVCwUFzo1uSj5R7LT-MZ-IrRQTotKSQdkSjiZly6TRW6Nw0BochuRuP-wte60xrHlxe8aOAf6ov7PFxH5trnkrhXaeM54jN7aGKJGdjjh76_r7perC-nSIhVYPotvXVbOYRGQ4YlIdWWKiBz0vq67H3dVb6dZRL5shsGluI8iG-sfgk0Fyxhg6YiUgzkyeKDhSLO8CeLdScKzvKzSz8_ffZ-8TgE-YfY64QdkZ33_YA8B_qzVKMxxOJbT0xHZHZ_MLy5HIZXwF41jDN8 |
| linkProvider | ProQuest |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9NAEB6VcigXxFMYCiwSXJBWtb3r1wGhJiWktAkItVJvZr2PNhK1S5OK9k_xG5nxq1hIvfXqnTiJZ3bmm9nxfABvRaF8G2GaWuAyl4EyXGEk4iZzeMV3qa-poD-bx9ND-eUoOlqDP927MNRW2fnE2lGbSlONfEv4GU3fx7zp49kvTqxRdLraUWg0ZrFnr35jyrb8sLuD-n0XhpNPB-Mpb1kFuEZHvOKRTmNtEafEzi-EwZTDxVFiA03bXimbuSRKTCEEggv0704oZwpfFkLq0MQyFXjfO3BXCpFRC2E6-dwneAFGw-bkFBf9rdOG4NYuw4xQTz0F-jr21RQBA1w77Mr8J8xNHsD9Fp-y7cagHsKaLR_BxrijhXsMl6OqWlKvNEPoyLZ1R4_GKsdmHdcu-3p5hZbJVGlqsR0aSWF6ue8nlVGniG_ZiC1K9o3Saz7BCNsUJnldEOOzyiwcImR2zMdiLp_A4a086KewXlalfQYsKZyWWaEcJm_SqTh1kUpiaxwFXhNbD_zuwea6nW1OFBs_c8xxSBf5f7rw4H3_kbNmsMdNwiPSVi9IM7nrC9X5cd5u8TxRLkxCSe269K_TzDlqOjIikKHOTOLBZqfrvHUUy_zarD140y-jSuncRpW2uqhlMnSbiN09SAc2MvhBw5VycVIPCw8CEcVpFj6_-dtfw8b0YLaf7-_O917AvRChG1XOA7EJ66vzC_sSodeqeFXbO4Mft73B_gJFp0WY |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9NAEF6VIgEXxFMYCiwSXJBWsb1rr_eAUJMQtZSEClEpN7PeRxuJ2qVJRfvX-HXM-JFgIfXWq3fiJJ7ZmW9mx_MR8pYXOnQJpKkFLDMRacs0RCJmlYcroc9CgwX96SzdOxKf58l8i_zp3oXBtsrOJ9aO2lYGa-QDHiqcvg9508C3bRGH48nHs18MGaTwpLWj02hM5MBd_Yb0bflhfwy6fhfHk0_fR3usZRhgBpzyiiUmS40DzJL6sOAW0g-fJtJFBl2A1k55mUhbcA5AA3y959rbIhQFFya2qcg43PcWuS05hE3YS3K-SfYiiIzNKSrnKhycNmS3bhkrRED1ROhNHKzpAnoYt9-h-U_Imzwg91usSncb43pItlz5iNwddRRxj8nlsKqW2DdNAUbSXdNRpdHK02nHu0u_Xl6BlVJd2lpsjOMp7Fru20ll9SlgXTqki5IeYqrNJhBtmyIlq4tjbFrZhQe0TI_ZiM_EE3J0Iw_6Kdkuq9I9I1QW3ghVaA-JnPA6zXyiZeqsxyBsUxeQsHuwuWnnnCPdxs8c8h3URf6fLgLyfv2Rs2bIx3XCQ9TWWhDnc9cXqvPjvN3uudQ-lrHA1l3815nyHhuQLI9EbJSVAdnpdJ23TmOZb0w8IG_Wy6BSPMPRpasuahkFLhRwfECyno30flB_pVyc1IPDo4gnaabi59d_-2tyB7ZW_mV_dvCC3IsBxWERPeI7ZHt1fuFeAgpbFa9qc6fkx03vr78I_EnF |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Boosting+the+Activation+of+Molecular+Oxygen+and+the+Degradation+of+Rhodamine+B+in+Polar-Functional-Group-Modified+g-C3N4&rft.jtitle=Molecules+%28Basel%2C+Switzerland%29&rft.au=Chen%2C+Jing&rft.au=Yang%2C+Minghua&rft.au=Zhang%2C+Hongjiao&rft.au=Chen%2C+Yuxin&rft.date=2024-08-13&rft.pub=MDPI+AG&rft.eissn=1420-3049&rft.volume=29&rft.issue=16&rft.spage=3836&rft_id=info:doi/10.3390%2Fmolecules29163836&rft.externalDBID=HAS_PDF_LINK |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1420-3049&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1420-3049&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1420-3049&client=summon |