A Highly Efficient Heterogeneous Catalyst of Bimetal-Organic Frameworks for the Epoxidation of Olefin with H2O2
A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the develope...
Saved in:
| Published in | Molecules (Basel, Switzerland) Vol. 25; no. 10; p. 2389 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Basel
MDPI AG
21.05.2020
MDPI |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1420-3049 1420-3049 |
| DOI | 10.3390/molecules25102389 |
Cover
Loading…
| Abstract | A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H2O2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn0.1Cu0.9-MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H2O2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation. |
|---|---|
| AbstractList | A series of bimetel organic framework MnxCu1-x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H2O2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn0.1Cu0.9-MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H2O2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation.A series of bimetel organic framework MnxCu1-x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H2O2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn0.1Cu0.9-MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H2O2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation. A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H2O2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn0.1Cu0.9-MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H2O2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation. A series of bimetel organic framework Mn x Cu 1−x -MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). The catalytic activity of the developed catalyst was tested on various olefins by H 2 O 2 as oxidant. The MOFs catalyst exhibits excellent catalytic activity for the epoxidations of various aromatic and cyclic olefins. Particularly, Mn 0.1 Cu 0.9 -MOF can achieve 90.2% conversion of styrene with 94.3% selectivity of styrene oxide at 0 °C after reaction 6 h. The MOF exhibited the catalytic activity of inverse temperature effect on epoxidation of styrene. The introduction of copper component can stabilize H 2 O 2 and inhibit its decomposition to a certain extent. The catalyst can be reused at least five cycles without significant loss in activity towards epoxidation. |
| Author | Yu, Wen-Wang Lv, Jing Meng, Xiang-Guang Wang, Fei Wu, Yan-Yan Huang, Hong |
| AuthorAffiliation | Key Laboratory of Green Chemistry and Technology, College of Chemistry, Sichuan University, Chengdu 610064, China; wangfei113322@126.com (F.W.); wuyanyan@stu.scu.edu.cn (Y.-Y.W.); 17844622232@163.com (H.H.); lvjing945@163.com (J.L.); yuwenwang@stu.scu.edu.cn (W.-W.Y.) |
| AuthorAffiliation_xml | – name: Key Laboratory of Green Chemistry and Technology, College of Chemistry, Sichuan University, Chengdu 610064, China; wangfei113322@126.com (F.W.); wuyanyan@stu.scu.edu.cn (Y.-Y.W.); 17844622232@163.com (H.H.); lvjing945@163.com (J.L.); yuwenwang@stu.scu.edu.cn (W.-W.Y.) |
| Author_xml | – sequence: 1 givenname: Fei surname: Wang fullname: Wang, Fei – sequence: 2 givenname: Xiang-Guang surname: Meng fullname: Meng, Xiang-Guang – sequence: 3 givenname: Yan-Yan surname: Wu fullname: Wu, Yan-Yan – sequence: 4 givenname: Hong surname: Huang fullname: Huang, Hong – sequence: 5 givenname: Jing surname: Lv fullname: Lv, Jing – sequence: 6 givenname: Wen-Wang surname: Yu fullname: Yu, Wen-Wang |
| BookMark | eNp1kktvEzEUhUeoiD7gB7CzxIZNit_2bJBKlJJKlbKBteXx3Jk4eMbBdij590ySIrVFrHzte8535aN7WZ2NcYSqek_wNWM1_jTEAG4XIFNBMGW6flVdEE7xjGFenz2pz6vLnDcYU8KJeFOdM8qFEJpdVPEGLX2_Dnu06DrvPIwFLaFAij2MEHcZzW2xYZ8Lih364geYbrNV6u3oHbpNdoCHmH5k1MWEyhrQYht_-9YWH8eDYxWg8yN68GWNlnRF31avOxsyvHs8r6rvt4tv8-XsfvX1bn5zP3Nc4TKTWlnJGywlE7pjmilCWyu1YIJ31MoWKxBdTZmSomlsbS0B61rRaoU5rjm7qu5O3DbajdkmP9i0N9F6c3yIqTc2Fe8CGGodBpDOTbO4oo1mQjaWS6oa3bpWT6zPJ9Z21wzQuimjZMMz6PPO6Nemj7-MolrVjE6Aj4-AFH_uIBcz-OwgBHuM2FCOFSNScjlJP7yQbuIujVNUB5VUHBNWTyp1UrkUc07QGefLMfNpvg-GYHNYEPPPgkxO8sL59xv_9_wBAyrBqQ |
| CitedBy_id | crossref_primary_10_1007_s40242_023_3106_1 crossref_primary_10_1016_j_jiec_2021_08_024 crossref_primary_10_1016_j_molstruc_2024_137706 crossref_primary_10_1021_acs_inorgchem_3c03128 crossref_primary_10_1016_j_jcis_2024_05_104 crossref_primary_10_1002_slct_202101353 crossref_primary_10_1002_ejic_202300483 crossref_primary_10_1016_j_ccr_2024_216231 crossref_primary_10_1016_j_electacta_2024_145636 crossref_primary_10_3390_molecules26041018 crossref_primary_10_1039_D4DT01701C crossref_primary_10_1039_D0NJ03473H crossref_primary_10_3390_inorganics9110081 crossref_primary_10_1039_D1TA10504C crossref_primary_10_3390_catal12101241 |
| Cites_doi | 10.1007/s10934-014-9822-7 10.1016/j.tetlet.2018.05.031 10.1021/ic400570h 10.1021/acs.inorgchem.5b01938 10.1039/C9CY00565J 10.1080/00958972.2011.636038 10.1039/C4RA07133F 10.1002/ejic.201301098 10.1002/adsc.201600848 10.1016/j.inoche.2016.01.001 10.1002/chem.201505141 10.1016/j.jssc.2014.05.011 10.1039/b418069k 10.1021/cr020471z 10.1016/j.tetasy.2006.01.029 10.1039/C6CC06675E 10.1039/C8CY00579F 10.1098/rspa.2012.0100 10.1021/ja9927467 10.1016/j.catcom.2014.09.040 10.1021/acscatal.7b02946 10.1002/ejic.201300560 10.1021/acssuschemeng.8b06736 10.1039/C7NR08882E 10.1016/j.molcata.2013.08.017 10.1039/C8DT04449J 10.1021/acscatal.5b02299 10.1021/acssuschemeng.6b02229 |
| ContentType | Journal Article |
| Copyright | 2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. 2020 by the authors. 2020 |
| Copyright_xml | – notice: 2020. This work is licensed under http://creativecommons.org/licenses/by/3.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. – notice: 2020 by the authors. 2020 |
| DBID | AAYXX CITATION 3V. 7X7 7XB 88E 8FI 8FJ 8FK ABUWG AFKRA AZQEC BENPR CCPQU DWQXO FYUFA GHDGH K9. M0S M1P PHGZM PHGZT PIMPY PJZUB PKEHL PPXIY PQEST PQQKQ PQUKI PRINS 7X8 5PM DOA |
| DOI | 10.3390/molecules25102389 |
| DatabaseName | CrossRef ProQuest Central (Corporate) Health & Medical Collection ProQuest Central (purchase pre-March 2016) Medical Database (Alumni Edition) Hospital Premium Collection Hospital Premium Collection (Alumni Edition) ProQuest Central (Alumni) (purchase pre-March 2016) ProQuest Central (Alumni) ProQuest Central UK/Ireland ProQuest Central Essentials ProQuest Central ProQuest One Community College ProQuest Central Health Research Premium Collection Health Research Premium Collection (Alumni) ProQuest Health & Medical Complete (Alumni) ProQuest Health & Medical Collection Medical Database ProQuest ProQuest Central Premium ProQuest One Academic (New) Publicly Available Content Database ProQuest Health & Medical Research Collection ProQuest One Academic Middle East (New) ProQuest One Health & Nursing ProQuest One Academic Eastern Edition (DO NOT USE) ProQuest One Academic ProQuest One Academic UKI Edition ProQuest Central China MEDLINE - Academic PubMed Central (Full Participant titles) DOAJ Directory of Open Access Journals |
| DatabaseTitle | CrossRef Publicly Available Content Database ProQuest One Academic Middle East (New) ProQuest Central Essentials ProQuest Health & Medical Complete (Alumni) ProQuest Central (Alumni Edition) ProQuest One Community College ProQuest One Health & Nursing ProQuest Central China ProQuest Central ProQuest Health & Medical Research Collection Health Research Premium Collection Health and Medicine Complete (Alumni Edition) ProQuest Central Korea Health & Medical Research Collection ProQuest Central (New) ProQuest Medical Library (Alumni) ProQuest One Academic Eastern Edition ProQuest Hospital Collection Health Research Premium Collection (Alumni) ProQuest Hospital Collection (Alumni) ProQuest Health & Medical Complete ProQuest Medical Library ProQuest One Academic UKI Edition ProQuest One Academic ProQuest One Academic (New) ProQuest Central (Alumni) MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic CrossRef Publicly Available Content Database |
| Database_xml | – sequence: 1 dbid: DOA name: DOAJ Directory of Open Access Journals url: https://www.doaj.org/ sourceTypes: Open Website – sequence: 2 dbid: BENPR name: ProQuest Central url: https://www.proquest.com/central sourceTypes: Aggregation Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1420-3049 |
| ExternalDocumentID | oai_doaj_org_article_2ac0ee6cc635472b8356ba4627b8dcd8 PMC7287932 10_3390_molecules25102389 |
| GroupedDBID | --- 0R~ 123 2WC 53G 5VS 7X7 88E 8FE 8FG 8FH 8FI 8FJ A8Z AADQD AAFWJ AAHBH AAYXX ABDBF ABUWG ACGFO ACIWK ACPRK ACUHS AEGXH AENEX AFKRA AFPKN AFRAH AFZYC AIAGR ALIPV ALMA_UNASSIGNED_HOLDINGS BENPR BPHCQ BVXVI CCPQU CITATION CS3 D1I DIK DU5 E3Z EBD EMOBN ESX FYUFA GROUPED_DOAJ GX1 HH5 HMCUK HYE HZ~ I09 IHR KQ8 LK8 M1P MODMG O-U O9- OK1 P2P PHGZM PHGZT PIMPY PQQKQ PROAC PSQYO RPM SV3 TR2 TUS UKHRP ~8M 3V. 7XB 8FK AZQEC DWQXO K9. PJZUB PKEHL PPXIY PQEST PQUKI PRINS 7X8 5PM PUEGO |
| ID | FETCH-LOGICAL-c470t-687a64b066358f383712da685354f2a6d07e5f923765bba9aa1eacd5d87040943 |
| IEDL.DBID | BENPR |
| ISSN | 1420-3049 |
| IngestDate | Wed Aug 27 01:31:49 EDT 2025 Thu Aug 21 18:23:57 EDT 2025 Fri Jul 11 10:14:36 EDT 2025 Fri Jul 25 20:03:41 EDT 2025 Tue Jul 01 01:16:46 EDT 2025 Thu Apr 24 23:14:54 EDT 2025 |
| IsDoiOpenAccess | true |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 10 |
| Language | English |
| License | https://creativecommons.org/licenses/by/4.0 Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/). |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c470t-687a64b066358f383712da685354f2a6d07e5f923765bba9aa1eacd5d87040943 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23 |
| OpenAccessLink | https://www.proquest.com/docview/2406740139?pq-origsite=%requestingapplication% |
| PMID | 32455583 |
| PQID | 2406740139 |
| PQPubID | 2032355 |
| ParticipantIDs | doaj_primary_oai_doaj_org_article_2ac0ee6cc635472b8356ba4627b8dcd8 pubmedcentral_primary_oai_pubmedcentral_nih_gov_7287932 proquest_miscellaneous_2407316646 proquest_journals_2406740139 crossref_citationtrail_10_3390_molecules25102389 crossref_primary_10_3390_molecules25102389 |
| ProviderPackageCode | CITATION AAYXX |
| PublicationCentury | 2000 |
| PublicationDate | 20200521 |
| PublicationDateYYYYMMDD | 2020-05-21 |
| PublicationDate_xml | – month: 5 year: 2020 text: 20200521 day: 21 |
| PublicationDecade | 2020 |
| PublicationPlace | Basel |
| PublicationPlace_xml | – name: Basel |
| PublicationTitle | Molecules (Basel, Switzerland) |
| PublicationYear | 2020 |
| Publisher | MDPI AG MDPI |
| Publisher_xml | – name: MDPI AG – name: MDPI |
| References | Brown (ref_13) 2015; 59 Berijani (ref_15) 2019; 9 Lousada (ref_29) 2013; 379 Li (ref_23) 2018; 59 ref_12 Song (ref_25) 2012; 468 Stekrova (ref_9) 2014; 21 Huang (ref_6) 2016; 65 Richardson (ref_27) 2000; 122 ref_17 Jiang (ref_3) 2013; 52 Tang (ref_19) 2014; 4 Tuccitto (ref_24) 2016; 52 Lv (ref_5) 2006; 17 Doke (ref_8) 2017; 5 Hajian (ref_7) 2011; 64 Ottenbacher (ref_16) 2016; 6 Page (ref_4) 2016; 14 Yuan (ref_22) 2018; 10 Dhakshinamoorthy (ref_10) 2016; 22 Song (ref_14) 2019; 7 Wang (ref_21) 2015; 54 Mitra (ref_2) 2019; 48 Miao (ref_1) 2017; 359 Sen (ref_18) 2013; 2013 Stubbs (ref_26) 2018; 8 Ahmad (ref_11) 2018; 8 Sheldon (ref_28) 2005; 7 Bagherzadeh (ref_20) 2015; 223 |
| References_xml | – volume: 21 start-page: 757 year: 2014 ident: ref_9 article-title: Indene epoxidation over immobilized methyltrioxorhenium on MCM-41 silica, fumed silica and aluminosilicate materials publication-title: J. Porous Mater. doi: 10.1007/s10934-014-9822-7 – volume: 59 start-page: 2436 year: 2018 ident: ref_23 article-title: Efficient epoxidation reaction of terminal olefins with hydrogen peroxide catalyzed by an iron (II) complex publication-title: Tetrahedron Lett. doi: 10.1016/j.tetlet.2018.05.031 – volume: 52 start-page: 5814 year: 2013 ident: ref_3 article-title: Catalysis of alkene epoxidation by a series of gallium (III) complexes with neutral N-donor ligands publication-title: Inorg. Chem. doi: 10.1021/ic400570h – volume: 54 start-page: 10865 year: 2015 ident: ref_21 article-title: Co (II)-MOF: A Highly Efficient Organic Oxidation Catalyst with Open Metal Sites publication-title: Inorg. Chem. doi: 10.1021/acs.inorgchem.5b01938 – volume: 9 start-page: 3388 year: 2019 ident: ref_15 article-title: An Effective Strategy in the Creating of Asymmetric MOFs for Chirality Induction: Chiral Zr-based MOF in Enantioselective Epoxidation publication-title: Catal. Sci. Technol. doi: 10.1039/C9CY00565J – volume: 64 start-page: 4134 year: 2011 ident: ref_7 article-title: Olefin epoxidation with tert-BuOOH catalyzed by vanadium polyoxometalate immobilized on ionic liquid-modified MCM-41 publication-title: J. Coord. Chem. doi: 10.1080/00958972.2011.636038 – volume: 4 start-page: 42977 year: 2014 ident: ref_19 article-title: Efficient Molybdenum (VI) Modified Zr-MOF Catalyst for Epoxidation of Olefins publication-title: RSC Adv. doi: 10.1039/C4RA07133F – ident: ref_12 doi: 10.1002/ejic.201301098 – volume: 359 start-page: 476 year: 2017 ident: ref_1 article-title: Bioinspired Manganese Complexes and Graphene Oxide Synergistically Catalyzed Asymmetric Epoxidation of Olefins with Aqueous Hydrogen Peroxide publication-title: Adv. Synth. Catal. doi: 10.1002/adsc.201600848 – volume: 65 start-page: 4 year: 2016 ident: ref_6 article-title: Layered crystalline chiral salen Mn (III) complexes immobilized on organic polymer–inorganic hybrid zinc phosphonate-phosphate as efficient and reusable catalysts for the unfunctionalized olefin epoxidation publication-title: Inorg. Chem. Commun. doi: 10.1016/j.inoche.2016.01.001 – volume: 22 start-page: 8012 year: 2016 ident: ref_10 article-title: Metal-Organic Frameworks as Catalysts for Oxidation Reactions publication-title: Chem. Eur. J. doi: 10.1002/chem.201505141 – volume: 223 start-page: 32 year: 2015 ident: ref_20 article-title: Synthesis, characterizations and catalytic studies of a new two-dimensional metal−organic framework based on Co–carboxylate secondary building units publication-title: J. Solid State Chem. doi: 10.1016/j.jssc.2014.05.011 – volume: 7 start-page: 267 year: 2005 ident: ref_28 article-title: Green Solvents for Sustainable Organic Synthesis: State of the Art publication-title: Green Chem. doi: 10.1039/b418069k – volume: 14 start-page: 4220 year: 2016 ident: ref_4 article-title: Asymmetric epoxidation using iminium salt organocatalysts featuring dynamically controlled atropoisomerism publication-title: Org. Biomol. Chem. – ident: ref_17 doi: 10.1021/cr020471z – volume: 17 start-page: 330 year: 2006 ident: ref_5 article-title: Catalytic asymmetric epoxidation of chalcones under poly (ethylene glycol)-supported Cinchona ammonium salt catalyzed conditions publication-title: Tetrahedron Asymmetry. doi: 10.1016/j.tetasy.2006.01.029 – volume: 52 start-page: 11681 year: 2016 ident: ref_24 article-title: The memory-driven order–disorder transition of a 3D-supramolecular architecture based on calix [5] arene and porphyrin derivatives publication-title: Chem. Commun. doi: 10.1039/C6CC06675E – volume: 8 start-page: 4010 year: 2018 ident: ref_11 article-title: Synthesis of 2D MOF having potential for efficient dye adsorption and catalytic applications publication-title: Catal. Sci. Technol. doi: 10.1039/C8CY00579F – volume: 468 start-page: 2035 year: 2012 ident: ref_25 article-title: Chiral porous metal-organic frameworks with dual active sites for sequential asymmetric catalysis publication-title: Proc. R. Soc. A doi: 10.1098/rspa.2012.0100 – volume: 122 start-page: 1729 year: 2000 ident: ref_27 article-title: Equilibria, Kinetics, and Mechanism in the Bicarbonate Activation of Hydrogen Peroxide: Oxidation of Sulfides by Peroxymonocarbonate publication-title: J. Am. Chem. Soc. doi: 10.1021/ja9927467 – volume: 59 start-page: 50 year: 2015 ident: ref_13 article-title: Epoxidation of alkenes with molecular oxygen catalyzed by a manganese porphyrin-based metal–organic framework publication-title: Catal.Commun. doi: 10.1016/j.catcom.2014.09.040 – volume: 8 start-page: 596 year: 2018 ident: ref_26 article-title: Selective Catalytic Olefin Epoxidation with Mn II -Exchanged MOF-5 publication-title: ACS Catal. doi: 10.1021/acscatal.7b02946 – volume: 2013 start-page: 5103 year: 2013 ident: ref_18 article-title: Cobalt-Based 3D Metal-Organic Frameworks: Useful Candidates for Olefin Epoxidation at Ambient Temperature by H2O2 publication-title: Eur. J. Inorg. Chem. doi: 10.1002/ejic.201300560 – volume: 7 start-page: 3624 year: 2019 ident: ref_14 article-title: Polyoxomolybdic Cobalt Encapsulated within Zr-Based Metal− Organic Frameworks as Efficient Heterogeneous Catalysts for Olefins Epoxidation publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.8b06736 – volume: 10 start-page: 1591 year: 2018 ident: ref_22 article-title: Bimetal–organic frameworks for functionality optimization: MnFe-MOF-74 as a stable and efficient catalyst for the epoxidation of alkenes with H2O2 publication-title: Nanoscale doi: 10.1039/C7NR08882E – volume: 379 start-page: 178 year: 2013 ident: ref_29 article-title: Catalytic decomposition of hydrogen peroxide on transition metal and lanthanide oxides publication-title: J. Mol. Catal. A Chem. doi: 10.1016/j.molcata.2013.08.017 – volume: 48 start-page: 6123 year: 2019 ident: ref_2 article-title: Highly enantioselective epoxidation of olefins by H2O2 catalyzed by a non-heme Fe(ii) catalyst of a chiral tetradentate ligand publication-title: Dalton Trans. doi: 10.1039/C8DT04449J – volume: 6 start-page: 979 year: 2016 ident: ref_16 article-title: Highly Enantioselective Bioinspired Epoxidation of Electron-Deficient Olefins with H2O2 on Aminopyridine Mn Catalysts publication-title: ACS Catal. doi: 10.1021/acscatal.5b02299 – volume: 5 start-page: 904 year: 2017 ident: ref_8 article-title: Environmentally Benign Bioderived Carbon Microspheres-Supported Molybdena Nanoparticles as Catalyst for the Epoxidation Reaction publication-title: ACS Sustain. Chem. Eng. doi: 10.1021/acssuschemeng.6b02229 |
| SSID | ssj0021415 |
| Score | 2.3781614 |
| Snippet | A series of bimetel organic framework MnxCu1−x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray... A series of bimetel organic framework MnxCu1-x-MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray... A series of bimetel organic framework Mn x Cu 1−x -MOF were prepared. The MOFs was characterized and analyzed by powder X-ray diffraction (PXRD), X-ray... |
| SourceID | doaj pubmedcentral proquest crossref |
| SourceType | Open Website Open Access Repository Aggregation Database Enrichment Source Index Database |
| StartPage | 2389 |
| SubjectTerms | Acids Catalysis catalysts epoxidation Fourier transforms H2O2 Hydrogen peroxide Ligands metal-organic frameworks MOF olefin Scanning electron microscopy Vibration |
| SummonAdditionalLinks | – databaseName: DOAJ Directory of Open Access Journals dbid: DOA link: http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwrV3NS8MwFA_iRS_iJ06nRPAklLVZmrRHHRtDUC8Odiv5Kg62drgJ7r_3vbQdFkEvHtskbZr30vf7JS_vEXIrAQI4nuqAWRsGHP0bVRqzQCQ2NpwrJXwwnadnMZ7wx2k8_ZbqC33CqvDA1cD1mDKhc8IYsIxcMg2IQWjFBZM6scb6Y75g8xoyVVOtCOxStYfZB1LfW1SpZt0KrDkaqbRlhXyw_hbCbPtHfjM4o0NyUCNFel_18IjsuOKY7A2aBG0npLyn6KUx39ChjwMBj6Fj9G4pQSkcMHo6wLWZzWpNy5w-zBYOroLq8KWho8Yra0UBt1LAgXS4LD9nVY4lbPEyd_msoLhSS8fshZ2SyWj4OhgHdf6EwHAZrmG8pRJce1CR5EhFI2aVAAMd85wpYUPp4jxFv5hYa5UqFcFv2MYW5jDSvv4Z2S3Kwp0TaiNuE-0YS3LLBQ81zyMdAT4zwqRMyw4Jm_HMTB1cHHNczDMgGSiC7IcIOuRu22RZRdb4rfIDCmlbEYNi-xugKlmtKtlfqtIh3UbEWT1TVxkiGp-VEN5xsy0GSeLGifLSwjqY4Etw0SGypRqtDrVLitmbj9YtgZMCSL74jy-4JPsM-X4YByzqkt31-4e7AlC01tde_78AVYENxg priority: 102 providerName: Directory of Open Access Journals |
| Title | A Highly Efficient Heterogeneous Catalyst of Bimetal-Organic Frameworks for the Epoxidation of Olefin with H2O2 |
| URI | https://www.proquest.com/docview/2406740139 https://www.proquest.com/docview/2407316646 https://pubmed.ncbi.nlm.nih.gov/PMC7287932 https://doaj.org/article/2ac0ee6cc635472b8356ba4627b8dcd8 |
| Volume | 25 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwfV3da9swED_W9GF7Gftk3rqgwZ4GprYqS_bTaEKyMFg7xgp5M_ryFkjttM5g_e93J9vZzKAvBluSP3SS7nen8_0A3iuEAF4UJubOJbGg-EZdZDyWucusEFrLkEzny4VcXYnP62zdO9zaPqxyWBPDQu0aSz7yU9I8gT2u-Li7iYk1inZXewqNIzjGJTjPJnA8W1x8_XYwuVLUT91e5hka96fXHeWsb1Grk7IqRtooJO0fIc1xnOQ_imf5BB73iJGddyJ-Cg98_QwezgeitufQnDOK1tjesUXIB4G3YSuKcmlwcHi07NmcfDR37Z41FZttrj2exd1PmJYth-isliF-ZYgH2WLX_N50XEvU4nLrq03NyGPLVvySv4Cr5eL7fBX3PAqxFSrZY78rLYUJ4CKvyCRNudMSFXUmKq6lS5TPqoLiYzJjdKF1isuxyxzOZTL_zl7CpG5q_wqYS4XLjec8r5yQIjGiSk2KOM1KW3CjIkiG_ixtn2ScuC62JRobJILyPxFE8OHQZNdl2Liv8oyEdKhIybHDheb2R9nPtZJrm3gvrcXvFYobBJnSaCG5MrmzLo_gZBBx2c_Ytvw7viJ4dyhGSdIGig7SojpE9CWFjECNhsbohcYl9eZnyNqt0DZFsPz6_oe_gUecLPoki3l6ApP97S__FmHP3kzhSK0VHvPlp2k_zqfBhfAHidgI5w |
| linkProvider | ProQuest |
| linkToHtml | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1Lb9NAEB6V9lAuiKcwFFgkuCBZtTfrtX1AqAmJUtqmCLVSb2ZfhkipHepUkD_Fb2TGj4CF1FuPttf22jO7883s7HwAb2KEAE6k2ufWBr6g_EaVRtyXiY2MEErJupjOyUxOz8Wni-hiC353e2EorbKbE-uJ2paGYuT7ZHlq9rj0w_KHT6xRtLraUWg0anHk1j_RZaveH35E-b7lfDI-G039llXANyIOVtiLWEmha1Ob5OSghdwqiWYrEjlX0gaxi_KUskUirVWqVIiTk40sajY5QwN87h3YQZiR4ijaGY5nn79sXLwQ7WGzdjoYpMH-ZUNx6ypEEWQc0571q0kCesi2n5f5j6Gb3Id7LUJlB41KPYAtVzyE3VFHDPcIygNG2SGLNRvX9SfwMWxKWTUlKqMrrys2opjQulqxMmfD-aXDI7_Z9GnYpMsGqxjiZYb4k42X5a95w-1Ed5wuXD4vGEWI2ZSf8sdwfit_-AlsF2XhngKzobCJdpwnuRVSBFrkoQ4RFxppUq5jD4Luf2amLWpO3BqLDJ0bEkH2nwg8eLe5ZdlU9Lip8ZCEtGlIxbjrE-XVt6wd2xlXJnBOGoPfK2KuEdRKrYTksU6ssYkHe52Is3aGqLK_-uzB681llCQt2KhaWtSGiMWkkB7EPdXodah_pZh_r6uEx-gLIzh_dvPLX8Hu9OzkODs-nB09h7ucoglB5PNwD7ZXV9fuBUKulX7Z6jmDr7c9tP4AMnRBcA |
| linkToPdf | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV3db9MwED-NTgJeEJ9aYICR4AUpauI6TvKA0Nq16hh0E2LS3oK_ApW6piydoP8afx13-ShESHvbY2LHcXJn3-_s8_0AXscIAZxItc-tDXxB8Y0qjbgvExsZIZSSVTKdTzM5PRMfzqPzHfjdnoWhsMp2TqwmalsYWiPvk-Wp2OPSft6ERZweTt6vfvjEIEU7rS2dRq0ix27zE9238t3RIcr6DeeT8ZfR1G8YBnwj4mCNPYqVFLoyu0lOzlrIrZJowiKRcyVtELsoTylyJNJapUqFOFHZyKKWk2M0wHZvwS72SyY92B2OZ6eft-5eiLax3kcdDNKgf1HT3boSEQUZyrRjCSvCgA7K7cZo_mP0JvfhXoNW2UGtXg9gxy0fwp1RSxL3CIoDRpEiiw0bV7kosBk2pQibAhXTFVclG9H60KZcsyJnw_mFwyu_PgBq2KSNDCsZYmeGWJSNV8Wvec3zRE-cLFw-XzJaLWZTfsIfw9mN_OEn0FsWS7cHzIbCJtpxnuRWSBFokYc6RIxopEm5jj0I2v-ZmSbBOfFsLDJ0dEgE2X8i8ODt9pFVnd3juspDEtK2IiXmrm4Ul9-yZpxnXJnAOWkMfq-IuUaAK7USksc6scYmHuy3Is6a2aLM_uq2B6-2xShJ2rxRlbSoDpGMSSE9iDuq0elQt2Q5_15lDI_RL0ag_vT6l7-E2zikso9Hs-NncJfTwkIQ-Tzch9768so9R_S11i8aNWfw9aZH1h_N9kWc |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=A+Highly+Efficient+Heterogeneous+Catalyst+of+Bimetal-Organic+Frameworks+for+the+Epoxidation+of+Olefin+with+H2O2&rft.jtitle=Molecules+%28Basel%2C+Switzerland%29&rft.au=Wang%2C+Fei&rft.au=Meng%2C+Xiang-Guang&rft.au=Wu%2C+Yan-Yan&rft.au=Huang%2C+Hong&rft.date=2020-05-21&rft.issn=1420-3049&rft.eissn=1420-3049&rft.volume=25&rft.issue=10&rft_id=info:doi/10.3390%2Fmolecules25102389&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1420-3049&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1420-3049&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1420-3049&client=summon |