Comment on “Citrate adsorption can decrease soluble phosphate concentration in soils: Results of theoretical modelling” by Marek Duputel, Nicolas Devau, Michel Brossard, Benoît Jaillard, Davey L. Jones, Philippe Hinsinger and Frédéric Gérard (2013)
By use of a multi-site surface complexation model, Duputel et al. (2013) showed that citrate can decrease the solubility of phosphorus in soils, in contrast to what is commonly expected. We have identified several major errors in their model, which put the conclusions in doubt. We argue that major r...
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| Published in | Applied geochemistry Vol. 46; pp. 85 - 89 |
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| Main Authors | , |
| Format | Journal Article |
| Language | English |
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| Abstract | By use of a multi-site surface complexation model, Duputel et al. (2013) showed that citrate can decrease the solubility of phosphorus in soils, in contrast to what is commonly expected. We have identified several major errors in their model, which put the conclusions in doubt. We argue that major re-evaluation of their modelling approach is needed. |
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| AbstractList | By use of a multi-site surface complexation model, Duputel et al. (2013) showed that citrate can decrease the solubility of phosphorus in soils, in contrast to what is commonly expected. We have identified several major errors in their model, which put the conclusions in doubt. We argue that major re-evaluation of their modelling approach is needed. By use of a multi-site surface complexation model, Duputel et al. (2013) showed that citrate can decrease the solubility of phosphorus in soils, in contrast to what is commonly expected. We have identified several major errors in their model, which put the conclusions in doubt. We argue that major re-evaluation of their modelling approach is needed. (c) 2014 Elsevier Ltd. All rights reserved. |
| Author | Lumsdon, David G. Gustafsson, Jon Petter |
| Author_xml | – sequence: 1 givenname: Jon Petter surname: Gustafsson fullname: Gustafsson, Jon Petter email: jon-petter.gustafsson@slu.se organization: Swedish University of Agricultural Sciences, Department of Soil and Environment, Box 7014, 750 07 Uppsala, Sweden – sequence: 2 givenname: David G. surname: Lumsdon fullname: Lumsdon, David G. organization: The James Hutton Institute, Environmental & Biogeochemical Science Group, Craigiebuckler, Aberdeen, Scotland AB15 8QH, UK |
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| Cites_doi | 10.1039/CT8946500115 10.1016/S0021-9797(03)00693-3 10.1016/j.gca.2013.03.044 10.1346/CCMN.1996.0440504 10.1016/j.apgeochem.2009.09.020 10.1093/aob/mcq098 10.1006/jcis.1996.0242 10.1021/es025597s 10.1006/jcis.1997.4970 10.1016/j.gca.2012.05.042 10.1016/j.gca.2011.02.034 10.1021/es305180e 10.1021/es801631d 10.1021/es970908y 10.1016/j.apgeochem.2013.03.018 10.1016/j.apgeochem.2010.03.008 10.2134/jeq2011.0250 |
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| References | Weng, van Riemsdijk, Hiemstra (b0090) 2008; 42 Devau, Le Cadre, Hinsinger, Gérard (b0015) 2010; 105 Lumsdon (b0070) 2012; 92 Weng, van Riemsdijk, Hiemstra (b0095) 2012; 41 Devau, Hinsinger, Le Cadre, Colomb, Gérard (b0020) 2011; 75 Dyer (b0035) 1894; 65 Duputel, Devau, Brossard, Jaillard, Jones, Hinsinger, Gérard (b0030) 2013; 35 Manning, Goldberg (b0075) 1996; 44 . Gustafsson, J.P., 2012. Visual MINTEQ. Available from Geelhoed, Hiemstra, van Riemdijk (b0040) 1998; 32 Iannou, Dimirkou (b0060) 1997; 192 Meeussen (b0080) 2003; 37 Wang, Giammar (b0085) 2013; 47 Lackovic, Johnson, Angove, Wells (b0065) 2003; 267 Hiemstra, van Riemsdijk (b0055) 1996; 179 Devau, Le Cadre, Hinsinger, Jaillard, Gérard (b0010) 2010; 25 Devau, N., Hinsinger, P., Le Cadre, E., Colomb, E., Gérard, F., 2014. Reply to the comment by D.G. Lumsdon on “Fertilization and pH effects on processes and mechanisms controlling dissolved inorganic phosphorus in soils” by N. Devau, P. Hinsinger, E. Le Cadre, E. Colomb, F. Gérard. Geochim. Cosmochim. Acta, 124, 110–117. Devau, Le Cadre, Hinsinger, Jaillard, Gérard (b0005) 2009; 24 Dyer (10.1016/j.apgeochem.2014.02.006_b0035) 1894; 65 Manning (10.1016/j.apgeochem.2014.02.006_b0075) 1996; 44 10.1016/j.apgeochem.2014.02.006_b0050 Devau (10.1016/j.apgeochem.2014.02.006_b0015) 2010; 105 Wang (10.1016/j.apgeochem.2014.02.006_b0085) 2013; 47 Iannou (10.1016/j.apgeochem.2014.02.006_b0060) 1997; 192 Hiemstra (10.1016/j.apgeochem.2014.02.006_b0055) 1996; 179 Devau (10.1016/j.apgeochem.2014.02.006_b0020) 2011; 75 Meeussen (10.1016/j.apgeochem.2014.02.006_b0080) 2003; 37 10.1016/j.apgeochem.2014.02.006_b0025 Geelhoed (10.1016/j.apgeochem.2014.02.006_b0040) 1998; 32 Devau (10.1016/j.apgeochem.2014.02.006_b0010) 2010; 25 Devau (10.1016/j.apgeochem.2014.02.006_b0005) 2009; 24 Weng (10.1016/j.apgeochem.2014.02.006_b0095) 2012; 41 Duputel (10.1016/j.apgeochem.2014.02.006_b0030) 2013; 35 Lackovic (10.1016/j.apgeochem.2014.02.006_b0065) 2003; 267 Lumsdon (10.1016/j.apgeochem.2014.02.006_b0070) 2012; 92 Weng (10.1016/j.apgeochem.2014.02.006_b0090) 2008; 42 |
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Technol. doi: 10.1021/es305180e – volume: 42 start-page: 8747 year: 2008 ident: 10.1016/j.apgeochem.2014.02.006_b0090 article-title: Humic nano-particles at the oxide-water interface: interactions with phosphate ion adsorption publication-title: Environ. Sci. Technol. doi: 10.1021/es801631d – volume: 32 start-page: 2119 year: 1998 ident: 10.1016/j.apgeochem.2014.02.006_b0040 article-title: Competitive interaction between phosphate and citrate on goethite publication-title: Environ. Sci. Technol. doi: 10.1021/es970908y – volume: 35 start-page: 120 year: 2013 ident: 10.1016/j.apgeochem.2014.02.006_b0030 article-title: Citrate adsorption can decrease soluble phosphate concentrations in soils: results of theoretical modeling publication-title: Appl. 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| SubjectTerms | Earth sciences Earth, ocean, space Engineering and environment geology. Geothermics Exact sciences and technology Geochemistry Geokemi Pollution, environment geology |
| Title | Comment on “Citrate adsorption can decrease soluble phosphate concentration in soils: Results of theoretical modelling” by Marek Duputel, Nicolas Devau, Michel Brossard, Benoît Jaillard, Davey L. Jones, Philippe Hinsinger and Frédéric Gérard (2013) |
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