Efficient Synthesis of Novel Plasticizers by Direct Palladium‐Catalyzed Di‐ or Multi‐carbonylations

• Published in: Angewandte Chemie International Edition Vol. 62; no. 6; pp. e202214706 - n/a
• Main Authors: Hu, Yuya, Sang, Rui, Vroemans, Robby, Mollaert, Guillaume, Razzaq, Rauf, Neumann, Helfried, Junge, Henrik, Franke, Robert, Jackstell, Ralf, Maes, Bert U. W., Beller, Matthias
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 01.02.2023; Wiley Subscription Services, Inc; John Wiley and Sons Inc
• Edition: International ed. in English
• Subjects: Alcohols; Alkenes; Calorimetry; Carbonylation; Carbonyls; Catalysts; Chemical industry; Chemical synthesis; Chemistry; Chemistry, Multidisciplinary; Diesters; Differential scanning calorimetry; Esterification; Glass transition temperature; Lubricants; Olefins; Palladium; Physical Sciences; Plasticizers; Polyols; Science & Technology; Surfactants; Sustainability; Transition temperatures; Plasticizers; ALKOXYCARBONYLATION; Olefins; POLY(VINYLIDENE FLUORIDE); Palladium; DESIGNING GREEN PLASTICIZERS; HIGHLY SELECTIVE FORMATION; HYDROESTERIFICATION; ALKENES; Carbonylation; BIODIESEL PRODUCTION; Sustainability; ESTERS; ENGINE PERFORMANCE; PHTHALATE DEHP

Diesters are of fundamental importance in the chemical industry and are used for many applications, e.g. as plasticizers, surfactants, emulsifiers, and lubricants. Herein, we present a straightforward and efficient method for the selective synthesis of diesters via palladium‐catalyzed direct carbony...