Room‐Temperature Spin‐Dependent Transport in Metalloporphyrin‐Based Supramolecular Wires

• Published in: Angewandte Chemie International Edition Vol. 60; no. 49; pp. 25958 - 25965
• Main Authors: Aragonès, Albert C., Martín‐Rodríguez, Alejandro, Aravena, Daniel, Palma, Giuseppe, Qian, Wenjie, Puigmartí‐Luis, Josep, Aliaga‐Alcalde, Núria, González‐Campo, Arántzazu, Díez‐Pérez, Ismael, Ruiz, Eliseo
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01.12.2021; John Wiley and Sons Inc
• Edition: International ed. in English
• Subjects: Charge transport; density functional calculations; Electrodes; Electronic structure; Ferromagnetism; Magnetoresistance; Magnetoresistivity; metalloporphyrins; Porphyrins; single-molecule junctions; spinterface; Temperature dependence; magnetoresistance; density functional calculations; single-molecule junctions; metalloporphyrins; spinterface

Here we present room‐temperature spin‐dependent charge transport measurements in single‐molecule junctions made of metalloporphyrin‐based supramolecular assemblies. They display large conductance switching for magnetoresistance in a single‐molecule junction. The magnetoresistance depends acutely on...