Proton-conducting crystalline porous materials

Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures an...

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Published in	Chemical Society reviews Vol. 46; no. 2; pp. 464 - 48
Main Authors	Meng, Xing, Wang, Hai-Ning, Song, Shu-Yan, Zhang, Hong-Jie
Format	Journal Article
Language	English
Published	England 23.01.2017
Subjects	Acetal resins Carriers coordination polymers Covalence Crystal structure crystals electrical conductivity Metal-organic frameworks Polyoxometallates Porous materials porous media protons Surface area synthesis
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Abstract	Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures and high surface areas of these materials provide great opportunities to orderly accommodate proton carriers and to systemically modify the concentration and mobility of proton carriers in available spaces. Based on the understanding of the relationship between the structure and proton conductivity, controllable synthesis of porous materials with high proton conductivity will gradually be achieved. This review summarizes the emerging studies of these materials and their unique proton conductivities. This review summarizes the emerging studies of proton-conducting materials, and discusses the synthetic strategies and possible mechanisms, identifying key structural factors.
AbstractList	Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures and high surface areas of these materials provide great opportunities to orderly accommodate proton carriers and to systemically modify the concentration and mobility of proton carriers in available spaces. Based on the understanding of the relationship between the structure and proton conductivity, controllable synthesis of porous materials with high proton conductivity will gradually be achieved. This review summarizes the emerging studies of these materials and their unique proton conductivities. Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic frameworks (MOFs), coordination polymers (CPs), polyoxometalates (POMs) and covalent organic frameworks (COFs). The designable structures and high surface areas of these materials provide great opportunities to orderly accommodate proton carriers and to systemically modify the concentration and mobility of proton carriers in available spaces. Based on the understanding of the relationship between the structure and proton conductivity, controllable synthesis of porous materials with high proton conductivity will gradually be achieved. This review summarizes the emerging studies of these materials and their unique proton conductivities. This review summarizes the emerging studies of proton-conducting materials, and discusses the synthetic strategies and possible mechanisms, identifying key structural factors.
Author	Wang, Hai-Ning Meng, Xing Zhang, Hong-Jie Song, Shu-Yan
AuthorAffiliation	College of Chemical Engineering Changchun Institute of Applied Chemistry Chinese Academy of Sciences State Key Laboratory of Rare Earth Resource Utilization Shandong University of Technology
AuthorAffiliation_xml	– name: State Key Laboratory of Rare Earth Resource Utilization – name: Changchun Institute of Applied Chemistry – name: Shandong University of Technology – name: Chinese Academy of Sciences – name: College of Chemical Engineering
Author_xml	– sequence: 1 givenname: Xing surname: Meng fullname: Meng, Xing – sequence: 2 givenname: Hai-Ning surname: Wang fullname: Wang, Hai-Ning – sequence: 3 givenname: Shu-Yan surname: Song fullname: Song, Shu-Yan – sequence: 4 givenname: Hong-Jie surname: Zhang fullname: Zhang, Hong-Jie
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/27918056$$D View this record in MEDLINE/PubMed
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Notes	Xing Meng received her BSc degree from Materials Chemistry from Langfang Teachers University in 2009 and her MSc in Physical Chemistry in 2012 from Northeast Normal University. In the same year, she joined Professor Hongjie Zhang to pursue her PhD degree in Inorganic Chemistry at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (CAS). She is working as a lecturer at Shandong University of Technology. Her research interests focus on multi-functional porous materials and relevant properties. Hong-Jie Zhang received his BSc degree from Peking University in 1978. He then worked as a research assistant in Changchun Institute of Applied Chemistry, where he received his MSc degree in Inorganic Chemistry in 1985. Then, he worked as an assistant professor at the same institute from 1985-1989. He then studied at Universite de Bordeaux I, Laboratoire de Chimie du Solide du CNRS (France), where he received his PhD degree in Solid State Chemistry and Materials Sciences in 1993. He joined Changchun Institute of Applied Chemistry, CAS, as a professor in 1994. His current research interests include lanthanide organic-inorganic hybrid materials, electroluminescent devices, functional nanomaterials, and the structure and properties of rare earth magnesium alloys. Hai-Ning Wang received his BSc degree in Chemistry from Northeast Normal University in 2009, and in the same year, he joined Professor Zhong-Min Su to pursue his PhD degree in Physical Chemistry from Northeast Normal University. He is currently working as a lecturer at Shandong University of Technology. His research interests focus on crystalline porous materials and sensors based on these materials. Shu-Yan Song received his BSc degree in Chemistry in 2003 and MSc degree in Inorganic Chemistry in 2006, both from Northeast Normal University. He joined the group of Prof. Hongjie Zhang at Changchun Institute of Applied Chemistry, Chinese Academy of Sciences (CAS), where he received his PhD degree in Inorganic Chemistry in 2009. He is working as an associate professor at Changchun Institute of Applied Chemistry, CAS. His research focus is primarily on the development of porous functional materials for gas catalysis, proton conduction, chemical sensing and detection. ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-3 content type line 23 ObjectType-Review-1 ObjectType-Article-1 ObjectType-Feature-2
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Snippet	Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal-organic... Crystalline porous materials are currently a hot research topic in the field of proton-conducting materials. Crystalline porous materials include metal–organic...
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SubjectTerms	Acetal resins Carriers coordination polymers Covalence Crystal structure crystals electrical conductivity Metal-organic frameworks Polyoxometallates Porous materials porous media protons Surface area synthesis
Title	Proton-conducting crystalline porous materials
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