2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetra-hydro-1H-1,5-benzodiazepin-1-yl)ethanone

In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro-acetyl group is trans to the N atom of the diazepine ring. In the crystal, the mol-ecules form chains running along the diagonal of the ac plane through N-H⋯O hydrogen bonds.

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Published inActa crystallographica. Section E, Structure reports online Vol. 69; no. Pt 6; p. o874
Main Authors Thiruselvam, V, Rajakumari, D Deepa, Akila, A, Ponnuswamy, S, Ponnuswamy, M N
Format Journal Article
LanguageEnglish
Published United States International Union of Crystallography 01.06.2013
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Organic Papers
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Abstract In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro-acetyl group is trans to the N atom of the diazepine ring. In the crystal, the mol-ecules form chains running along the diagonal of the ac plane through N-H⋯O hydrogen bonds.
AbstractList In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloroacetyl group is trans to the N atom of the diazepine ring. In the crystal, the molecules form chains running along the diagonal of the ac plane through N-H...O hydrogen bonds.
In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro-acetyl group is trans to the N atom of the diazepine ring. In the crystal, the mol-ecules form chains running along the diagonal of the ac plane through N-H⋯O hydrogen bonds.
In the title compound, C 14 H 19 ClN 2 O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro­acetyl group is trans to the N atom of the diazepine ring. In the crystal, the mol­ecules form chains running along the diagonal of the ac plane through N—H⋯O hydrogen bonds.
Author Ponnuswamy, S
Thiruselvam, V
Rajakumari, D Deepa
Akila, A
Ponnuswamy, M N
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10.1021/jo981536u
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Snippet In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro-acetyl group is trans to the N atom of the...
In the title compound, C 14 H 19 ClN 2 O, the diazepine ring adopts a boat conformation. The Cl atom of the chloro­acetyl group is trans to the N atom of the...
In the title compound, C14H19ClN2O, the diazepine ring adopts a boat conformation. The Cl atom of the chloroacetyl group is trans to the N atom of the...
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Title 2-Chloro-1-(2,4,4-trimethyl-2,3,4,5-tetra-hydro-1H-1,5-benzodiazepin-1-yl)ethanone
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