Transformation of Phenol, Resorcinol, Pyrocatechol, and Hydroquinone in Water Under Exposure to Low Doses of UV Radiation

The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of 10 –4 to 10 –6 M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action...

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Published in	Journal of applied spectroscopy Vol. 88; no. 4; pp. 807 - 815
Main Authors	Nekrasova, L. P., Kochetkov, P. P.
Format	Journal Article
Language	English
Published	New York Springer US 01.09.2021 Springer Springer Nature B.V
Subjects	Analysis Analytical Chemistry Atomic/Molecular Structure and Spectra Fluorescence High performance liquid chromatography Hydroquinone Phenols Photolysis Physics Physics and Astronomy Ultraviolet radiation UV radiation phenol resorcinol transformation pyrocatechol
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Abstract	The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of 10 –4 to 10 –6 M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action of UV radiation more readily than the other compounds. It was shown that the main products from the photolysis of phenol are pyrocatechol and dihydroxybiphenyls. Resorcinol, pyrocatechol, and hydroquinone form trihydroxybenzenes.
AbstractList	The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of [10.sup.-4] to [10.sup.-6] M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action of UV radiation more readily than the other compounds. It was shown that the main products from the photolysis of phenol are pyrocatechol and dihydroxybiphenyls. Resorcinol, pyrocatechol, and hydroquinone form trihydroxybenzenes. Keywords: phenol, resorcinol, pyrocatechol, transformation, UV radiation. The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of [10.sup.-4] to [10.sup.-6] M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action of UV radiation more readily than the other compounds. It was shown that the main products from the photolysis of phenol are pyrocatechol and dihydroxybiphenyls. Resorcinol, pyrocatechol, and hydroquinone form trihydroxybenzenes. The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of 10–4 to 10–6 M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action of UV radiation more readily than the other compounds. It was shown that the main products from the photolysis of phenol are pyrocatechol and dihydroxybiphenyls. Resorcinol, pyrocatechol, and hydroquinone form trihydroxybenzenes. The transformation of phenol, resorcinol, pyrocatechol, and hydroquinone in water at concentrations of 10 –4 to 10 –6 M under short-term exposure to UV radiation was studied by fluorescence analysis and high-performance liquid chromatography. It was found that resorcinol is transformed by the action of UV radiation more readily than the other compounds. It was shown that the main products from the photolysis of phenol are pyrocatechol and dihydroxybiphenyls. Resorcinol, pyrocatechol, and hydroquinone form trihydroxybenzenes.
Audience	Academic
Author	Kochetkov, P. P. Nekrasova, L. P.
Author_xml	– sequence: 1 givenname: L. P. surname: Nekrasova fullname: Nekrasova, L. P. email: LNekrasova@cspmz.ru organization: Federal State Budgetary Institution “Center for Strategic Planning and Management of Biomedical Health Risks” of the Federal Medical and Biological Agency – sequence: 2 givenname: P. P. surname: Kochetkov fullname: Kochetkov, P. P. organization: Federal State Budgetary Institution “Center for Strategic Planning and Management of Biomedical Health Risks” of the Federal Medical and Biological Agency
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Cites_doi	10.1021/ja00966a019 10.1016/S1093-0191(00)00024-1 10.18821/0016-9900-2019-98-11-1206-1211 10.1016/j.envint.2008.09.004 10.1093/clinchem/39.1.108 10.18821/0016-9900-2017-96-6-531-535 10.1080/02772249409358000 10.1021/acs.jpca.5b07914 10.1021/tx9902082 10.1080/00986445.2013.848804 10.1016/j.chemosphere.2014.04.035 10.1016/S1010-6030(96)04454-1 10.1021/ja01856a044 10.1007/s11356-020-10897-8 10.1007/s10812-006-0162-5 10.1016/j.cej.2007.06.025
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SubjectTerms	Analysis Analytical Chemistry Atomic/Molecular Structure and Spectra Fluorescence High performance liquid chromatography Hydroquinone Phenols Photolysis Physics Physics and Astronomy Ultraviolet radiation
Title	Transformation of Phenol, Resorcinol, Pyrocatechol, and Hydroquinone in Water Under Exposure to Low Doses of UV Radiation
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