Hydrothermal conversion of xylose, glucose, and cellulose under the catalysis of transition metal sulfates

•Zn2+ and Ni2+ showed obvious effect on converting biomass into lactic acid.•Cu2+ and Fe3+ could accelerate the formations of levulinic acid and formic acid.•Positive correlations among xylose, glucose, and cellulose degradation were observed.•HTC of monosaccharide can be used to screen catalysts fo...

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Published inCarbohydrate polymers Vol. 118; pp. 44 - 51
Main Authors Cao, Xuefei, Peng, Xinwen, Sun, Shaoni, Zhong, Linxin, Chen, Wei, Wang, Sha, Sun, Run-Cang
Format Journal Article
LanguageEnglish
Published England Elsevier Ltd 15.03.2015
Subjects
biomass
Catalysis
catalysts
catalytic activity
Cellulose
Cellulose - chemistry
cobalt
Cobalt - chemistry
copper
Copper - chemistry
Degradation correlation
energy efficiency
formic acid
fuels
Glucose
Glucose - chemistry
hydrolysis
Hydrothermal conversion
iron
Iron - chemistry
lactic acid
levulinic acid
manganese
nickel
Nickel - chemistry
screening
sulfates
Sulfates - chemistry
temperature
Transition Elements - chemistry
Transition metal sulfates
xylose
Xylose - chemistry
zinc
Zinc - chemistry
Hydrothermal conversion
Glucose
Degradation correlation
Cellulose
Transition metal sulfates
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Abstract •Zn2+ and Ni2+ showed obvious effect on converting biomass into lactic acid.•Cu2+ and Fe3+ could accelerate the formations of levulinic acid and formic acid.•Positive correlations among xylose, glucose, and cellulose degradation were observed.•HTC of monosaccharide can be used to screen catalysts for biomass upgradation. Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, and Zn2+) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn2+ and Ni2+ showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu2+ and Fe3+, which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.
AbstractList •Zn2+ and Ni2+ showed obvious effect on converting biomass into lactic acid.•Cu2+ and Fe3+ could accelerate the formations of levulinic acid and formic acid.•Positive correlations among xylose, glucose, and cellulose degradation were observed.•HTC of monosaccharide can be used to screen catalysts for biomass upgradation. Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, and Zn2+) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn2+ and Ni2+ showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu2+ and Fe3+, which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.
Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn(2+), Fe(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn(2+) and Ni(2+) showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu(2+) and Fe(3+), which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn(2+), Fe(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn(2+) and Ni(2+) showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu(2+) and Fe(3+), which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.
Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn2+, Fe2+, Fe3+, Co2+, Ni2+, Cu2+, and Zn2+) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn2+ and Ni2+ showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu2+ and Fe3+, which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.
Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with non-catalytic HTC, catalytic HTC shows high energy efficiency on biomass upgradation. In this work, the catalytic performances of various transition metal sulfates (Mn(2+), Fe(2+), Fe(3+), Co(2+), Ni(2+), Cu(2+), and Zn(2+)) in the HTCs of xylose, glucose, and cellulose under different conditions were explored. Among these catalysts, Zn(2+) and Ni(2+) showed obvious effects on the conversions of xylose, glucose, and cellulose into lactic acid, while Cu(2+) and Fe(3+), which could significantly accelerate the hydrolysis of cellulose into glucose at 200°C, displayed high efficiency on converting glucose and cellulose into levulinic acid and formic acid at high temperature. Additionally, significant positive correlative relationships among xylose, glucose, and cellulose degradations were observed. This study is helpful for screening appropriate catalysts for biomass upgradation through catalytic HTC of monosaccharide.
Author Chen, Wei
Peng, Xinwen
Wang, Sha
Cao, Xuefei
Zhong, Linxin
Sun, Shaoni
Sun, Run-Cang
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  fullname: Peng, Xinwen
  organization: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
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  fullname: Sun, Shaoni
  organization: Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China
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  surname: Zhong
  fullname: Zhong, Linxin
  email: lxzhong0611@scut.edu.cn
  organization: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
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  givenname: Wei
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  organization: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
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  surname: Wang
  fullname: Wang, Sha
  organization: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
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  givenname: Run-Cang
  surname: Sun
  fullname: Sun, Run-Cang
  email: rcsun3@bjfu.edu.cn
  organization: State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/25542106$$D View this record in MEDLINE/PubMed
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Keywords Hydrothermal conversion
Glucose
Degradation correlation
Cellulose
Transition metal sulfates
Language English
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Snippet •Zn2+ and Ni2+ showed obvious effect on converting biomass into lactic acid.•Cu2+ and Fe3+ could accelerate the formations of levulinic acid and formic...
Hydrothermal conversion (HTC) is an important thermochemical process to upgrade low-cost biomass into valuable chemicals or fuels. As compared with...
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StartPage 44
SubjectTerms biomass
Catalysis
catalysts
catalytic activity
Cellulose
Cellulose - chemistry
cobalt
Cobalt - chemistry
copper
Copper - chemistry
Degradation correlation
energy efficiency
formic acid
fuels
Glucose
Glucose - chemistry
hydrolysis
Hydrothermal conversion
iron
Iron - chemistry
lactic acid
levulinic acid
manganese
nickel
Nickel - chemistry
screening
sulfates
Sulfates - chemistry
temperature
Transition Elements - chemistry
Transition metal sulfates
xylose
Xylose - chemistry
zinc
Zinc - chemistry
Title Hydrothermal conversion of xylose, glucose, and cellulose under the catalysis of transition metal sulfates
URI https://dx.doi.org/10.1016/j.carbpol.2014.10.069
https://www.ncbi.nlm.nih.gov/pubmed/25542106
https://www.proquest.com/docview/1641018125
https://www.proquest.com/docview/2000278312
Volume 118
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