Role of electrostatic interactions in the adsorption kinetics of nanoparticles at fluid-fluid interfaces
The adsorption of particles to the fluid-fluid interface is a key factor for the stabilization of fluid-fluid interfaces such as those found in emulsions, foams and bijels. However, for the formation of stable particle-laden interfaces, the particles must migrate to the interface from the bulk. Rece...
Saved in:
| Published in | Physical chemistry chemical physics : PCCP Vol. 18; no. 7; pp. 5499 - 5508 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
21.02.2016
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | The adsorption of particles to the fluid-fluid interface is a key factor for the stabilization of fluid-fluid interfaces such as those found in emulsions, foams and bijels. However, for the formation of stable particle-laden interfaces, the particles must migrate to the interface from the bulk. Recent studies show that the adsorption of particles to the interface formed during emulsification is influenced by the surface charge of the particles. To further investigate this phenomenon, we study the effect of the surface charge of the particle on the adsorption kinetics of particles to the oil-water interface. By suspending a drop of aqueous dispersion of charge stabilized nanoparticles in decane, the adsorption dynamics of particles to the decane-water interface is studied using the dynamic surface tension measurements. When the particles are highly charged (low salt), a negligible change in the interface tension is observed indicating that almost no particles are adsorbed. These results show that the charged particles experience an energy barrier when they approach the interface. But when the particle surface charge is screened by the addition of monovalent salt, a significant reduction in surface tension is observed indicating the migration and adsorption of particles to the decane-water interface. We estimate the effective diffusivity of particles to the interface by analyzing the initial decay in the measured surface tension by considering particle laden drops containing different amounts of salt using the modified Ward and Tordai theory. This effective diffusivity is used to calculate the energy barrier for the adsorption of particles to the interface. The energy barrier from the analysis of dynamic surface tension data agrees well with the concept of image charge repulsion which inhibits the adsorption of highly charged particles to the interface. By considering various types of relevant interactions, we derive an analytical expression that qualitatively captures the effect of the surface charge on the equilibrium surface coverage of particles at the drop surface. |
|---|---|
| AbstractList | The adsorption of particles to the fluid-fluid interface is a key factor for the stabilization of fluid-fluid interfaces such as those found in emulsions, foams and bijels. However, for the formation of stable particle-laden interfaces, the particles must migrate to the interface from the bulk. Recent studies show that the adsorption of particles to the interface formed during emulsification is influenced by the surface charge of the particles. To further investigate this phenomenon, we study the effect of the surface charge of the particle on the adsorption kinetics of particles to the oil-water interface. By suspending a drop of aqueous dispersion of charge stabilized nanoparticles in decane, the adsorption dynamics of particles to the decane-water interface is studied using the dynamic surface tension measurements. When the particles are highly charged (low salt), a negligible change in the interface tension is observed indicating that almost no particles are adsorbed. These results show that the charged particles experience an energy barrier when they approach the interface. But when the particle surface charge is screened by the addition of monovalent salt, a significant reduction in surface tension is observed indicating the migration and adsorption of particles to the decane-water interface. We estimate the effective diffusivity of particles to the interface by analyzing the initial decay in the measured surface tension by considering particle laden drops containing different amounts of salt using the modified Ward and Tordai theory. This effective diffusivity is used to calculate the energy barrier for the adsorption of particles to the interface. The energy barrier from the analysis of dynamic surface tension data agrees well with the concept of image charge repulsion which inhibits the adsorption of highly charged particles to the interface. By considering various types of relevant interactions, we derive an analytical expression that qualitatively captures the effect of the surface charge on the equilibrium surface coverage of particles at the drop surface. |
| Author | Basavaraj, Madivala G Muthukuru, Jyothi Sri Mani, Ethayaraja Dugyala, Venkateshwar Rao |
| Author_xml | – sequence: 1 givenname: Venkateshwar Rao surname: Dugyala fullname: Dugyala, Venkateshwar Rao email: basa@iitm.ac.in, ethaya@iitm.ac.in organization: Polymer Engineering and Colloid Science Lab (PECS Lab), Department of Chemical Engineering, Indian Institute of Technology Madras, India. basa@iitm.ac.in ethaya@iitm.ac.in – sequence: 2 givenname: Jyothi Sri surname: Muthukuru fullname: Muthukuru, Jyothi Sri – sequence: 3 givenname: Ethayaraja surname: Mani fullname: Mani, Ethayaraja – sequence: 4 givenname: Madivala G surname: Basavaraj fullname: Basavaraj, Madivala G |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/26863078$$D View this record in MEDLINE/PubMed |
| BookMark | eNqFkclOwzAQhi1URBe48AAoR4QUsOMl8RFFbFIlEIJz5EzGaiCNg-0eeHvSFnrlMKu--Q__zMmkdz0Scs7oNaNc34CEgUotNRyRGROKp5oWYnLoczUl8xA-KKVMMn5CppkqFKd5MSOrV9dh4myCHUL0LkQTW0jaPqI3EFvXh3FI4goT0wTnh-0q-Wx7HLGwPexN7wbjx7HDkJiY2G7TNuku73WsAQyn5NiaLuDZb12Q9_u7t_IxXT4_PJW3yxSEEjEt6rwRslY1YwA5gLEFFzo3tMmKDJFKleUWrNK6tjaTouYC0I4hAawROV-Qy73u4N3XBkOs1m0A7DrTo9uEihWUCkUZV_-juZKMSa35iF7tURgtCh5tNfh2bfx3xWi1fUJVyvJl94RyhC9-dTf1GpsD-uc6_wGED4Yl |
| CitedBy_id | crossref_primary_10_1016_j_cis_2019_102089 crossref_primary_10_1021_acs_langmuir_0c03458 crossref_primary_10_1088_1361_6633_abbcd8 crossref_primary_10_1021_acs_biomac_9b01384 crossref_primary_10_1016_j_apsadv_2023_100460 crossref_primary_10_1016_j_cocis_2018_05_001 crossref_primary_10_1002_cssc_202000965 crossref_primary_10_1021_acs_energyfuels_9b01102 crossref_primary_10_1016_j_colsurfa_2019_05_023 crossref_primary_10_1021_acs_langmuir_9b02139 crossref_primary_10_1103_PhysRevApplied_16_064045 crossref_primary_10_1088_1361_648X_ac0938 crossref_primary_10_1016_j_ijbiomac_2022_09_066 crossref_primary_10_1021_acs_langmuir_2c03369 crossref_primary_10_1016_j_cis_2022_102620 crossref_primary_10_1016_j_colsurfa_2023_131503 crossref_primary_10_1016_j_addma_2023_103943 crossref_primary_10_1016_j_jcis_2021_03_148 crossref_primary_10_1016_j_jcis_2018_08_044 crossref_primary_10_1007_s11947_020_02481_2 crossref_primary_10_1080_10942912_2023_2233707 crossref_primary_10_1016_j_fuel_2018_03_046 crossref_primary_10_1039_C8SM02048E crossref_primary_10_1016_j_cherd_2022_06_006 crossref_primary_10_1021_acs_langmuir_2c00348 crossref_primary_10_1016_j_foodhyd_2023_108997 crossref_primary_10_1021_acs_langmuir_9b01933 crossref_primary_10_1016_j_seppur_2024_127803 crossref_primary_10_1021_acs_langmuir_1c00559 crossref_primary_10_1016_j_colsurfa_2022_128403 crossref_primary_10_1021_acs_langmuir_1c02919 crossref_primary_10_1039_C9NA00506D crossref_primary_10_1016_j_jcis_2017_03_114 crossref_primary_10_1021_acs_langmuir_8b02310 crossref_primary_10_1002_cite_201900049 crossref_primary_10_1039_D2SM00142J crossref_primary_10_1039_C8CP04041A crossref_primary_10_1016_j_molliq_2018_09_049 crossref_primary_10_1016_j_cis_2021_102522 crossref_primary_10_1016_j_jhazmat_2020_122929 crossref_primary_10_1021_acs_langmuir_7b00599 crossref_primary_10_1021_acs_langmuir_3c01579 crossref_primary_10_1021_acs_langmuir_8b01139 crossref_primary_10_1038_s41526_022_00234_3 crossref_primary_10_1016_j_petlm_2019_09_001 crossref_primary_10_1021_acsami_8b17748 crossref_primary_10_1016_j_jcis_2019_07_017 crossref_primary_10_1021_acsanm_7b00356 crossref_primary_10_1007_s41204_019_0065_3 crossref_primary_10_1016_j_chemosphere_2022_136333 crossref_primary_10_1016_j_psep_2022_06_001 crossref_primary_10_1039_C6SM01377E crossref_primary_10_1021_acs_energyfuels_0c02591 crossref_primary_10_1016_j_ijbiomac_2024_133504 crossref_primary_10_1016_j_jcis_2022_01_110 crossref_primary_10_1021_acs_langmuir_0c02339 crossref_primary_10_1021_acs_nanolett_7b03462 crossref_primary_10_1039_C8SC00678D crossref_primary_10_1039_C6FD00036C crossref_primary_10_1016_j_cis_2020_102233 crossref_primary_10_1039_D1PY01333E crossref_primary_10_1021_acs_langmuir_8b00877 crossref_primary_10_1021_acs_langmuir_6b03534 crossref_primary_10_1016_j_jece_2021_106849 |
| Cites_doi | 10.1021/la202954c 10.1039/B604535A 10.1007/s00396-011-2511-z 10.1016/S0001-8686(97)00003-1 10.1006/jcis.1997.5076 10.1002/adfm.201201090 10.1209/epl/i2006-10209-3 10.1021/la4006899 10.1063/1.476167 10.1021/la103046w 10.1016/j.jcis.2005.09.057 10.1007/s11051-011-0565-y 10.1021/la034868p 10.1103/PhysRevLett.95.218301 10.1021/la060693i 10.1021/la00059a055 10.1103/PhysRevE.92.052314 10.1006/jcis.1993.1088 10.1021/la700444a 10.1021/la204017z 10.1021/la990887g 10.1039/c0sm01290d 10.1039/C5FD00136F 10.1021/la020858x 10.1002/adfm.201002562 10.1021/la903817b 10.1021/la402436w 10.1201/9781315274287 10.1039/b816680c 10.1021/la0103822 10.1016/j.cis.2014.09.003 10.1016/0927-7757(96)03650-3 10.1002/ange.200462470 10.1021/la803554u 10.1021/la950928i 10.1016/S0001-8686(02)00069-6 10.1021/la404357j 10.1063/1.1724167 10.1039/c1sm05457k 10.1039/C4SM01881H 10.1021/jz300909z 10.1039/b710060b 10.1021/la060812u 10.1021/acs.langmuir.5b02443 10.1021/la100497h 10.1021/la0203584 |
| ContentType | Journal Article |
| DBID | NPM AAYXX CITATION 7X8 7SR 7U5 8BQ 8FD JG9 L7M |
| DOI | 10.1039/c5cp05959c |
| DatabaseName | PubMed CrossRef MEDLINE - Academic Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | PubMed CrossRef MEDLINE - Academic Materials Research Database Engineered Materials Abstracts Solid State and Superconductivity Abstracts Technology Research Database Advanced Technologies Database with Aerospace METADEX |
| DatabaseTitleList | PubMed CrossRef Materials Research Database MEDLINE - Academic |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1463-9084 |
| EndPage | 5508 |
| ExternalDocumentID | 10_1039_C5CP05959C 26863078 |
| Genre | Journal Article |
| GroupedDBID | --- -DZ -JG -~X 0-7 0R~ 123 29O 2WC 4.4 53G 705 70~ 7~J 87K AAEMU AAIWI AAJAE AAMEH AANOJ AAWGC AAXHV AAXPP ABASK ABDVN ABEMK ABJNI ABPDG ABRYZ ABXOH ACGFO ACGFS ACIWK ACLDK ACNCT ADMRA ADSRN AEFDR AENEX AENGV AESAV AETIL AFLYV AFOGI AFRDS AFVBQ AGEGJ AGKEF AGRSR AGSTE AHGCF ALMA_UNASSIGNED_HOLDINGS ANBJS ANUXI APEMP ASKNT AUDPV AZFZN BLAPV BSQNT C6K CS3 D0L DU5 EBS ECGLT EE0 EF- EJD F5P GGIMP GNO H13 HZ~ H~N IDZ J3G J3I M4U N9A NHB NPM O9- OK1 P2P R7B R7C RAOCF RCNCU RIG RNS ROL RPMJG RRA RRC RSCEA SKA SKF SLH TN5 TWZ UCJ UHB VH6 WH7 YNT 0UZ 1TJ 6TJ 71~ 9M8 AAYXX ACHDF ACMRT AFFNX AHGXI ANLMG ASPBG AVWKF BBWZM CAG CITATION COF EEHRC FEDTE HVGLF H~9 IDY J3H KC5 L-8 MVM NDZJH R56 RCLXC XJT XOL ZCG 7X8 7SR 7U5 8BQ 8FD JG9 L7M |
| ID | FETCH-LOGICAL-c464t-8b7d45b6b11cc7ccaf83497a0d282ee05627fcf699bff254b34cef4ce5ccfa473 |
| ISSN | 1463-9076 |
| IngestDate | Fri Oct 25 03:35:18 EDT 2024 Fri Oct 25 03:38:16 EDT 2024 Fri Aug 23 01:54:58 EDT 2024 Tue Aug 27 13:49:28 EDT 2024 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 7 |
| Language | English |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c464t-8b7d45b6b11cc7ccaf83497a0d282ee05627fcf699bff254b34cef4ce5ccfa473 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| PMID | 26863078 |
| PQID | 1765115993 |
| PQPubID | 23479 |
| PageCount | 10 |
| ParticipantIDs | proquest_miscellaneous_1800460136 proquest_miscellaneous_1765115993 crossref_primary_10_1039_C5CP05959C pubmed_primary_26863078 |
| PublicationCentury | 2000 |
| PublicationDate | 2016-02-21 |
| PublicationDateYYYYMMDD | 2016-02-21 |
| PublicationDate_xml | – month: 02 year: 2016 text: 2016-02-21 day: 21 |
| PublicationDecade | 2010 |
| PublicationPlace | England |
| PublicationPlace_xml | – name: England |
| PublicationTitle | Physical chemistry chemical physics : PCCP |
| PublicationTitleAlternate | Phys Chem Chem Phys |
| PublicationYear | 2016 |
| References | Hiemenz (C5CP05959C-(cit35)/*[position()=1]) 1997 Bergström (C5CP05959C-(cit44)/*[position()=1]) 1997; 70 Kutuzov (C5CP05959C-(cit28)/*[position()=1]) 2007; 9 Reincke (C5CP05959C-(cit36)/*[position()=1]) 2006; 8 Gurkov (C5CP05959C-(cit31)/*[position()=1]) 2011; 289 Binks (C5CP05959C-(cit40)/*[position()=1]) 2013; 29 Ravera (C5CP05959C-(cit32)/*[position()=1]) 1993; 156 Song (C5CP05959C-(cit38)/*[position()=1]) 1991; 7 Lee (C5CP05959C-(cit11)/*[position()=1]) 2013; 23 Garbin (C5CP05959C-(cit24)/*[position()=1]) 2011; 28 Madivala (C5CP05959C-(cit17)/*[position()=1]) 2009; 25 Marinova (C5CP05959C-(cit42)/*[position()=1]) 1996; 12 Du (C5CP05959C-(cit22)/*[position()=1]) 2010; 26 Ferdous (C5CP05959C-(cit23)/*[position()=1]) 2011; 13 Rana (C5CP05959C-(cit29)/*[position()=1]) 2011; 28 Binks (C5CP05959C-(cit7)/*[position()=1]) 2005; 117 Moorkanikkara (C5CP05959C-(cit34)/*[position()=1]) 2006; 296 Paunov (C5CP05959C-(cit47)/*[position()=1]) 2002; 18 Aveyard (C5CP05959C-(cit41)/*[position()=1]) 2003; 100 Wierenga (C5CP05959C-(cit37)/*[position()=1]) 2003; 19 Sun (C5CP05959C-(cit27)/*[position()=1]) 2013; 29 Pushpam (C5CP05959C-(cit14)/*[position()=1]) 2015; 92 Tavacoli (C5CP05959C-(cit12)/*[position()=1]) 2011; 21 Lin (C5CP05959C-(cit46)/*[position()=1]) 2010; 26 Wang (C5CP05959C-(cit4)/*[position()=1]) 2009; 26 Nallamilli (C5CP05959C-(cit13)/*[position()=1]) 2015; 31 Israelachvili (C5CP05959C-(cit45)/*[position()=1]) 2011 Deshmukh (C5CP05959C-(cit21)/*[position()=1]) 2014; 222 Nelson (C5CP05959C-(cit26)/*[position()=1]) 2015; 11 Ward (C5CP05959C-(cit30)/*[position()=1]) 1946; 14 Bhattacharjee (C5CP05959C-(cit43)/*[position()=1]) 1997; 193 Dugyala (C5CP05959C-(cit48)/*[position()=1]) 2015 Binks (C5CP05959C-(cit1)/*[position()=1]) 2001; 17 Pawar (C5CP05959C-(cit3)/*[position()=1]) 2011; 7 Binks (C5CP05959C-(cit8)/*[position()=1]) 2007; 23 Aveyard (C5CP05959C-(cit15)/*[position()=1]) 2000; 16 Kluijtmans (C5CP05959C-(cit39)/*[position()=1]) 1998; 108 Stocco (C5CP05959C-(cit6)/*[position()=1]) 2011; 7 Würger (C5CP05959C-(cit18)/*[position()=1]) 2006; 75 Fujii (C5CP05959C-(cit9)/*[position()=1]) 2006; 22 Bizmark (C5CP05959C-(cit20)/*[position()=1]) 2014; 30 Madivala (C5CP05959C-(cit2)/*[position()=1]) 2009; 5 Chen (C5CP05959C-(cit16)/*[position()=1]) 2005; 95 Horozov (C5CP05959C-(cit19)/*[position()=1]) 2003; 19 Tavacoli (C5CP05959C-(cit10)/*[position()=1]) 2011; 21 Liggieri (C5CP05959C-(cit33)/*[position()=1]) 1996; 114 Wang (C5CP05959C-(cit5)/*[position()=1]) 2012; 3 Glaser (C5CP05959C-(cit25)/*[position()=1]) 2006; 22 |
| References_xml | – volume: 28 start-page: 1663 year: 2011 ident: C5CP05959C-(cit24)/*[position()=1] publication-title: Langmuir doi: 10.1021/la202954c contributor: fullname: Garbin – volume: 8 start-page: 3828 year: 2006 ident: C5CP05959C-(cit36)/*[position()=1] publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/B604535A contributor: fullname: Reincke – volume: 289 start-page: 1905 year: 2011 ident: C5CP05959C-(cit31)/*[position()=1] publication-title: Colloid Polym. Sci. doi: 10.1007/s00396-011-2511-z contributor: fullname: Gurkov – volume: 70 start-page: 125 year: 1997 ident: C5CP05959C-(cit44)/*[position()=1] publication-title: Adv. Colloid Interface Sci. doi: 10.1016/S0001-8686(97)00003-1 contributor: fullname: Bergström – volume: 193 start-page: 273 year: 1997 ident: C5CP05959C-(cit43)/*[position()=1] publication-title: J. Colloid Interface Sci. doi: 10.1006/jcis.1997.5076 contributor: fullname: Bhattacharjee – volume: 23 start-page: 417 year: 2013 ident: C5CP05959C-(cit11)/*[position()=1] publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201201090 contributor: fullname: Lee – volume: 75 start-page: 978 year: 2006 ident: C5CP05959C-(cit18)/*[position()=1] publication-title: EPL (Europhysics Letters) doi: 10.1209/epl/i2006-10209-3 contributor: fullname: Würger – volume: 29 start-page: 4923 year: 2013 ident: C5CP05959C-(cit40)/*[position()=1] publication-title: Langmuir doi: 10.1021/la4006899 contributor: fullname: Binks – volume: 108 start-page: 7469 year: 1998 ident: C5CP05959C-(cit39)/*[position()=1] publication-title: J. Chem. Phys. doi: 10.1063/1.476167 contributor: fullname: Kluijtmans – volume: 26 start-page: 16638 year: 2010 ident: C5CP05959C-(cit46)/*[position()=1] publication-title: Langmuir doi: 10.1021/la103046w contributor: fullname: Lin – volume: 296 start-page: 442 year: 2006 ident: C5CP05959C-(cit34)/*[position()=1] publication-title: J. Colloid Interface Sci. doi: 10.1016/j.jcis.2005.09.057 contributor: fullname: Moorkanikkara – volume: 13 start-page: 6579 year: 2011 ident: C5CP05959C-(cit23)/*[position()=1] publication-title: J. Nanopart. Res. doi: 10.1007/s11051-011-0565-y contributor: fullname: Ferdous – volume: 19 start-page: 8964 year: 2003 ident: C5CP05959C-(cit37)/*[position()=1] publication-title: Langmuir doi: 10.1021/la034868p contributor: fullname: Wierenga – volume: 95 start-page: 218301 year: 2005 ident: C5CP05959C-(cit16)/*[position()=1] publication-title: Phys. Rev. Lett. doi: 10.1103/PhysRevLett.95.218301 contributor: fullname: Chen – volume: 22 start-page: 5227 year: 2006 ident: C5CP05959C-(cit25)/*[position()=1] publication-title: Langmuir doi: 10.1021/la060693i contributor: fullname: Glaser – volume: 7 start-page: 2737 year: 1991 ident: C5CP05959C-(cit38)/*[position()=1] publication-title: Langmuir doi: 10.1021/la00059a055 contributor: fullname: Song – volume: 92 start-page: 052314 year: 2015 ident: C5CP05959C-(cit14)/*[position()=1] publication-title: Physical Review E doi: 10.1103/PhysRevE.92.052314 contributor: fullname: Pushpam – volume: 156 start-page: 109 year: 1993 ident: C5CP05959C-(cit32)/*[position()=1] publication-title: J. Colloid Interface Sci. doi: 10.1006/jcis.1993.1088 contributor: fullname: Ravera – volume: 23 start-page: 8691 year: 2007 ident: C5CP05959C-(cit8)/*[position()=1] publication-title: Langmuir doi: 10.1021/la700444a contributor: fullname: Binks – volume: 28 start-page: 2023 year: 2011 ident: C5CP05959C-(cit29)/*[position()=1] publication-title: Langmuir doi: 10.1021/la204017z contributor: fullname: Rana – volume: 16 start-page: 1969 year: 2000 ident: C5CP05959C-(cit15)/*[position()=1] publication-title: Langmuir doi: 10.1021/la990887g contributor: fullname: Aveyard – volume-title: Intermolecular and surface forces year: 2011 ident: C5CP05959C-(cit45)/*[position()=1] contributor: fullname: Israelachvili – volume: 7 start-page: 1260 year: 2011 ident: C5CP05959C-(cit6)/*[position()=1] publication-title: Soft Matter doi: 10.1039/c0sm01290d contributor: fullname: Stocco – year: 2015 ident: C5CP05959C-(cit48)/*[position()=1] publication-title: Farady discussion doi: 10.1039/C5FD00136F contributor: fullname: Dugyala – volume: 19 start-page: 2822 year: 2003 ident: C5CP05959C-(cit19)/*[position()=1] publication-title: Langmuir doi: 10.1021/la020858x contributor: fullname: Horozov – volume: 21 start-page: 2020 year: 2011 ident: C5CP05959C-(cit10)/*[position()=1] publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201002562 contributor: fullname: Tavacoli – volume: 26 start-page: 5397 year: 2009 ident: C5CP05959C-(cit4)/*[position()=1] publication-title: Langmuir doi: 10.1021/la903817b contributor: fullname: Wang – volume: 29 start-page: 13407 year: 2013 ident: C5CP05959C-(cit27)/*[position()=1] publication-title: Langmuir doi: 10.1021/la402436w contributor: fullname: Sun – volume-title: Principles of Colloid and Surface Chemistry, revised and expanded year: 1997 ident: C5CP05959C-(cit35)/*[position()=1] doi: 10.1201/9781315274287 contributor: fullname: Hiemenz – volume: 5 start-page: 1717 year: 2009 ident: C5CP05959C-(cit2)/*[position()=1] publication-title: Soft Matter doi: 10.1039/b816680c contributor: fullname: Madivala – volume: 17 start-page: 4540 year: 2001 ident: C5CP05959C-(cit1)/*[position()=1] publication-title: Langmuir doi: 10.1021/la0103822 contributor: fullname: Binks – volume: 222 start-page: 215 year: 2014 ident: C5CP05959C-(cit21)/*[position()=1] publication-title: Adv. Colloid Interface Sci. doi: 10.1016/j.cis.2014.09.003 contributor: fullname: Deshmukh – volume: 21 start-page: 2020 year: 2011 ident: C5CP05959C-(cit12)/*[position()=1] publication-title: Adv. Funct. Mater. doi: 10.1002/adfm.201002562 contributor: fullname: Tavacoli – volume: 114 start-page: 351 year: 1996 ident: C5CP05959C-(cit33)/*[position()=1] publication-title: Colloids and surfaces A: physicochemical and engineering aspects doi: 10.1016/0927-7757(96)03650-3 contributor: fullname: Liggieri – volume: 117 start-page: 3788 year: 2005 ident: C5CP05959C-(cit7)/*[position()=1] publication-title: Angew. Chem. doi: 10.1002/ange.200462470 contributor: fullname: Binks – volume: 25 start-page: 2718 year: 2009 ident: C5CP05959C-(cit17)/*[position()=1] publication-title: Langmuir doi: 10.1021/la803554u contributor: fullname: Madivala – volume: 12 start-page: 2045 year: 1996 ident: C5CP05959C-(cit42)/*[position()=1] publication-title: Langmuir doi: 10.1021/la950928i contributor: fullname: Marinova – volume: 100 start-page: 503 year: 2003 ident: C5CP05959C-(cit41)/*[position()=1] publication-title: Adv. Colloid Interface Sci. doi: 10.1016/S0001-8686(02)00069-6 contributor: fullname: Aveyard – volume: 30 start-page: 710 year: 2014 ident: C5CP05959C-(cit20)/*[position()=1] publication-title: Langmuir doi: 10.1021/la404357j contributor: fullname: Bizmark – volume: 14 start-page: 453 year: 1946 ident: C5CP05959C-(cit30)/*[position()=1] publication-title: J. Chem. Phys. doi: 10.1063/1.1724167 contributor: fullname: Ward – volume: 7 start-page: 7710 year: 2011 ident: C5CP05959C-(cit3)/*[position()=1] publication-title: Soft Matter doi: 10.1039/c1sm05457k contributor: fullname: Pawar – volume: 11 start-page: 118 year: 2015 ident: C5CP05959C-(cit26)/*[position()=1] publication-title: Soft matter doi: 10.1039/C4SM01881H contributor: fullname: Nelson – volume: 3 start-page: 2986 year: 2012 ident: C5CP05959C-(cit5)/*[position()=1] publication-title: J. Phys. Chem. Lett. doi: 10.1021/jz300909z contributor: fullname: Wang – volume: 9 start-page: 6351 year: 2007 ident: C5CP05959C-(cit28)/*[position()=1] publication-title: Phys. Chem. Chem. Phys. doi: 10.1039/b710060b contributor: fullname: Kutuzov – volume: 22 start-page: 7512 year: 2006 ident: C5CP05959C-(cit9)/*[position()=1] publication-title: Langmuir doi: 10.1021/la060812u contributor: fullname: Fujii – volume: 31 start-page: 11200 year: 2015 ident: C5CP05959C-(cit13)/*[position()=1] publication-title: Langmuir doi: 10.1021/acs.langmuir.5b02443 contributor: fullname: Nallamilli – volume: 26 start-page: 12518 year: 2010 ident: C5CP05959C-(cit22)/*[position()=1] publication-title: Langmuir doi: 10.1021/la100497h contributor: fullname: Du – volume: 18 start-page: 6946 year: 2002 ident: C5CP05959C-(cit47)/*[position()=1] publication-title: Langmuir doi: 10.1021/la0203584 contributor: fullname: Paunov |
| SSID | ssj0001513 |
| Score | 2.4779797 |
| Snippet | The adsorption of particles to the fluid-fluid interface is a key factor for the stabilization of fluid-fluid interfaces such as those found in emulsions,... The adsorption of particles to the fluid–fluid interface is a key factor for the stabilization of fluid–fluid interfaces such as those found in emulsions,... |
| SourceID | proquest crossref pubmed |
| SourceType | Aggregation Database Index Database |
| StartPage | 5499 |
| SubjectTerms | Adsorption Barriers Charged particles Dynamic tests Dynamics Surface charge Surface chemistry Surface tension |
| Title | Role of electrostatic interactions in the adsorption kinetics of nanoparticles at fluid-fluid interfaces |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/26863078 https://search.proquest.com/docview/1765115993 https://search.proquest.com/docview/1800460136 |
| Volume | 18 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1bb9MwFLZK9wAvaNzLABnBW5XRxLETP05hMBCganRob5Xj2lvXKUFpAipP_Af-Ib-EYztpUjbQ4CE3q04Tn0_H33HOBaHnkhHFJA88QtQIDBTQgymn1NN-qJjiKZgAJlD4_Qd2cBS-PabHvV43Q3BVprvy26VxJf8jVWgDuZoo2X-Q7Pqm0ADnIF_Yg4RhfyUZH9augXUtGxMcNJc2A0Th4hWWjRujmC3zwmmHBfBKm5vZuHCIDIzm2jfOxDXq8wreonaAIPbK3U8b160ukx03ApZNyTh3ZprccsnSLjeMk2QdQvayOlmJc0tXP6lsYWju6VdRDA9F3gq-PK0WVVFZeK0AR_Phx2LeLpzbElTGTV-sRCHO2vUEsRRfTIuLQJrNYaDF8PVud1nDt57QLla61sQhIx5Y7nWe7G6bqyl3UX1XjdOx08XG8u3M62CKxZfOGSNiUq4mNBkD1aQ8aWfGxhvgtwlz7cZoP-ATPm37XkNbAWi8uI-29vYnb96tSQEQK-IC3dxbNZlyCX_R9t7kRn8weCzxmWyjm7XFgvccSm6hnspuo-tJI_U76MzAEOcab8AQd2EIFxhgiFsY4gaGpuMGDLEosQXez-8_7BG3ALyLjl7tT5IDry7h4cmQhaUXp9EspClLfV_KCLSFjknIIzGagamvlGHfkZaacZ5qHdAwJaFUGjYqpRZhRO6hfpZn6gHC2ieaipEeCW1KBnAeCBLpQNGYEcFSPUDPmsGbfnaZWqYXBTRAT5txncIwma9jIlN5tZz6EQPjgwJf_8tvYhts7RM2QPedUNb_FTB4ECDcD6_0HDvoRov6R6hfFpV6DPS2TJ_U0PkFqi2rbg |
| link.rule.ids | 315,783,787,27938,27939 |
| linkProvider | Royal Society of Chemistry |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Role+of+electrostatic+interactions+in+the+adsorption+kinetics+of+nanoparticles+at+fluid%E2%80%93fluid+interfaces&rft.jtitle=Physical+chemistry+chemical+physics+%3A+PCCP&rft.au=Dugyala%2C+Venkateshwar+Rao&rft.au=Muthukuru%2C+Jyothi+Sri&rft.au=Mani%2C+Ethayaraja&rft.au=Basavaraj%2C+Madivala+G.&rft.date=2016-02-21&rft.issn=1463-9076&rft.eissn=1463-9084&rft.volume=18&rft.issue=7&rft.spage=5499&rft.epage=5508&rft_id=info:doi/10.1039%2FC5CP05959C&rft.externalDBID=n%2Fa&rft.externalDocID=10_1039_C5CP05959C |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1463-9076&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1463-9076&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1463-9076&client=summon |