Carboxymethyl cellulose/cellulose nanocrystals immobilized silver nanoparticles as an effective coating to improve barrier and antibacterial properties of paper for food packaging applications

•Cellulose nanocrystals (CNC) immobilized AgNPs (CNC@AgNPs) were synthesized.•CMC/CNC@AgNPs formulations were coated onto paper surface.•CMC/CNC@AgNPs coated papers exhibited enhanced mechanical and barrier properties.•CMC/CNC@AgNPs coated papers showed excellent antibacterial activities.•The obtain...

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Published inCarbohydrate polymers Vol. 252; p. 117156
Main Authors He, Yunqing, Li, Hui, Fei, Xiang, Peng, Lincai
Format Journal Article
LanguageEnglish
Published England Elsevier Ltd 15.01.2021
Subjects
Online AccessGet full text
ISSN0144-8617
1879-1344
1879-1344
DOI10.1016/j.carbpol.2020.117156

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Abstract •Cellulose nanocrystals (CNC) immobilized AgNPs (CNC@AgNPs) were synthesized.•CMC/CNC@AgNPs formulations were coated onto paper surface.•CMC/CNC@AgNPs coated papers exhibited enhanced mechanical and barrier properties.•CMC/CNC@AgNPs coated papers showed excellent antibacterial activities.•The obtained functional paper has promising application in food packaging. A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength, water vapor and air barrier properties, and antibacterial activities of CMC/CNC@AgNPs coated paper improved with the increasing content of CNC@AgNPs. CMC/CNC@AgNPs7 % coated paper exhibited 1.26 times increase in tensile strength, 45.4 % decrease in WVP, 93.3 % reduction in air permeability as well as the best antibacterial activities against E.coli and S.aureus compared with uncoated paper. Moreover, the cumulative release rate of AgNPs from coated paper significantly reduced due to the immobilization effect of CNC on AgNPs. Furthermore, CMC/CNC@AgNPs coated paper was used to package strawberries under ambient conditions. The results showed that coated paper could maintain better strawberries quality compared with unpackaged strawberries and extend the shelf-life of strawberries to 7 days. Therefore, the prepared CMC/CNC@AgNPs coated paper will have a great application prospect in the food packaging.
AbstractList A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength, water vapor and air barrier properties, and antibacterial activities of CMC/CNC@AgNPs coated paper improved with the increasing content of CNC@AgNPs. CMC/CNC@AgNPs7 % coated paper exhibited 1.26 times increase in tensile strength, 45.4 % decrease in WVP, 93.3 % reduction in air permeability as well as the best antibacterial activities against E.coli and S.aureus compared with uncoated paper. Moreover, the cumulative release rate of AgNPs from coated paper significantly reduced due to the immobilization effect of CNC on AgNPs. Furthermore, CMC/CNC@AgNPs coated paper was used to package strawberries under ambient conditions. The results showed that coated paper could maintain better strawberries quality compared with unpackaged strawberries and extend the shelf-life of strawberries to 7 days. Therefore, the prepared CMC/CNC@AgNPs coated paper will have a great application prospect in the food packaging.
A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength, water vapor and air barrier properties, and antibacterial activities of CMC/CNC@AgNPs coated paper improved with the increasing content of CNC@AgNPs. CMC/CNC@AgNPs7 % coated paper exhibited 1.26 times increase in tensile strength, 45.4 % decrease in WVP, 93.3 % reduction in air permeability as well as the best antibacterial activities against E.coli and S.aureus compared with uncoated paper. Moreover, the cumulative release rate of AgNPs from coated paper significantly reduced due to the immobilization effect of CNC on AgNPs. Furthermore, CMC/CNC@AgNPs coated paper was used to package strawberries under ambient conditions. The results showed that coated paper could maintain better strawberries quality compared with unpackaged strawberries and extend the shelf-life of strawberries to 7 days. Therefore, the prepared CMC/CNC@AgNPs coated paper will have a great application prospect in the food packaging.A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength, water vapor and air barrier properties, and antibacterial activities of CMC/CNC@AgNPs coated paper improved with the increasing content of CNC@AgNPs. CMC/CNC@AgNPs7 % coated paper exhibited 1.26 times increase in tensile strength, 45.4 % decrease in WVP, 93.3 % reduction in air permeability as well as the best antibacterial activities against E.coli and S.aureus compared with uncoated paper. Moreover, the cumulative release rate of AgNPs from coated paper significantly reduced due to the immobilization effect of CNC on AgNPs. Furthermore, CMC/CNC@AgNPs coated paper was used to package strawberries under ambient conditions. The results showed that coated paper could maintain better strawberries quality compared with unpackaged strawberries and extend the shelf-life of strawberries to 7 days. Therefore, the prepared CMC/CNC@AgNPs coated paper will have a great application prospect in the food packaging.
•Cellulose nanocrystals (CNC) immobilized AgNPs (CNC@AgNPs) were synthesized.•CMC/CNC@AgNPs formulations were coated onto paper surface.•CMC/CNC@AgNPs coated papers exhibited enhanced mechanical and barrier properties.•CMC/CNC@AgNPs coated papers showed excellent antibacterial activities.•The obtained functional paper has promising application in food packaging. A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength, water vapor and air barrier properties, and antibacterial activities of CMC/CNC@AgNPs coated paper improved with the increasing content of CNC@AgNPs. CMC/CNC@AgNPs7 % coated paper exhibited 1.26 times increase in tensile strength, 45.4 % decrease in WVP, 93.3 % reduction in air permeability as well as the best antibacterial activities against E.coli and S.aureus compared with uncoated paper. Moreover, the cumulative release rate of AgNPs from coated paper significantly reduced due to the immobilization effect of CNC on AgNPs. Furthermore, CMC/CNC@AgNPs coated paper was used to package strawberries under ambient conditions. The results showed that coated paper could maintain better strawberries quality compared with unpackaged strawberries and extend the shelf-life of strawberries to 7 days. Therefore, the prepared CMC/CNC@AgNPs coated paper will have a great application prospect in the food packaging.
ArticleNumber 117156
Author Peng, Lincai
Li, Hui
He, Yunqing
Fei, Xiang
Author_xml – sequence: 1
  givenname: Yunqing
  surname: He
  fullname: He, Yunqing
  organization: Faculty of Agriculture and Food, Kunming University of Science and Technology, Kunming, 650500, China
– sequence: 2
  givenname: Hui
  surname: Li
  fullname: Li, Hui
  email: lihuiscut@126.com
  organization: Faculty of Agriculture and Food, Kunming University of Science and Technology, Kunming, 650500, China
– sequence: 3
  givenname: Xiang
  surname: Fei
  fullname: Fei, Xiang
  organization: Faculty of Agriculture and Food, Kunming University of Science and Technology, Kunming, 650500, China
– sequence: 4
  givenname: Lincai
  surname: Peng
  fullname: Peng, Lincai
  email: penglincai@kust.edu.cn
  organization: Faculty of Chemical Engineering, Kunming University of Science and Technology, Kunming, 650500, China
BackLink https://www.ncbi.nlm.nih.gov/pubmed/33183607$$D View this record in MEDLINE/PubMed
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ISSN 0144-8617
1879-1344
IngestDate Fri Jul 11 06:51:20 EDT 2025
Fri Jul 11 01:42:25 EDT 2025
Thu Apr 03 07:07:49 EDT 2025
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Fri Feb 23 02:41:16 EST 2024
IsPeerReviewed true
IsScholarly true
Keywords Carboxymethyl cellulose
Barrier properties
Antibacterial activity
Cellulose nanocrystals
Silver nanoparticles
Language English
License Copyright © 2020 Elsevier Ltd. All rights reserved.
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crossref_citationtrail_10_1016_j_carbpol_2020_117156
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  year: 2021
  text: 2021-01-15
  day: 15
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PublicationTitle Carbohydrate polymers
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Snippet •Cellulose nanocrystals (CNC) immobilized AgNPs (CNC@AgNPs) were synthesized.•CMC/CNC@AgNPs formulations were coated onto paper surface.•CMC/CNC@AgNPs coated...
A new natural formulation composed of CMC and various contents of CNC immobilized AgNPs (CNC@AgNPs) was developed for paper coating. The mechanical strength,...
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SubjectTerms air
Anti-Bacterial Agents - pharmacology
Antibacterial activity
Barrier properties
Carboxymethyl cellulose
carboxymethylcellulose
Carboxymethylcellulose Sodium - chemistry
Cellulose nanocrystals
Escherichia coli - drug effects
Food Packaging
Metal Nanoparticles - chemistry
Nanocomposites - chemistry
nanocrystals
nanosilver
Permeability
shelf life
Silver - pharmacology
Silver nanoparticles
Staphylococcus aureus - drug effects
Steam
Tensile Strength
water vapor
Title Carboxymethyl cellulose/cellulose nanocrystals immobilized silver nanoparticles as an effective coating to improve barrier and antibacterial properties of paper for food packaging applications
URI https://dx.doi.org/10.1016/j.carbpol.2020.117156
https://www.ncbi.nlm.nih.gov/pubmed/33183607
https://www.proquest.com/docview/2460771076
https://www.proquest.com/docview/2636426076
Volume 252
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