Adsorption kinetic models: Physical meanings, applications, and solving methods

[Display omitted] •Adsorption empirical kinetic models and mass transfer kinetic models were reviewed.•The physical meanings and applications of 16 adsorption kinetic models were analyzed.•The model validity evaluation equations were summarized based on literature.•A user interface for solving kinet...

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Published in	Journal of hazardous materials Vol. 390; p. 122156
Main Authors	Wang, Jianlong, Guo, Xuan
Format	Journal Article
Language	English
Published	Netherlands Elsevier B.V 15.05.2020
Subjects	active sites adsorbents Adsorption computer software empirical models equations Kinetic model kinetics mass transfer model validation Physical meaning Solving method user interface wastewater treatment Kinetic model Adsorption Solving method Physical meaning
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Abstract	[Display omitted] •Adsorption empirical kinetic models and mass transfer kinetic models were reviewed.•The physical meanings and applications of 16 adsorption kinetic models were analyzed.•The model validity evaluation equations were summarized based on literature.•A user interface for solving kinetic models was developed based on Excel software. Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process.
AbstractList	Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process.Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process. Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process. [Display omitted] •Adsorption empirical kinetic models and mass transfer kinetic models were reviewed.•The physical meanings and applications of 16 adsorption kinetic models were analyzed.•The model validity evaluation equations were summarized based on literature.•A user interface for solving kinetic models was developed based on Excel software. Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have been used to evaluate the performance of the adsorbent and to investigate the adsorption mass transfer mechanisms. However, the physical meanings and the solving methods of the kinetic models have not been well established. The proper interpretation of the physical meanings and the standard solving methods for the adsorption kinetic models are very important for the applications of the kinetic models. This paper mainly focused on the physical meanings, applications, as well as the solving methods of 16 adsorption kinetic models. Firstly, the mathematical derivations, physical meanings and applications of the adsorption reaction models, the empirical models, the diffusion models, and the models for adsorption onto active sites were analyzed and discussed in detail. Secondly, the model validity evaluation equations were summarized based on literature. Thirdly, a convenient user interface (UI) for solving the kinetic models was developed based on Excel software and provided in supplementary information, which is helpful for readers to simulate the adsorption kinetic process.
ArticleNumber	122156
Author	Wang, Jianlong Guo, Xuan
Author_xml	– sequence: 1 givenname: Jianlong orcidid: 0000-0001-9572-851X surname: Wang fullname: Wang, Jianlong email: wangjl@mail.tsinghua.edu.cn, wangjl@tsinghua.edu.cn organization: Collaborative Innovation Center for Advanced Nuclear Energy Technology, INET, Tsinghua University, Beijing 100084, PR China – sequence: 2 givenname: Xuan surname: Guo fullname: Guo, Xuan organization: Collaborative Innovation Center for Advanced Nuclear Energy Technology, INET, Tsinghua University, Beijing 100084, PR China
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/32006847$$D View this record in MEDLINE/PubMed
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Snippet	[Display omitted] •Adsorption empirical kinetic models and mass transfer kinetic models were reviewed.•The physical meanings and applications of 16 adsorption... Adsorption technology has been widely applied in water and wastewater treatment, due to its low cost and high efficiency. The adsorption kinetic models have...
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SubjectTerms	active sites adsorbents Adsorption computer software empirical models equations Kinetic model kinetics mass transfer model validation Physical meaning Solving method user interface wastewater treatment
Title	Adsorption kinetic models: Physical meanings, applications, and solving methods
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