Determination of the mass-transport properties of vanadium ions through the porous electrodes of vanadium redox flow batteries
This work is concerned with the determination of two critical constitutive properties for mass transport of ions through porous electrodes saturated with a liquid electrolyte solution. One is the effective diffusivity that is required to model the mass transport at the representative element volume...
Saved in:
| Published in | Physical chemistry chemical physics : PCCP Vol. 15; no. 26; pp. 1841 - 1848 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
14.07.2013
|
| Subjects | |
| Online Access | Get full text |
Cover
Loading…
| Abstract | This work is concerned with the determination of two critical constitutive properties for mass transport of ions through porous electrodes saturated with a liquid electrolyte solution. One is the effective diffusivity that is required to model the mass transport at the representative element volume (REV) level of porous electrodes in the framework of Darcy's law, while the other is the pore-level mass-transfer coefficient for modeling the mass transport from the REV level to the solid surfaces of pores induced by redox reactions. Based on the theoretical framework of mass transport through the electrodes of vanadium redox flow batteries (VRFBs), unique experimental setups for electrochemically determining the two transport properties by measuring limiting current densities are devised. The effective diffusivity and the pore-level mass-transfer coefficient through the porous electrode made of graphite felt, a typical material for VRFB electrodes, are measured at different electrolyte flow rates. The correlation equations, respectively, for the effective diffusivity and the pore-level mass-transfer coefficient are finally proposed based on the experimental data.
The proposed correlation equation for the effective diffusivity of vanadium ions through the porous electrode includes the effects of both the porous electrode structure and flow dispersion, in which the effect of flow dispersion becomes more significant with an increase in flow rates. |
|---|---|
| AbstractList | This work is concerned with the determination of two critical constitutive properties for mass transport of ions through porous electrodes saturated with a liquid electrolyte solution. One is the effective diffusivity that is required to model the mass transport at the representative element volume (REV) level of porous electrodes in the framework of Darcy's law, while the other is the pore-level mass-transfer coefficient for modeling the mass transport from the REV level to the solid surfaces of pores induced by redox reactions. Based on the theoretical framework of mass transport through the electrodes of vanadium redox flow batteries (VRFBs), unique experimental setups for electrochemically determining the two transport properties by measuring limiting current densities are devised. The effective diffusivity and the pore-level mass-transfer coefficient through the porous electrode made of graphite felt, a typical material for VRFB electrodes, are measured at different electrolyte flow rates. The correlation equations, respectively, for the effective diffusivity and the pore-level mass-transfer coefficient are finally proposed based on the experimental data. This work is concerned with the determination of two critical constitutive properties for mass transport of ions through porous electrodes saturated with a liquid electrolyte solution. One is the effective diffusivity that is required to model the mass transport at the representative element volume (REV) level of porous electrodes in the framework of Darcy's law, while the other is the pore-level mass-transfer coefficient for modeling the mass transport from the REV level to the solid surfaces of pores induced by redox reactions. Based on the theoretical framework of mass transport through the electrodes of vanadium redox flow batteries (VRFBs), unique experimental setups for electrochemically determining the two transport properties by measuring limiting current densities are devised. The effective diffusivity and the pore-level mass-transfer coefficient through the porous electrode made of graphite felt, a typical material for VRFB electrodes, are measured at different electrolyte flow rates. The correlation equations, respectively, for the effective diffusivity and the pore-level mass-transfer coefficient are finally proposed based on the experimental data. The proposed correlation equation for the effective diffusivity of vanadium ions through the porous electrode includes the effects of both the porous electrode structure and flow dispersion, in which the effect of flow dispersion becomes more significant with an increase in flow rates. |
| Author | Xu, Qian Zhao, T.S |
| AuthorAffiliation | The Hong Kong University of Science and Technology Department of Mechanical Engineering |
| AuthorAffiliation_xml | – name: The Hong Kong University of Science and Technology – name: Department of Mechanical Engineering |
| Author_xml | – sequence: 1 givenname: Qian surname: Xu fullname: Xu, Qian – sequence: 2 givenname: T.S surname: Zhao fullname: Zhao, T.S |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27465581$$DView record in Pascal Francis https://www.ncbi.nlm.nih.gov/pubmed/23698744$$D View this record in MEDLINE/PubMed |
| BookMark | eNqF0UlP3TAQAGALgdjaC_dW4YBUIaX1Fjs-ImgBCYkLnCMvk5IqiVPbYbn0t2N4j4foAU62NN8s9uyg9dGPgNAewd8JZuqHZXaqiOJcr6FtwgUrFa75-uouxRbaifEPxphUhG2iLcqEqiXn2-jfCSQIQzfq1Pmx8G2RbqAYdIxlCnqMkw-pmIKfIKQO4hO41aN23TwUOSFmHvz8--Y5LWM_xwJ6sCl49x8P4Px90fb-rjA65a653ie00eo-wufluYuuf_28Oj4rLy5Pz4-PLkrLBU9lxYzNw9dC1NQIRbVU0lWcUSsUNpJw7JQ0wjnKJLQgqDKY0RqocboVtWG76Nuibn7K3xliaoYuWuh7PUIeuSGVkIRxwunHlAlZ4TyEzPRwQW3wMQZomyl0gw4PDcHN02qa19Vk_HVZdzYDuBV92UUGB0ugo9V9m7_fdvHVSS6qqibZfVm4EO0q-qbR_nvxZnItewQ8F694 |
| CitedBy_id | crossref_primary_10_1016_j_apenergy_2014_05_034 crossref_primary_10_1007_s11356_018_2830_4 crossref_primary_10_1016_j_pecs_2015_02_001 crossref_primary_10_1016_j_coelec_2019_05_007 crossref_primary_10_1016_j_jelechem_2015_03_029 crossref_primary_10_1038_s41598_017_00585_y crossref_primary_10_1016_j_jpowsour_2020_228817 crossref_primary_10_1016_j_jpowsour_2022_232084 crossref_primary_10_1016_j_apenergy_2014_06_077 crossref_primary_10_1149_1945_7111_aba36b crossref_primary_10_3390_batteries9050253 crossref_primary_10_1016_j_electacta_2021_138725 crossref_primary_10_1016_j_est_2023_108734 crossref_primary_10_1016_j_jpowsour_2022_231904 crossref_primary_10_1002_ente_202400244 crossref_primary_10_1016_j_ensm_2020_06_012 crossref_primary_10_1149_1945_7111_ac975f crossref_primary_10_1016_j_apenergy_2016_07_134 crossref_primary_10_1016_j_ces_2018_10_049 crossref_primary_10_1149_2_0601805jes crossref_primary_10_1149_2_0681816jes crossref_primary_10_1002_cite_201800164 crossref_primary_10_1039_D0SE00667J crossref_primary_10_1016_j_cej_2020_124753 crossref_primary_10_1149_2_0212001JES crossref_primary_10_1016_j_est_2018_05_012 crossref_primary_10_1039_D0SE00675K crossref_primary_10_1016_j_xcrp_2020_100102 crossref_primary_10_1016_j_jpowsour_2021_230192 crossref_primary_10_1002_cssc_202300303 crossref_primary_10_1016_j_jpowsour_2017_08_075 crossref_primary_10_1002_ente_201600016 crossref_primary_10_1016_j_electacta_2021_139404 crossref_primary_10_1039_C7CP07456E crossref_primary_10_1149_2_0201711jes crossref_primary_10_1002_ente_202300175 crossref_primary_10_1149_1945_7111_ac99a2 crossref_primary_10_1149_2_0741712jes crossref_primary_10_1016_j_energy_2024_130237 crossref_primary_10_1016_j_electacta_2022_141043 crossref_primary_10_1115_1_4046661 crossref_primary_10_1016_j_jpowsour_2019_226920 crossref_primary_10_1002_ente_202000708 crossref_primary_10_1149_2_1031714jes crossref_primary_10_1115_1_4038555 crossref_primary_10_1016_j_apenergy_2021_117678 crossref_primary_10_1299_transjsme_16_00458 crossref_primary_10_1016_j_est_2022_104003 crossref_primary_10_1149_2_0611910jes crossref_primary_10_1002_aenm_202000758 crossref_primary_10_1016_j_apenergy_2018_05_124 crossref_primary_10_1016_j_apenergy_2016_05_048 crossref_primary_10_1149_1945_7111_ac6aea crossref_primary_10_1016_j_jpowsour_2016_11_040 crossref_primary_10_1016_j_electacta_2019_134799 |
| Cites_doi | 10.1016/j.electacta.2012.06.065 10.1149/2.091206jes 10.1016/j.ssnmr.2011.11.005 10.1039/c2cc31433a 10.1016/j.jpowsour.2012.06.072 10.1002/bit.260480623 10.1016/0013-4686(90)85008-B 10.1016/j.jpowsour.2010.12.032 10.1016/j.memsci.2007.03.042 10.1016/j.jpowsour.2011.10.102 10.1149/1.2086573 10.1149/1.2109035 10.1039/c2ra20668d 10.1098/rspa.1956.0065 10.1016/j.jpowsour.2012.02.047 10.1016/j.electacta.2009.06.086 10.1016/j.energy.2010.03.060 10.1016/j.jpowsour.2011.12.026 10.1016/j.jpowsour.2010.01.015 10.1016/j.jpowsour.2008.12.040 10.1039/c2ee22749e 10.1016/j.electacta.2012.05.099 10.1002/elan.201100181 10.1016/j.electacta.2008.05.067 10.1016/j.jpowsour.2006.02.095 10.1039/c1ee01776d 10.1016/S0017-9310(98)00120-3 10.1149/2.F06103if 10.4152/pea.200903381 10.1016/0009-2509(79)85064-2 10.1021/es0505043 10.1007/s10800-011-0335-7 10.1146/annurev-chembioeng-061010-114116 10.1039/c1ee01249e 10.1002/aenm.201100008 10.1017/S0022112089001679 10.1021/jp054092w |
| ContentType | Journal Article |
| Copyright | 2014 INIST-CNRS |
| Copyright_xml | – notice: 2014 INIST-CNRS |
| DBID | IQODW NPM AAYXX CITATION 7X8 7SP 7TB 7U5 8FD FR3 L7M |
| DOI | 10.1039/c3cp51944a |
| DatabaseName | Pascal-Francis PubMed CrossRef MEDLINE - Academic Electronics & Communications Abstracts Mechanical & Transportation Engineering Abstracts Solid State and Superconductivity Abstracts Technology Research Database Engineering Research Database Advanced Technologies Database with Aerospace |
| DatabaseTitle | PubMed CrossRef MEDLINE - Academic Solid State and Superconductivity Abstracts Engineering Research Database Technology Research Database Mechanical & Transportation Engineering Abstracts Advanced Technologies Database with Aerospace Electronics & Communications Abstracts |
| DatabaseTitleList | Solid State and Superconductivity Abstracts MEDLINE - Academic PubMed |
| Database_xml | – sequence: 1 dbid: NPM name: PubMed url: https://proxy.k.utb.cz/login?url=http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?db=PubMed sourceTypes: Index Database |
| DeliveryMethod | fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1463-9084 |
| EndPage | 1848 |
| ExternalDocumentID | 10_1039_c3cp51944a 23698744 27465581 c3cp51944a |
| Genre | Journal Article |
| GroupedDBID | --- -DZ -JG -~X 0-7 0R~ 0UZ 123 1TJ 29O 2WC 4.4 53G 6TJ 705 70J 70~ 71~ 7~J 87K 8W4 9M8 AAEMU AAGNR AAIWI AANOJ AAXPP ABASK ABDVN ABFLS ABGFH ABRYZ ACGFO ACGFS ACHDF ACHRU ACIWK ACLDK ACNCT ADMRA ADSRN AENEX AFDAS AFFNX AFMIJ AFOGI AFVBQ AGKEF AGRSR AGSTE AHGVY AHGXI ALMA_UNASSIGNED_HOLDINGS ANLMG ANUXI ASKNT ASPBG AUDPV AVWKF AZFZN BBWZM BLAPV BSQNT C6K CAG COF CS3 D0L DU5 EBS ECGLT EE0 EF- EJD F5P FEDTE GNO H13 HVGLF HZ~ H~9 H~N IDY IDZ IPNFZ IQODW J3G J3H J3I KC5 L-8 M4U MVM N9A NDZJH NHB O9- OK1 P2P R56 R7B R7C RCLXC RCNCU RIG RNS ROL RPMJG RRA RRC RSCEA SKA SKF SLH TN5 TWZ UCJ UHB VH6 VOH WH7 XFK XJT XOL YNT ZCG AAJAE AAMEH AAWGC AAXHV ABEMK ABJNI ABPDG ABXOH AEFDR AENGV AESAV AETIL AFLYV AFRDS AGEGJ AHGCF ANBJS APEMP GGIMP NPM RAOCF AAYXX ACMRT CITATION EEHRC 7X8 7SP 7TB 7U5 8FD FR3 L7M |
| ID | FETCH-LOGICAL-c464t-53bc00186682b692a797d5432c690b7140d97b6dd237efe629b0328e2bdaf68b3 |
| ISSN | 1463-9076 |
| IngestDate | Wed Jul 24 19:41:32 EDT 2024 Wed Jul 24 17:55:39 EDT 2024 Fri Aug 23 01:54:11 EDT 2024 Sat Sep 28 08:08:48 EDT 2024 Thu Nov 24 18:35:42 EST 2022 Sat Jun 01 02:25:55 EDT 2019 Fri May 20 01:53:05 EDT 2016 |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 26 |
| Keywords | Electrodes Transition metal Transport properties Porous material Vanadium Vanadium ion |
| Language | English |
| License | CC BY 4.0 |
| LinkModel | OpenURL |
| MergedId | FETCHMERGED-LOGICAL-c464t-53bc00186682b692a797d5432c690b7140d97b6dd237efe629b0328e2bdaf68b3 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 ObjectType-Article-2 ObjectType-Feature-1 |
| PMID | 23698744 |
| PQID | 1367506927 |
| PQPubID | 23479 |
| PageCount | 8 |
| ParticipantIDs | pascalfrancis_primary_27465581 rsc_primary_c3cp51944a proquest_miscellaneous_1567134142 pubmed_primary_23698744 proquest_miscellaneous_1367506927 crossref_primary_10_1039_c3cp51944a |
| PublicationCentury | 2000 |
| PublicationDate | 2013-07-14 |
| PublicationDateYYYYMMDD | 2013-07-14 |
| PublicationDate_xml | – month: 07 year: 2013 text: 2013-07-14 day: 14 |
| PublicationDecade | 2010 |
| PublicationPlace | Cambridge |
| PublicationPlace_xml | – name: Cambridge – name: England |
| PublicationTitle | Physical chemistry chemical physics : PCCP |
| PublicationTitleAlternate | Phys Chem Chem Phys |
| PublicationYear | 2013 |
| Publisher | Royal Society of Chemistry |
| Publisher_xml | – name: Royal Society of Chemistry |
| References | Soloveichik (c3cp51944a-(cit1)/*[position()=1]) 2011; 2 Aaron (c3cp51944a-(cit22)/*[position()=1]) 2012; 206 Shah (c3cp51944a-(cit23)/*[position()=1]) 2008; 53 de Leon (c3cp51944a-(cit2)/*[position()=1]) 2006; 160 Delanghe (c3cp51944a-(cit33)/*[position()=1]) 1990; 35 Luo (c3cp51944a-(cit27)/*[position()=1]) 2005; 109 Yang (c3cp51944a-(cit34)/*[position()=1]) 1995; 48 Nguyen (c3cp51944a-(cit3)/*[position()=1]) 2010 Li (c3cp51944a-(cit14)/*[position()=1]) 2011; 1 Wu (c3cp51944a-(cit12)/*[position()=1]) 2012; 78 Han (c3cp51944a-(cit17)/*[position()=1]) 2011; 4 Tsai (c3cp51944a-(cit8)/*[position()=1]) 2012; 77 Tsai (c3cp51944a-(cit10)/*[position()=1]) 2011; 23 Yao (c3cp51944a-(cit11)/*[position()=1]) 2012; 218 Cho (c3cp51944a-(cit31)/*[position()=1]) 2005; 39 Qiu (c3cp51944a-(cit28)/*[position()=1]) 2007; 297 Verbrugge (c3cp51944a-(cit25)/*[position()=1]) 1990; 137 Amiri (c3cp51944a-(cit41)/*[position()=1]) 1998; 41 Vijayakumar (c3cp51944a-(cit16)/*[position()=1]) 2012; 42 Wei (c3cp51944a-(cit18)/*[position()=1]) 2012; 208 Aris (c3cp51944a-(cit36)/*[position()=1]) 1956; 235 Kim (c3cp51944a-(cit9)/*[position()=1]) 2012; 48 Jia (c3cp51944a-(cit29)/*[position()=1]) 2012; 203 Vynnycky (c3cp51944a-(cit26)/*[position()=1]) 2011; 36 Armaroli (c3cp51944a-(cit5)/*[position()=1]) 2011; 4 Wakao (c3cp51944a-(cit40)/*[position()=1]) 1979; 34 Zhao (c3cp51944a-(cit19)/*[position()=1]) 2012; 2 Jia (c3cp51944a-(cit13)/*[position()=1]) 2012; 159 Schreiber (c3cp51944a-(cit4)/*[position()=1]) 2012; 206 Jia (c3cp51944a-(cit20)/*[position()=1]) 2012; 203 Matlosz (c3cp51944a-(cit32)/*[position()=1]) 1986; 133 Nava (c3cp51944a-(cit35)/*[position()=1]) 2009; 27 You (c3cp51944a-(cit24)/*[position()=1]) 2009; 54 Aaron (c3cp51944a-(cit21)/*[position()=1]) 2011; 41 Teng (c3cp51944a-(cit15)/*[position()=1]) 2009; 189 Shao (c3cp51944a-(cit7)/*[position()=1]) 2010; 195 Araujo (c3cp51944a-(cit6)/*[position()=1]) 2012; 5 Frankel (c3cp51944a-(cit37)/*[position()=1]) 1989; 204 |
| References_xml | – issn: 2007 publication-title: Microfluidics Theory and Simulation Course Report doi: Jarlgaard – issn: 2011 publication-title: MPhil Thesis doi: Pant – volume: 78 start-page: 475 year: 2012 ident: c3cp51944a-(cit12)/*[position()=1] publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2012.06.065 contributor: fullname: Wu – volume: 159 start-page: A843 year: 2012 ident: c3cp51944a-(cit13)/*[position()=1] publication-title: J. Electrochem. Soc. doi: 10.1149/2.091206jes contributor: fullname: Jia – volume: 42 start-page: 71 year: 2012 ident: c3cp51944a-(cit16)/*[position()=1] publication-title: Solid State Nucl. Magn. Reson. doi: 10.1016/j.ssnmr.2011.11.005 contributor: fullname: Vijayakumar – volume: 48 start-page: 5455 year: 2012 ident: c3cp51944a-(cit9)/*[position()=1] publication-title: Chem. Commun. doi: 10.1039/c2cc31433a contributor: fullname: Kim – volume: 218 start-page: 455 year: 2012 ident: c3cp51944a-(cit11)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2012.06.072 contributor: fullname: Yao – volume: 48 start-page: 737 year: 1995 ident: c3cp51944a-(cit34)/*[position()=1] publication-title: Biotechnol. Bioeng. doi: 10.1002/bit.260480623 contributor: fullname: Yang – volume: 35 start-page: 1369 year: 1990 ident: c3cp51944a-(cit33)/*[position()=1] publication-title: Electrochim. Acta doi: 10.1016/0013-4686(90)85008-B contributor: fullname: Delanghe – volume: 206 start-page: 483 year: 2012 ident: c3cp51944a-(cit4)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2010.12.032 contributor: fullname: Schreiber – volume: 297 start-page: 174 year: 2007 ident: c3cp51944a-(cit28)/*[position()=1] publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2007.03.042 contributor: fullname: Qiu – volume: 203 start-page: 190 year: 2012 ident: c3cp51944a-(cit20)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2011.10.102 contributor: fullname: Jia – volume: 137 start-page: 886 year: 1990 ident: c3cp51944a-(cit25)/*[position()=1] publication-title: J. Electrochem. Soc. doi: 10.1149/1.2086573 contributor: fullname: Verbrugge – volume: 133 start-page: 1850 year: 1986 ident: c3cp51944a-(cit32)/*[position()=1] publication-title: J. Electrochem. Soc. doi: 10.1149/1.2109035 contributor: fullname: Matlosz – volume: 2 start-page: 5554 year: 2012 ident: c3cp51944a-(cit19)/*[position()=1] publication-title: RSC Adv. doi: 10.1039/c2ra20668d contributor: fullname: Zhao – volume: 235 start-page: 67 year: 1956 ident: c3cp51944a-(cit36)/*[position()=1] publication-title: Proc. R. Soc. London, Ser. A doi: 10.1098/rspa.1956.0065 contributor: fullname: Aris – volume: 208 start-page: 421 year: 2012 ident: c3cp51944a-(cit18)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2012.02.047 contributor: fullname: Wei – volume: 54 start-page: 6827 year: 2009 ident: c3cp51944a-(cit24)/*[position()=1] publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2009.06.086 contributor: fullname: You – volume: 36 start-page: 2242 year: 2011 ident: c3cp51944a-(cit26)/*[position()=1] publication-title: Energy doi: 10.1016/j.energy.2010.03.060 contributor: fullname: Vynnycky – volume: 206 start-page: 450 year: 2012 ident: c3cp51944a-(cit22)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2011.12.026 contributor: fullname: Aaron – volume: 195 start-page: 4375 year: 2010 ident: c3cp51944a-(cit7)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2010.01.015 contributor: fullname: Shao – volume: 189 start-page: 1240 year: 2009 ident: c3cp51944a-(cit15)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2008.12.040 contributor: fullname: Teng – volume: 5 start-page: 9534 year: 2012 ident: c3cp51944a-(cit6)/*[position()=1] publication-title: Energy Environ. Sci. doi: 10.1039/c2ee22749e contributor: fullname: Araujo – volume: 77 start-page: 232 year: 2012 ident: c3cp51944a-(cit8)/*[position()=1] publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2012.05.099 contributor: fullname: Tsai – volume: 23 start-page: 2139 year: 2011 ident: c3cp51944a-(cit10)/*[position()=1] publication-title: Electroanalysis doi: 10.1002/elan.201100181 contributor: fullname: Tsai – volume: 53 start-page: 8087 year: 2008 ident: c3cp51944a-(cit23)/*[position()=1] publication-title: Electrochim. Acta doi: 10.1016/j.electacta.2008.05.067 contributor: fullname: Shah – volume: 160 start-page: 716 year: 2006 ident: c3cp51944a-(cit2)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2006.02.095 contributor: fullname: de Leon – volume: 4 start-page: 4710 year: 2011 ident: c3cp51944a-(cit17)/*[position()=1] publication-title: Energy Environ. Sci. doi: 10.1039/c1ee01776d contributor: fullname: Han – volume: 203 start-page: 190 year: 2012 ident: c3cp51944a-(cit29)/*[position()=1] publication-title: J. Power Sources doi: 10.1016/j.jpowsour.2011.10.102 contributor: fullname: Jia – volume: 41 start-page: 4259 year: 1998 ident: c3cp51944a-(cit41)/*[position()=1] publication-title: Int. J. Heat Mass Transfer doi: 10.1016/S0017-9310(98)00120-3 contributor: fullname: Amiri – start-page: 54 year: 2010 ident: c3cp51944a-(cit3)/*[position()=1] publication-title: Electrochem. Soc. Interface doi: 10.1149/2.F06103if contributor: fullname: Nguyen – volume: 27 start-page: 381 year: 2009 ident: c3cp51944a-(cit35)/*[position()=1] publication-title: Port. Electrochim. Acta doi: 10.4152/pea.200903381 contributor: fullname: Nava – volume: 34 start-page: 325 year: 1979 ident: c3cp51944a-(cit40)/*[position()=1] publication-title: Chem. Eng. Sci. doi: 10.1016/0009-2509(79)85064-2 contributor: fullname: Wakao – volume: 39 start-page: 7883 year: 2005 ident: c3cp51944a-(cit31)/*[position()=1] publication-title: Environ. Sci. Technol. doi: 10.1021/es0505043 contributor: fullname: Cho – volume: 41 start-page: 1175 year: 2011 ident: c3cp51944a-(cit21)/*[position()=1] publication-title: J. Appl. Electrochem. doi: 10.1007/s10800-011-0335-7 contributor: fullname: Aaron – volume: 2 start-page: 503 year: 2011 ident: c3cp51944a-(cit1)/*[position()=1] publication-title: Annu. Rev. Chem. Biomol. Eng. doi: 10.1146/annurev-chembioeng-061010-114116 contributor: fullname: Soloveichik – volume: 4 start-page: 3193 year: 2011 ident: c3cp51944a-(cit5)/*[position()=1] publication-title: Energy Environ. Sci. doi: 10.1039/c1ee01249e contributor: fullname: Armaroli – volume: 1 start-page: 394 year: 2011 ident: c3cp51944a-(cit14)/*[position()=1] publication-title: Adv. Energy Mater. doi: 10.1002/aenm.201100008 contributor: fullname: Li – volume: 204 start-page: 97 year: 1989 ident: c3cp51944a-(cit37)/*[position()=1] publication-title: J. Fluid Mech. doi: 10.1017/S0022112089001679 contributor: fullname: Frankel – volume: 109 start-page: 20310 year: 2005 ident: c3cp51944a-(cit27)/*[position()=1] publication-title: J. Phys. Chem. B doi: 10.1021/jp054092w contributor: fullname: Luo |
| SSID | ssj0001513 |
| Score | 2.3679829 |
| Snippet | This work is concerned with the determination of two critical constitutive properties for mass transport of ions through porous electrodes saturated with a... |
| SourceID | proquest crossref pubmed pascalfrancis rsc |
| SourceType | Aggregation Database Index Database Enrichment Source Publisher |
| StartPage | 1841 |
| SubjectTerms | Chemistry Coefficients Colloidal state and disperse state Current density Diffusivity Electrodes Electrolytes Exact sciences and technology General and physical chemistry Mathematical models Porous materials Transport Vanadium |
| Title | Determination of the mass-transport properties of vanadium ions through the porous electrodes of vanadium redox flow batteries |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/23698744 https://search.proquest.com/docview/1367506927 https://search.proquest.com/docview/1567134142 |
| Volume | 15 |
| hasFullText | 1 |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3Nb9MwFLdgO4CEEF-DDpiC4FYFGtux4-NUOg1UxpBSqeISxY4jDqytug4QB_523rPjJEUVGlyi9PU1Sf37xX623wchr6qRVpUqy1hLw2KuRRZrk6k4qU0iZZbaMsPY4Q9n4nTG38_T3ka7iy7Z6Nfm5864kv9BFWSAK0bJ_gOy7UVBAOeALxwBYTheC-O3wZclmH1oRV6AORxvQs5ydMBaoe-0Ty77zfl4XV0Mnf9bKNLjwqWWa_SGbcriVH-oY1rRH8P66_L7ULuMnMH3sLFrzwPcJhSQ82co8osnl27x4Xw8bgPK5leI76cePz9_Kd3Kbd4syDarEVgZQsY-CrTpQLlgMUy4m_TWfZkvBdf2ummPXbTfhyagmfQGZPyc7eztRwyTpRpmVmCHct4b08I-_tnH4mQ2nRb5ZJ7fJPtUqhRm6PvHk_zdtB2wwehhPgjNP3rIYsvUm-7aW3bLnVV5CQ1Y-9onuyYnYKqsQwkZZ6rk98jdZo4RHXvC3Cc37OIBuTUOyDwkv7aIEy3rCBgQbRMn6oiDCoEJERInaojjfuaJE3XE2VJ3xImQOFFLnEdkdjLJx6dxU4gjNlzwTZwybbB6oxAZ1ULRUipZpZxRI9RIY8rHSkktqooyaWsrqNKYptFSXZW1yDQ7IHuL5cI-IVEtLBUa-oES7FhruJLwQhsNktJSw-2AvAzNXKx8vpXC-UkwVXRgDMjRFgKtKpWYDzBLBuRFgKSAtsVNsHJhoTUKTFGYjuBPyL_opAJDrBNOB-Sxx7O7AxMKS0YMyAEA3Ir7z3a4-4tiVdWH17jnU3K7e7Oekb3N-so-B8t3o48a5v4GFMK2Cg |
| link.rule.ids | 315,786,790,27957,27958 |
| linkProvider | Royal Society of Chemistry |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Determination+of+the+mass-transport+properties+of+vanadium+ions+through+the+porous+electrodes+of+vanadium+redox+flow+batteries&rft.jtitle=Physical+chemistry+chemical+physics+%3A+PCCP&rft.au=Xu%2C+Qian&rft.au=Zhao%2C+T+S&rft.date=2013-07-14&rft.issn=1463-9076&rft.eissn=1463-9084&rft.volume=15&rft.issue=26&rft.spage=10841&rft.epage=10848&rft_id=info:doi/10.1039%2Fc3cp51944a&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1463-9076&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1463-9076&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1463-9076&client=summon |