Non-conventional oils for biodiesel production: a study of thermal and oxidative stability
Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of non-conventional oils such as andiroba, babassu, sesame, oiticica, jatropha,...
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Published in | Journal of thermal analysis and calorimetry Vol. 117; no. 2; pp. 845 - 849 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Springer Netherlands
01.08.2014
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Abstract | Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of non-conventional oils such as andiroba, babassu, sesame, oiticica, jatropha, and grape through accelerated oxidation techniques (pressurized differential scanning calorimetry, Rancimat and PetroOxy). It was verified that babassu and andiroba oil do not showed detectable induction period presenting high oxidative stability; moreover, it was observed that the enthalpic events occurred in 1.19, >10, 0.53, 0.49, 0.49, and 0.60 h for the andiroba oil, babassu oil, sesame seeds, jatropha, oiticica oils, and grapes, respectively, stimulating the conclusion of greater stability for the babassu oil. |
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AbstractList | Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of nonconventional oils such as andiroba, babassu, sesame, oiticica, jatropha, and grape through accelerated oxidation techniques (pressurized differential scanning calorimetry, Rancimat and PetroOxy). It was verified that babassu and andiroba oil do not showed detectable induction period presenting high oxidative stability; moreover, it was observed that the enthalpic events occurred in 1.19, >10, 0.53, 0.49, 0.49, and 0.60 h for the andiroba oil, babassu oil, sesame seeds, jatropha, oiticica oils, and grapes, respectively, stimulating the conclusion of greater stability for the babassu oil. Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of non-conventional oils such as andiroba, babassu, sesame, oiticica, jatropha, and grape through accelerated oxidation techniques (pressurized differential scanning calorimetry, Rancimat and PetroOxy). It was verified that babassu and andiroba oil do not showed detectable induction period presenting high oxidative stability; moreover, it was observed that the enthalpic events occurred in 1.19, >10, 0.53, 0.49, 0.49, and 0.60 h for the andiroba oil, babassu oil, sesame seeds, jatropha, oiticica oils, and grapes, respectively, stimulating the conclusion of greater stability for the babassu oil. Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of non-conventional oils such as andiroba, babassu, sesame, oiticica, jatropha, and grape through accelerated oxidation techniques (pressurized differential scanning calorimetry, Rancimat and PetroOxy). It was verified that babassu and andiroba oil do not showed detectable induction period presenting high oxidative stability; moreover, it was observed that the enthalpic events occurred in 1.19, >10, 0.53, 0.49, 0.49, and 0.60 h for the andiroba oil, babassu oil, sesame seeds, jatropha, oiticica oils, and grapes, respectively, stimulating the conclusion of greater stability for the babassu oil. Vegetable oils with variable proportions of oleic, linoleic, and linolenic acids are more susceptible to oxidative processes. In this subject, this study evaluates the physical chemical properties and oxidative stability of nonconventional oils such as andiroba, babassu, sesame, oiticica, jatropha, and grape through accelerated oxidation techniques (pressurized differential scanning calorimetry, Rancimat and PetroOxy). It was verified that babassu and andiroba oil do not showed detectable induction period presenting high oxidative stability; moreover, it was observed that the enthalpic events occurred in 1.19, >10, 0.53, 0.49, 0.49, and 0.60 h for the andiroba oil, babassu oil, sesame seeds, jatropha, oiticica oils, and grapes, respectively, stimulating the conclusion of greater stability for the babassu oil. Keywords PDSC * Rancimat * PetroOxy |
Audience | Academic |
Author | de Melo, Marco Aurélio Rodrigues Calixto, Clediana Dantas Pontes, Andrea Suame Gouvea Costa Farias, Ana Flávia Félix Dantas, Manoel Barbosa Melo, Maria Andrea Mendes Formiga de Carvalho Filho, José Rodrigues de Souza, Antonio Gouveia |
Author_xml | – sequence: 1 givenname: Maria Andrea Mendes Formiga surname: Melo fullname: Melo, Maria Andrea Mendes Formiga email: andrea_formigamelo@ig.com.br organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 2 givenname: Marco Aurélio Rodrigues surname: de Melo fullname: de Melo, Marco Aurélio Rodrigues organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 3 givenname: Andrea Suame Gouvea Costa surname: Pontes fullname: Pontes, Andrea Suame Gouvea Costa organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 4 givenname: Ana Flávia Félix surname: Farias fullname: Farias, Ana Flávia Félix organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 5 givenname: Manoel Barbosa surname: Dantas fullname: Dantas, Manoel Barbosa organization: Unidade Acadêmica de Química, Instituto Federal de Educação Ciência e Tecnologia da Paraíba – sequence: 6 givenname: Clediana Dantas surname: Calixto fullname: Calixto, Clediana Dantas organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 7 givenname: Antonio Gouveia surname: de Souza fullname: de Souza, Antonio Gouveia organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba – sequence: 8 givenname: José Rodrigues surname: de Carvalho Filho fullname: de Carvalho Filho, José Rodrigues organization: LACOM, CCEN, Departamento de Química, Universidade Federal da Paraíba |
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Cites_doi | 10.1007/s10973-006-7786-9 10.1016/j.fuproc.2007.01.005 10.1007/s10973-011-1545-2 10.1007/s10973-008-9600-3 10.1201/9781439822357 10.1007/s10973-009-0362-3 10.1590/S0100-40422005000100004 10.1590/S0103-90162005000300014 10.1590/S0100-40422009000600044 |
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References | Melo, Santos, Rosenhaim, Souza, Athayde Filho (CR10) 2011 Silva, Silva, Santos, Conceicão, Souza, Santos (CR1) 2011 Ferrari, Oliveira, Scabio (CR6) 2005; 62 Lôbo, Ferreira, Cruz (CR9) 2009; 32 Zenebon, Pascuet, Tiglea (CR13) 2008 Freedman, Bagby (CR8) 1989; 66 Knothe, Krahl, Van Gerpen (CR2) 2005 Nascimento, Couri, Antoniassi, Freitas (CR14) 2008 Bailey (CR7) 1996 Conceicão, Dantas, Rosenhaim, Fernandes, Santos, Souza (CR11) 2000; 97 Knothe (CR15) 2007; 88 Hui (CR17) 2006 Dantas, Almeida, Conceição, Fernades, Santos, Silva, Soledade, Souza (CR5) 2007; 87 (CR12) 1999 Ferrari, Oliveira, Scabio (CR4) 2005; 28 Rodrigues, Souza, Santos, Bicudo, Silva, Sinfrônio, Vasconselos (CR3) 2009; 97 Ramalho, Albuquerque, Souza, Barro, Maia, Santos, Souza (CR16) 2011; 106 G Knothe (3825_CR2) 2005 YH Hui (3825_CR17) 2006 AE Bailey (3825_CR7) 1996 RA Ferrari (3825_CR4) 2005; 28 MB Dantas (3825_CR5) 2007; 87 RJS Nascimento (3825_CR14) 2008 BE Freedman (3825_CR8) 1989; 66 MCD Silva (3825_CR1) 2011 G Knothe (3825_CR15) 2007; 88 EFSM Ramalho (3825_CR16) 2011; 106 RA Ferrari (3825_CR6) 2005; 62 IP Lôbo (3825_CR9) 2009; 32 MLS Melo (3825_CR10) 2011 AOCS—American Oil Chemists Society (3825_CR12) 1999 MM Conceicão (3825_CR11) 2000; 97 O Zenebon (3825_CR13) 2008 FMG Rodrigues (3825_CR3) 2009; 97 |
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SubjectTerms | Analytical Chemistry Babassu oil Biodiesel Biodiesel fuels Calorimetry Chemical properties Chemistry Chemistry and Materials Science Differential scanning calorimetry Grapes Inorganic Chemistry Measurement Science and Instrumentation Physical Chemistry Polymer Sciences Seeds Stability Vegetable oils |
Title | Non-conventional oils for biodiesel production: a study of thermal and oxidative stability |
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