Solution processable titanium dioxide precursor and nanoparticulated ink: Application in Dye Sensitized Solar Cells

• Published in: Journal of colloid and interface science Vol. 416; no. 416; pp. 112 - 118
• Main Authors: Bosch-Jimenez, Pau, Yu, Youhai, Lira-Cantu, Mónica, Domingo, Concepción, Ayllón, José A.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 15.02.2014; Elsevier
• Subjects: Applied sciences; Capping; Chemistry; Colloidal state and disperse state; Colloids; Decanoic Acids - chemistry; Dye Sensitized Solar Cells (DSSCs); Electric Power Supplies; Electrodes; Energy; Equipment Design; Ethanol; Ethyl alcohol; Exact sciences and technology; General and physical chemistry; Hydrogen Bonding; Ink; Low-temperature; Nanoparticles; Nanoparticles - chemistry; Natural energy; Photovoltaic cells; Photovoltaic conversion; Physical and chemical studies. Granulometry. Electrokinetic phenomena; Porosity; Proton Nuclear Magnetic Resonance (1H NMR); Solar cells; Solar cells. Photoelectrochemical cells; Solar energy; Solar Energy - utilization; Solutions; Solvents; Temperature; Titanium - chemistry; Titanium dioxide; Water; Nanoparticles; Proton Nuclear Magnetic Resonance (1H NMR); Dye Sensitized Solar Cells (DSSCs); Titanium dioxide; Ink; Low-temperature; Dye-sensitized solar cell; Nanoparticle; Transition element compounds; (; Precursor; Proton; Nuclear magnetic resonance; Titanium oxide; H NMR; Proton Nuclear Magnetic Resonance; Low temperature; Proton Nuclear Magnetic Resonance (H NMR)
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2013.11.013

[Display omitted] •A colloidal TiO2 ink assists the low temperature manufacturing of photoanodes.•The ink key component is a TiO2 colloid stabilized with 3,6,9-trioxadecanoic acid.•3,6,9-Trioxadecanoic acid was linked to titania colloid through labile hydrogen bonds.•The optimized ink has a simple composition, high stability and homogeneity.•DSSCs had a 5.6% efficiency after a soft thermal treatment (140°C). Colloidal TiO2 anatase nanoparticles of 4–8nm diameter capped with 3,6,9-trioxadecanoic acid (TODA) were synthesized at low temperature using water and ethanol as the solvents. ATR-FTIR and 1H NMR characterization showed the capping acid capability of stabilizing the TiO2 nanoparticles through labile hydrogen bonds. The presence of the capping ligand permitted the further preparation of homogeneous and stable colloidal dispersions of the TiO2 powder in aqueous media. Moreover, after solvent evaporation, the ligand could be easily eliminated by soft treatments, such as UV irradiation or low-temperature thermal annealing. These properties have been used in this work to fabricate mesoporous TiO2 electrodes, which can be applied as photoanodes in Dye Sensitized Solar Cells (DSSCs). For the preparation of the electrodes, the as-synthesized mesoporous TiO2 nanoparticles were mixed with commercial TiO2 (Degussa P25) and deposited on FTO substrates by using the doctor blade technique. A mixture of water and ethanol was used as the solvent. A soft thermal treatment at 140°C for 2h eliminated the organic compound and produced a sintered mesoporous layer of 6μm thickness. The photovoltaic performance of the DSSCs applying these electrodes sensitized with the N3 dye resulted in 5.6% power conversion efficiency.