Experimental investigation on the properties and microstructure of magnesium oxychloride cement prepared with caustic magnesite and dolomite
[Display omitted] •We made magnesium oxychloride cements with caustic magnesite and dolomite.•The minimum of active MgO in magnesium oxychloride is suggested by 33.4wt.%.•We defined two very important parameters in MgO–MgCl2–H2O system, K1 and K2.•The water resistance coefficient of magnesium oxychl...
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| Published in | Construction & building materials Vol. 85; pp. 247 - 255 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Elsevier Ltd
15.06.2015
Elsevier B.V |
| Subjects | |
| Online Access | Get full text |
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| Abstract | [Display omitted]
•We made magnesium oxychloride cements with caustic magnesite and dolomite.•The minimum of active MgO in magnesium oxychloride is suggested by 33.4wt.%.•We defined two very important parameters in MgO–MgCl2–H2O system, K1 and K2.•The water resistance coefficient of magnesium oxychloride is not related with the compressive strength.
Magnesium oxychloride cements (MOCs) with different amount of active magnesium oxide were prepared with caustic magnesite and dolomite. The fluidity, compressive and flexural strength were measured. After that, the MOCs were analyzed by XRD and SEM. The results indicated that MOCs prepared with caustic magnesite and dolomite obtained a good engineering performance. The result suggested that the minimum active MgO content used in MOCs should be 33.4wt.%. At the same time, this study shows that the water resistance coefficient of MOC is concerned with the balance of hydration and hydrolysis reactions which provides two main modification approaches, improving the hydration rate or preventing the reverse reaction. Meanwhile, it is shown in the experiment that there is no significant relationship between the water resistance coefficient and the compressive strength of MOCs. |
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| AbstractList | [Display omitted]
•We made magnesium oxychloride cements with caustic magnesite and dolomite.•The minimum of active MgO in magnesium oxychloride is suggested by 33.4wt.%.•We defined two very important parameters in MgO–MgCl2–H2O system, K1 and K2.•The water resistance coefficient of magnesium oxychloride is not related with the compressive strength.
Magnesium oxychloride cements (MOCs) with different amount of active magnesium oxide were prepared with caustic magnesite and dolomite. The fluidity, compressive and flexural strength were measured. After that, the MOCs were analyzed by XRD and SEM. The results indicated that MOCs prepared with caustic magnesite and dolomite obtained a good engineering performance. The result suggested that the minimum active MgO content used in MOCs should be 33.4wt.%. At the same time, this study shows that the water resistance coefficient of MOC is concerned with the balance of hydration and hydrolysis reactions which provides two main modification approaches, improving the hydration rate or preventing the reverse reaction. Meanwhile, it is shown in the experiment that there is no significant relationship between the water resistance coefficient and the compressive strength of MOCs. |
| Audience | Trade |
| Author | Huang, Jian Wei, Zhenhua Wang, Shuai Liu, Zhuangzhuang Guan, Bowen Fang, Jianhong |
| Author_xml | – sequence: 1 givenname: Zhuangzhuang surname: Liu fullname: Liu, Zhuangzhuang email: liuzhuangzhuang1986@gmail.com organization: School of Highway, Chang’an University, Xi’an 710064, China – sequence: 2 givenname: Shuai surname: Wang fullname: Wang, Shuai organization: Engineering Research Center of Transportation Materials, Ministry of Education, Xi’an 710062, China – sequence: 3 givenname: Jian surname: Huang fullname: Huang, Jian organization: Department of Civil and Environmental Engineering, University of California, Los Angeles, CA 90095, USA – sequence: 4 givenname: Zhenhua surname: Wei fullname: Wei, Zhenhua organization: Department of Civil and Environmental Engineering, University of California, Los Angeles, CA 90095, USA – sequence: 5 givenname: Bowen surname: Guan fullname: Guan, Bowen email: guanbowen2001@163.com organization: Engineering Research Center of Transportation Materials, Ministry of Education, Xi’an 710062, China – sequence: 6 givenname: Jianhong surname: Fang fullname: Fang, Jianhong organization: Qinghai Research Institute of Transportation, Xining 810008, China |
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year: 2011 ident: 10.1016/j.conbuildmat.2015.01.056_b0070 article-title: Effect of activated magnesia and molar ratio on deformability of magnesium oxychloride cement publication-title: Bull Chin Ceram Soc – volume: 26 start-page: 526 issue: 4 year: 1998 ident: 10.1016/j.conbuildmat.2015.01.056_b0090 article-title: Study on hydration mechanism of magnesium oxychloride cement prepared by caustic dolomite publication-title: J Chin Ceram Soc |
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| Title | Experimental investigation on the properties and microstructure of magnesium oxychloride cement prepared with caustic magnesite and dolomite |
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