Influence of polymer modification on asphalt binder dynamic and steady flow viscosities

• Published in: Construction & building materials Vol. 71; pp. 435 - 443
• Main Authors: Cardone, F., Ferrotti, G., Frigio, F., Canestrari, F.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 30.11.2014; Elsevier B.V
• Subjects: Analysis; Bituminous materials; Cox–Merz relationship; Polymer modified bitumen; Polymers; Properties; Rheological properties; Testing; Viscosity; Italy; Viscosity; Cox–Merz relationship; Polymer modified bitumen; Rheological properties
• ISSN: 0950-0618; 1879-0526
• DOI: 10.1016/j.conbuildmat.2014.08.043

•Oscillatory analysis and steady state viscosity measurements were performed on PMBs.•Polymer nature and content strongly influence PMBs rheological properties.•The applicability of the Cox–Merz rule for modified bitumens was evaluated.•Cross and Carreau models were suitable for low polymer modified bitumen. Asphalt pavement performance such as rutting, crack initiation and propagation as well as fatigue behaviour are substantially affected by the rheological properties of the bitumen. In this sense, the use of polymer modification in road paving applications has been growing rapidly over the last decade as it allows significant enhancements in bitumen properties with consequent improvement in road service life. In fact, the use of polymer modified bitumens (PMBs) leads to pavements characterized by higher resistance to rutting and thermal cracking and lower fatigue damage, stripping and thermal susceptibility. This paper presents a laboratory investigation concerning the effect of polymer modification on the flow behaviour of bitumens. Two different polymers, an elastomer and a plastomer, were used as bitumen modifying agents at three different percentages (2%, 4% and 6% by bitumen weight). Oscillatory mechanical analysis as well as viscosity measurements under steady state conditions were performed taking into account different testing parameters such as temperature, loading frequency and shear rate. The results confirm that the rheological properties of PMBs are strongly influenced by polymer nature and polymer content. The bitumen viscosity on the dynamic domain was combined with that in the steady-state domain, confirming the applicability of the Cox–Merz relationship for the plain bitumen and the PMBs with low polymer content. Finally, the Cross and the Carreau models were found to be suitable to fit the steady state and the dynamic results in order to determine the viscosity function of the investigated bitumens.