The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor-acceptor charge-transfer molecules

A series of phenothiazine-dibenzothiophene-S, S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor-acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine...

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Published inChemical communications (Cambridge, England) Vol. 52; no. 12; pp. 2612 - 2615
Main Authors Ward, Jonathan S., Nobuyasu, Roberto S., Batsanov, Andrei S., Data, Przemyslaw, Monkman, Andrew P., Dias, Fernando B., Bryce, Martin R.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 11.02.2016
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Abstract A series of phenothiazine-dibenzothiophene-S, S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor-acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.
AbstractList A series of phenothiazine-dibenzothiophene-S,S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor-acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.
A series of phenothiazine–dibenzothiophene- S , S -dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor–acceptor bond significantly alters contributions from TADF and phosphorescence. Bulky substituents on the 1-(and 9) position(s) of the phenothiazine result in no TADF in the solid state; instead strong phosphorescence is observed at ambient temperature.
Author Data, Przemyslaw
Ward, Jonathan S.
Monkman, Andrew P.
Dias, Fernando B.
Nobuyasu, Roberto S.
Batsanov, Andrei S.
Bryce, Martin R.
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  orcidid: 0000-0002-4985-8572
  surname: Ward
  fullname: Ward, Jonathan S.
  organization: Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
– sequence: 2
  givenname: Roberto S.
  surname: Nobuyasu
  fullname: Nobuyasu, Roberto S.
  organization: Univ Durham, Dept Phys, Durham DH1 3LE, England
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  givenname: Andrei S.
  surname: Batsanov
  fullname: Batsanov, Andrei S.
  organization: Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
– sequence: 4
  givenname: Przemyslaw
  orcidid: 0000-0002-1831-971X
  surname: Data
  fullname: Data, Przemyslaw
  organization: Univ Durham, Dept Phys, Durham DH1 3LE, England
– sequence: 5
  givenname: Andrew P.
  orcidid: 0000-0002-0784-8640
  surname: Monkman
  fullname: Monkman, Andrew P.
  organization: Univ Durham, Dept Phys, Durham DH1 3LE, England
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  givenname: Fernando B.
  orcidid: 0000-0001-9841-863X
  surname: Dias
  fullname: Dias, Fernando B.
  organization: Univ Durham, Dept Phys, Durham DH1 3LE, England
– sequence: 7
  givenname: Martin R.
  orcidid: 0000-0003-2097-7823
  surname: Bryce
  fullname: Bryce, Martin R.
  email: m.r.bryce@durham.ac.uk
  organization: Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England
BackLink https://www.ncbi.nlm.nih.gov/pubmed/26750426$$D View this record in MEDLINE/PubMed
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SSID ssj0000158
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Snippet A series of phenothiazine-dibenzothiophene-S, S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the...
A series of phenothiazine-dibenzothiophene-S,S-dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the donor-acceptor...
A series of phenothiazine–dibenzothiophene- S , S -dioxide charge-transfer molecules have been synthesized. Increasing steric restriction around the...
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SubjectTerms Activated
Ambient temperature
Bonding
Chemistry
Chemistry, Multidisciplinary
Constrictions
Fluorescence
Phenothiazines
Phosphorescence
Physical Sciences
Science & Technology
Solid state
Title The interplay of thermally activated delayed fluorescence (TADF) and room temperature organic phosphorescence in sterically-constrained donor-acceptor charge-transfer molecules
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https://www.ncbi.nlm.nih.gov/pubmed/26750426
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https://search.proquest.com/docview/1800462146
Volume 52
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