Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations

1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad...

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Published in	Chemical communications (Cambridge, England) Vol. 55; no. 38; pp. 548 - 5419
Main Authors	Shang, Tian-Yi, Lu, Ling-Hui, Cao, Zhong, Liu, Yan, He, Wei-Min, Yu, Bing
Format	Journal Article
Language	English
Published	England Royal Society of Chemistry 07.05.2019
Subjects	chemical compounds Chemical reactions Electrons fluorescent dyes Organic chemistry Photocatalysis photocatalysts redox reactions
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Abstract	1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized. In this review, the recent advances of the application of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized.
AbstractList	1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized. 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized.1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized. 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron acceptor. It has emerged as a powerful organophotocatalyst since 2016. Excellent redox window, good chemical stability and broad applicability make 4CzIPN an attractive metal-free photocatalyst. In this review, the recent advances of the application of 4CzIPN as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized. In this review, the recent advances of the application of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as a photoredox catalyst in the past three years (2016-2018) for various organic reactions are summarized.
Author	Liu, Yan Yu, Bing Shang, Tian-Yi He, Wei-Min Cao, Zhong Lu, Ling-Hui
AuthorAffiliation	Department of Chemistry Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation Xinyang Agriculture & Forestry University Hunan University of Science and Engineering College of Chemistry and Molecular Engineering Changsha University of Science and Technology Hunan University of Science and Technology College of Biological and Pharmaceutical Engineering School of Chemistry and Chemical Engineering Zhengzhou University
AuthorAffiliation_xml	– name: Xinyang Agriculture & Forestry University – name: Changsha University of Science and Technology – name: Zhengzhou University – name: Department of Chemistry – name: School of Chemistry and Chemical Engineering – name: College of Biological and Pharmaceutical Engineering – name: Hunan University of Science and Engineering – name: Hunan University of Science and Technology – name: Hunan Provincial Key Laboratory of Materials Protection for Electric Power and Transportation – name: College of Chemistry and Molecular Engineering
Author_xml	– sequence: 1 givenname: Tian-Yi surname: Shang fullname: Shang, Tian-Yi – sequence: 2 givenname: Ling-Hui surname: Lu fullname: Lu, Ling-Hui – sequence: 3 givenname: Zhong surname: Cao fullname: Cao, Zhong – sequence: 4 givenname: Yan surname: Liu fullname: Liu, Yan – sequence: 5 givenname: Wei-Min surname: He fullname: He, Wei-Min – sequence: 6 givenname: Bing surname: Yu fullname: Yu, Bing
BackLink	https://www.ncbi.nlm.nih.gov/pubmed/31020957$$D View this record in MEDLINE/PubMed
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Notes	Wei-Min He was born in Anqing, China, on November 22, 1982, and received his PhD degree from the Hunan University in 2012. He was a research scholar at the University of California, Santa Barbara before joining the Hunan University, as an assistant professor in 2013. He moved to Hunan University of Science and Engineering in 2016 and is currently an associate professor. His research focuses on green organic synthesis. Bing Yu obtained his PhD degree from the Nankai University in 2014. He then moved to the Beijing Institute of Technology (2014-2015), the Seoul National University (2015-2016) and the Tokyo Institute of Technology (2016-2017) as a postdoctoral researcher. He joined Zhengzhou University in 2017. His research interest is developing novel approaches for green and efficient organic synthesis. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
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Snippet	1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor-acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as... 1,2,3,5-Tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) is a typical donor–acceptor fluorophore, with carbazolyl as an electron donor and dicyanobenzene as...
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SubjectTerms	chemical compounds Chemical reactions Electrons fluorescent dyes Organic chemistry Photocatalysis photocatalysts redox reactions
Title	Recent advances of 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) in photocatalytic transformations
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