On single bubble mass transfer in a volatile liquid
•Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is charac...
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Published in | International journal of heat and mass transfer Vol. 125; pp. 1144 - 1155 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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Oxford
Elsevier Ltd
01.10.2018
Elsevier BV Elsevier |
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Abstract | •Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is characterized.
We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number. |
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AbstractList | We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in indus- trial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P = 20 bar, 30° ≤ T ≤ 150°C and bubble Reynolds number Re = O(10—100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number. We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number. •Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is characterized. We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number. |
Author | Tuttlies, U. Daniel, C. Colombet, D. Guiraud, P. Nieken, U. Legendre, D. Cockx, A. Galinat, S. |
Author_xml | – sequence: 1 givenname: D. surname: Colombet fullname: Colombet, D. email: damien.colombet@legi.inp-grenoble.fr organization: Institut de Mécanique des Fluides de Toulouse, IMFT, Université de Toulouse, CNRS, Toulouse, France – sequence: 2 givenname: D. surname: Legendre fullname: Legendre, D. email: legendre@imft.fr organization: Institut de Mécanique des Fluides de Toulouse, IMFT, Université de Toulouse, CNRS, Toulouse, France – sequence: 3 givenname: U. surname: Tuttlies fullname: Tuttlies, U. organization: Institut für Chemische Verfahrenstechnik Universität Stuttgart, Böblinger Str. 78, 70199 Stuttgart, Germany – sequence: 4 givenname: A. surname: Cockx fullname: Cockx, A. organization: LISBP, Université de Toulouse, INSA, INRA, CNRS, Toulouse, France – sequence: 5 givenname: P. surname: Guiraud fullname: Guiraud, P. organization: LISBP, Université de Toulouse, INSA, INRA, CNRS, Toulouse, France – sequence: 6 givenname: U. surname: Nieken fullname: Nieken, U. organization: Institut für Chemische Verfahrenstechnik Universität Stuttgart, Böblinger Str. 78, 70199 Stuttgart, Germany – sequence: 7 givenname: S. surname: Galinat fullname: Galinat, S. organization: Solvay R&I, 85, Avenue des Frères Perret, BP 62, 69192 Saint Fons, France – sequence: 8 givenname: C. surname: Daniel fullname: Daniel, C. organization: Solvay R&I, 85, Avenue des Frères Perret, BP 62, 69192 Saint Fons, France |
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Keywords | Fluid mechanics Bubble Mass transfer phase liquide thermodynamique méthode de suivi liquid phase réacteur reactor thermodynamics particule - surface interactions transfert de masse interaction particule surface cyclohexane |
Language | English |
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Snippet | •Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass... We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in... We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in indus- trial conditions, as observed for example in... |
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SubjectTerms | Ambient temperature Bubble Bubbles Cyclohexane Evaporation Fluid flow Fluid mechanics Gas-liquid systems Hydrocarbons Image processing Liquid phase oxidation Mass transfer Mechanics Oxidation Particle tracking Physics Reynolds number |
Title | On single bubble mass transfer in a volatile liquid |
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