On single bubble mass transfer in a volatile liquid

•Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is charac...

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Published inInternational journal of heat and mass transfer Vol. 125; pp. 1144 - 1155
Main Authors Colombet, D., Legendre, D., Tuttlies, U., Cockx, A., Guiraud, P., Nieken, U., Galinat, S., Daniel, C.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 01.10.2018
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Abstract •Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is characterized. We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number.
AbstractList We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in indus- trial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P = 20 bar, 30° ≤ T ≤ 150°C and bubble Reynolds number Re = O(10—100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number.
We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number.
•Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass transfer and the liquid evaporation is put in evidence.•Bubble diameter variation due to both mass transfer and liquid evaporation is characterized. We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in hydrocarbons liquid phase oxidation processes. Instantaneous bubble size, shape and velocity are measured using image processing with a particle tracking method. The mass transfer rate nitrogen into hot and pressurized liquid cyclohexane is deduced from the bubble volume decrease rate and is compared to literature correlations valid under isothermal conditions. Experiments are performed in a pressurized reactor for P=20bar, 30°⩽T⩽150°C and bubble Reynolds number Re=O(10–100). The analysis of bubble rise dynamics shows that the gas-liquid system studied can be considered as a clean system. The mass transfer results are found to follow isothermal correlations predictions excepted for ambient temperature for which liquid evaporation in bubbles is shown to be coupled with mass transfer. This phenomena seems to be a consequence of having a high Lewis number.
Author Tuttlies, U.
Daniel, C.
Colombet, D.
Guiraud, P.
Nieken, U.
Legendre, D.
Cockx, A.
Galinat, S.
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Keywords Fluid mechanics
Bubble
Mass transfer
phase liquide
thermodynamique
méthode de suivi
liquid phase
réacteur
reactor
thermodynamics
particule - surface interactions
transfert de masse
interaction particule surface
cyclohexane
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Snippet •Bubble mass transfer into a volatile liquid phase under both high pressure and high temperature conditions is considered.•The coupling between the solute mass...
We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in industrial conditions, as observed for example in...
We consider single bubble mass transfer of an non-condensible gas into a volatile liquid phase in indus- trial conditions, as observed for example in...
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StartPage 1144
SubjectTerms Ambient temperature
Bubble
Bubbles
Cyclohexane
Evaporation
Fluid flow
Fluid mechanics
Gas-liquid systems
Hydrocarbons
Image processing
Liquid phase oxidation
Mass transfer
Mechanics
Oxidation
Particle tracking
Physics
Reynolds number
Title On single bubble mass transfer in a volatile liquid
URI https://dx.doi.org/10.1016/j.ijheatmasstransfer.2018.04.149
https://www.proquest.com/docview/2111751401
https://hal.science/hal-01886489
Volume 125
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