Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters

As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates...

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Published inChemical Society reviews Vol. 47; no. 2; pp. 44 - 421
Main Authors Fang, Wei-Hui, Zhang, Lei, Zhang, Jian
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 22.01.2018
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Abstract As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO 2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way. A review of polyoxo-titanium clusters (PTCs), with an emphasis on synthetic methodologies, diverse structures, tuneable optical properties and potential applications.
AbstractList As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO₂ materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO 2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way. A review of polyoxo-titanium clusters (PTCs), with an emphasis on synthetic methodologies, diverse structures, tuneable optical properties and potential applications.
As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many photo-activities that broadly impact not only chemical but also energy and environmental sciences. In contrast to the well-developed polyoxometalates like polyoxotungstates and polyoxomolybdates, there is still large room for the development of PTCs. The exploration of crystalline PTC materials originates from the molecular model of technically important TiO 2 materials but has been greatly hindered by their daunting and challenging synthesis. This review firstly summarizes the conventional and latest successful synthetic strategies applied to improve the poor degree of control of crystallization of PTCs. And attributed to the synthetic progress achieved in this area, there is a growing number of PTCs with diverse structures known to us, also enabling us to study their bandgap engineering and light absorption behaviours at the molecular level. In addition, exploitation of their applications in many fields is also under way.
Author Fang, Wei-Hui
Zhang, Jian
Zhang, Lei
AuthorAffiliation State Key Laboratory of Structural Chemistry
Chinese Academy of Sciences
Fujian Institute of Research on the Structure of Matter
AuthorAffiliation_xml – name: State Key Laboratory of Structural Chemistry
– name: Chinese Academy of Sciences
– name: Fujian Institute of Research on the Structure of Matter
Author_xml – sequence: 1
  givenname: Wei-Hui
  surname: Fang
  fullname: Fang, Wei-Hui
– sequence: 2
  givenname: Lei
  surname: Zhang
  fullname: Zhang, Lei
– sequence: 3
  givenname: Jian
  surname: Zhang
  fullname: Zhang, Jian
BackLink https://www.ncbi.nlm.nih.gov/pubmed/29177361$$D View this record in MEDLINE/PubMed
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Notes Wei-Hui Fang received her PhD degree in chemistry in 2013 from the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (FJIRSM-CAS), under the supervision of Prof. Guo-Yu Yang. Now she is an Associate Research Professor in FJIRSM-CAS. Her current research interest is the synthesis and application of titanium-oxo clusters.
Jian Zhang graduated from Xiamen University in 2001 and obtained his PhD in 2006 from the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (FJIRSM-CAS). After three years of postdoctoral work with Prof. Xianhui Bu in California State University, Long Beach, he came back to FJIRSM-CAS and served as a Full Research Professor in September 2009. His current research interest is in the synthesis and application of metal-organic frameworks.
Lei Zhang obtained his bachelors degree from Nanjing University in 2004 and his PhD degree from the Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (FJIRSM-CAS) in 2009. He then worked as a Postdoctoral Researcher with Prof. Wolfgang Schmitt at Trinity College Dublin from November 2009 to December 2012, and as an Alexander von Humboldt Research Fellow with Prof. Thomas F. Fässler at Technische Universität München from January 2013 to August 2014. Since September 2014, he has been working as a Full Research Professor at FJIRSM-CAS. His research interest is mainly focused on metal-oxo clusters.
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Snippet As one of the most prosperous classes of cluster-based materials reported to date, polyoxo-titanium clusters (PTCs) have been closely related to many...
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SubjectTerms absorption
Clusters
Crystallization
Electromagnetic absorption
energy
engineering
environmental science
molecular models
Polyoxometallates
Titanium
titanium dioxide
Titanium oxides
Title Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters
URI https://www.ncbi.nlm.nih.gov/pubmed/29177361
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