Facile, surfactant-free synthesis of Pd nanoparticles for heterogeneous catalysts
A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC) 2 by methanol at room temperature, without the need for any capping agents. These catalysts do not require pretreatment and exhibit high selectivity for the hydrogenation of acetylene to ethylene. [Display o...
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Published in | Journal of catalysis Vol. 280; no. 2; pp. 145 - 149 |
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Main Authors | , , |
Format | Journal Article |
Language | English |
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Elsevier Inc
13.06.2011
Elsevier Elsevier BV |
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Abstract | A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC)
2 by methanol at room temperature, without the need for any capping agents. These catalysts do not require pretreatment and exhibit high selectivity for the hydrogenation of acetylene to ethylene.
[Display omitted]
► Synthesis of Pd nanoparticles without capping agents. ► Surfactant-free synthesis ensures that Pd is active as-prepared. ► Facile RT reduction by alcohols represents an advance in nanoparticle synthesis. ► Pd deposited on carbon shows high selectivity for acetylene hydrogenation.
A simple route to a highly active and selective Pd/C heterogeneous hydrogenation catalyst has been developed. The 1.5
nm Pd
0 nanoparticles (NPs) were synthesized at room temperature from the reduction of palladium acetate in methanol under anhydrous conditions. A powdered carbon support was added during the synthesis and dried to produce an active catalyst that did not require any additional treatment. This technique alleviates many of the difficulties reported in using colloidal NPs, such as residues left from the removal of capping agents or agglomeration during ligand removal. |
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AbstractList | A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC)
2 by methanol at room temperature, without the need for any capping agents. These catalysts do not require pretreatment and exhibit high selectivity for the hydrogenation of acetylene to ethylene.
[Display omitted]
► Synthesis of Pd nanoparticles without capping agents. ► Surfactant-free synthesis ensures that Pd is active as-prepared. ► Facile RT reduction by alcohols represents an advance in nanoparticle synthesis. ► Pd deposited on carbon shows high selectivity for acetylene hydrogenation.
A simple route to a highly active and selective Pd/C heterogeneous hydrogenation catalyst has been developed. The 1.5
nm Pd
0 nanoparticles (NPs) were synthesized at room temperature from the reduction of palladium acetate in methanol under anhydrous conditions. A powdered carbon support was added during the synthesis and dried to produce an active catalyst that did not require any additional treatment. This technique alleviates many of the difficulties reported in using colloidal NPs, such as residues left from the removal of capping agents or agglomeration during ligand removal. Graphical abstract A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC)2 by methanol at room temperature, without the need for any capping agents. These catalysts do not require pretreatment and exhibit high selectivity for the hydrogenation of acetylene to ethylene. Display Omitted Highlights Synthesis of Pd nanoparticles without capping agents. Surfactant-free synthesis ensures that Pd is active as-prepared. Facile RT reduction by alcohols represents an advance in nanoparticle synthesis. Pd deposited on carbon shows high selectivity for acetylene hydrogenation. A simple route to a highly active and selective Pd/C heterogeneous hydrogenation catalyst has been developed. The 1.5nm Pd0 nanoparticles (NPs) were synthesized at room temperature from the reduction of palladium acetate in methanol under anhydrous conditions. A powdered carbon support was added during the synthesis and dried to produce an active catalyst that did not require any additional treatment. This technique alleviates many of the difficulties reported in using colloidal NPs, such as residues left from the removal of capping agents or agglomeration during ligand removal. [PUBLICATION ABSTRACT] |
Author | Boyle, Timothy J. Burton, Patrick D. Datye, Abhaya K. |
Author_xml | – sequence: 1 givenname: Patrick D. surname: Burton fullname: Burton, Patrick D. organization: Department of Chemical and Nuclear Engineering and Center for Micro-Engineered Materials, University of New Mexico, Albuquerque, NM 87131, United States – sequence: 2 givenname: Timothy J. surname: Boyle fullname: Boyle, Timothy J. organization: Advanced Materials Laboratory, Sandia National Laboratories, Albuquerque, NM 87106, United States – sequence: 3 givenname: Abhaya K. surname: Datye fullname: Datye, Abhaya K. email: datye@unm.edu organization: Department of Chemical and Nuclear Engineering and Center for Micro-Engineered Materials, University of New Mexico, Albuquerque, NM 87131, United States |
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Keywords | Acetylene hydrogenation Catalyst pre-treatment Surfactant-free nanoparticles Palladium nanoparticles Capping Support Nanoparticle Alcohol Agglomeration Surfactant Hydrogenation Powder Acetylene Chemical reduction Synthesis Alkanol Platinoid Methanol Transition metal Palladium Acetate Carbon Heterogeneous catalysis Residue Catalyst Room temperature |
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Snippet | A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC)
2 by methanol at room temperature, without the need for any... Graphical abstract A simple route is described for the preparation of Pd nanoparticles via reduction of Pd(OAC)2 by methanol at room temperature, without the... |
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SubjectTerms | Acetylene hydrogenation Catalysis Catalyst pre-treatment Catalysts Chemical synthesis Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Methanol Nanoparticles Palladium nanoparticles Physical and chemical studies. Granulometry. Electrokinetic phenomena Surfactant-free nanoparticles Surfactants Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry |
Title | Facile, surfactant-free synthesis of Pd nanoparticles for heterogeneous catalysts |
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