Mechanistic basis of oxygen sensitivity in titanium
A systematic study of Ti-O alloys reveals the mechanism behind acute oxygen sensitivity in titanium. One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen al...
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| Published in | Science advances Vol. 6; no. 43 |
|---|---|
| Main Authors | , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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United States
AAAS
23.10.2020
American Association for the Advancement of Science |
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| Abstract | A systematic study of Ti-O alloys reveals the mechanism behind acute oxygen sensitivity in titanium.
One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen also lead to a markedly decreased ductility, which in turn drives the increased cost to purify titanium to avoid this oxygen poisoning effect. Here, we report a systematic study on the oxygen sensitivity of titanium that provides a clear mechanistic view of how oxygen impurities affect the mechanical properties of titanium. The increased slip planarity of Ti-O alloys is caused by an interstitial shuffling mechanism, which is sensitive to temperature, strain rate, and oxygen content and leads to the subsequent alteration of deformation twinning behavior. The insights from our experimental and computational work provide a rationale for the design of titanium alloys with increased tolerance to variations in interstitial content, with notable implications for more widespread use of titanium alloys. |
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| AbstractList | One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen also lead to a markedly decreased ductility, which in turn drives the increased cost to purify titanium to avoid this oxygen poisoning effect. Here, we report a systematic study on the oxygen sensitivity of titanium that provides a clear mechanistic view of how oxygen impurities affect the mechanical properties of titanium. The increased slip planarity of Ti-O alloys is caused by an interstitial shuffling mechanism, which is sensitive to temperature, strain rate, and oxygen content and leads to the subsequent alteration of deformation twinning behavior. The insights from our experimental and computational work provide a rationale for the design of titanium alloys with increased tolerance to variations in interstitial content, with notable implications for more widespread use of titanium alloys. A systematic study of Ti-O alloys reveals the mechanism behind acute oxygen sensitivity in titanium. One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen also lead to a markedly decreased ductility, which in turn drives the increased cost to purify titanium to avoid this oxygen poisoning effect. Here, we report a systematic study on the oxygen sensitivity of titanium that provides a clear mechanistic view of how oxygen impurities affect the mechanical properties of titanium. The increased slip planarity of Ti-O alloys is caused by an interstitial shuffling mechanism, which is sensitive to temperature, strain rate, and oxygen content and leads to the subsequent alteration of deformation twinning behavior. The insights from our experimental and computational work provide a rationale for the design of titanium alloys with increased tolerance to variations in interstitial content, with notable implications for more widespread use of titanium alloys. One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen also lead to a markedly decreased ductility, which in turn drives the increased cost to purify titanium to avoid this oxygen poisoning effect. Here, we report a systematic study on the oxygen sensitivity of titanium that provides a clear mechanistic view of how oxygen impurities affect the mechanical properties of titanium. The increased slip planarity of Ti-O alloys is caused by an interstitial shuffling mechanism, which is sensitive to temperature, strain rate, and oxygen content and leads to the subsequent alteration of deformation twinning behavior. The insights from our experimental and computational work provide a rationale for the design of titanium alloys with increased tolerance to variations in interstitial content, with notable implications for more widespread use of titanium alloys.One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen. Unfortunately, these small amounts of oxygen also lead to a markedly decreased ductility, which in turn drives the increased cost to purify titanium to avoid this oxygen poisoning effect. Here, we report a systematic study on the oxygen sensitivity of titanium that provides a clear mechanistic view of how oxygen impurities affect the mechanical properties of titanium. The increased slip planarity of Ti-O alloys is caused by an interstitial shuffling mechanism, which is sensitive to temperature, strain rate, and oxygen content and leads to the subsequent alteration of deformation twinning behavior. The insights from our experimental and computational work provide a rationale for the design of titanium alloys with increased tolerance to variations in interstitial content, with notable implications for more widespread use of titanium alloys. |
| Author | Hooshmand, Mohammad S. Zhao, Shiteng Poschmann, Max Asta, Mark Chrzan, Daryl C. Zhang, Ruopeng Minor, Andrew M. Rothchild, Eric Morris, J. W. Chong, Yan Olmsted, David L. |
| Author_xml | – sequence: 1 givenname: Yan orcidid: 0000-0003-2897-5099 surname: Chong fullname: Chong, Yan organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA – sequence: 2 givenname: Max orcidid: 0000-0002-4955-6259 surname: Poschmann fullname: Poschmann, Max organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA – sequence: 3 givenname: Ruopeng orcidid: 0000-0001-7677-4051 surname: Zhang fullname: Zhang, Ruopeng organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA – sequence: 4 givenname: Shiteng orcidid: 0000-0003-4828-9651 surname: Zhao fullname: Zhao, Shiteng organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA – sequence: 5 givenname: Mohammad S. surname: Hooshmand fullname: Hooshmand, Mohammad S. organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA – sequence: 6 givenname: Eric surname: Rothchild fullname: Rothchild, Eric organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA – sequence: 7 givenname: David L. orcidid: 0000-0002-5909-3761 surname: Olmsted fullname: Olmsted, David L. organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA – sequence: 8 givenname: J. W. surname: Morris fullname: Morris, J. W. organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA – sequence: 9 givenname: Daryl C. orcidid: 0000-0001-6957-2240 surname: Chrzan fullname: Chrzan, Daryl C. organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA – sequence: 10 givenname: Mark orcidid: 0000-0002-8968-321X surname: Asta fullname: Asta, Mark organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA – sequence: 11 givenname: Andrew M. orcidid: 0000-0003-3606-8309 surname: Minor fullname: Minor, Andrew M. organization: Department of Materials Science and Engineering, University of California, Berkeley, Berkeley, CA 94720, USA., National Center for Electron Microscopy, Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA., Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA |
| BackLink | https://www.osti.gov/servlets/purl/1765578$$D View this record in Osti.gov |
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| Copyright | Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). 2020 The Authors |
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| Snippet | A systematic study of Ti-O alloys reveals the mechanism behind acute oxygen sensitivity in titanium.
One of the most potent examples of interstitial solute... One of the most potent examples of interstitial solute strengthening in metal alloys is the extreme sensitivity of titanium to small amounts of oxygen.... |
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| Title | Mechanistic basis of oxygen sensitivity in titanium |
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