High‐Entropy Metal Sulfide Nanoparticles Promise High‐Performance Oxygen Evolution Reaction
Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements i...
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| Published in | Advanced energy materials Vol. 11; no. 3 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
01.01.2021
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| Subjects | |
| Online Access | Get full text |
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| Abstract | Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high‐entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)Sx) solid solution nanoparticles is reported. Computational and X‐ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)Sx exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)Sx nanoparticles show one of the best activities (low overpotential 295 mV at 100 mA cm−2 in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high‐entropy compound nanoparticles for highly efficient electrocatalysis applications.
High‐entropy metal sulfide (HEMS) nanoparticles are achieved through a pulse thermal decomposition method by overcoming the immiscibility of multiple metallic constituents. Benefiting from synergistic effects and high‐entropy stabilization, nanoscale HEMS greatly promotes oxygen evolution reaction performance. Thus, a new synthesis paradigm for high‐entropy nanomaterials is established for renewable energy conversion and storage applications. |
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| AbstractList | Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high‐entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)Sx) solid solution nanoparticles is reported. Computational and X‐ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)Sx exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)Sx nanoparticles show one of the best activities (low overpotential 295 mV at 100 mA cm−2 in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high‐entropy compound nanoparticles for highly efficient electrocatalysis applications.
High‐entropy metal sulfide (HEMS) nanoparticles are achieved through a pulse thermal decomposition method by overcoming the immiscibility of multiple metallic constituents. Benefiting from synergistic effects and high‐entropy stabilization, nanoscale HEMS greatly promotes oxygen evolution reaction performance. Thus, a new synthesis paradigm for high‐entropy nanomaterials is established for renewable energy conversion and storage applications. Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high‐entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)S x ) solid solution nanoparticles is reported. Computational and X‐ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)S x exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)S x nanoparticles show one of the best activities (low overpotential 295 mV at 100 mA cm −2 in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high‐entropy compound nanoparticles for highly efficient electrocatalysis applications. Transition metal sulfides with a multi‐elemental nature represent a class of promising catalysts for oxygen evolution reaction (OER) owing to their good catalytic activity. However, their synthesis remains a challenge due to the thermodynamic immiscibility of the constituent multimetallic elements in a sulfide structure. Herein, for the first time the synthesis of high‐entropy metal sulfide (HEMS, i.e., (CrMnFeCoNi)Sx) solid solution nanoparticles is reported. Computational and X‐ray photoelectron spectroscopy analysis suggest that the (CrMnFeCoNi)Sx exhibits a synergistic effect among metal atoms that leads to desired electronic states to enhance OER activity. The (CrMnFeCoNi)Sx nanoparticles show one of the best activities (low overpotential 295 mV at 100 mA cm−2 in 1 m KOH solution) and good durability (only slight polarization after 10 h by chronopotentiometry) compared with their unary, binary, ternary, and quaternary sulfide counterparts. This work opens up a new synthesis paradigm for high‐entropy compound nanoparticles for highly efficient electrocatalysis applications. |
| Author | Wu, Meiling Li, Boyang Wang, Xizheng Hu, Liangbing Yang, Chunpeng Xie, Hua Cui, Mingjin Dong, Qi Hwang, Sooyeon Wang, Guofeng |
| Author_xml | – sequence: 1 givenname: Mingjin surname: Cui fullname: Cui, Mingjin organization: University of Maryland – sequence: 2 givenname: Chunpeng surname: Yang fullname: Yang, Chunpeng organization: University of Maryland – sequence: 3 givenname: Boyang surname: Li fullname: Li, Boyang organization: University of Pittsburgh – sequence: 4 givenname: Qi surname: Dong fullname: Dong, Qi organization: University of Maryland – sequence: 5 givenname: Meiling surname: Wu fullname: Wu, Meiling organization: University of Maryland – sequence: 6 givenname: Sooyeon surname: Hwang fullname: Hwang, Sooyeon organization: Brookhaven National Laboratory – sequence: 7 givenname: Hua surname: Xie fullname: Xie, Hua organization: University of Maryland – sequence: 8 givenname: Xizheng surname: Wang fullname: Wang, Xizheng organization: University of Maryland – sequence: 9 givenname: Guofeng surname: Wang fullname: Wang, Guofeng email: guw8@pitt.edu organization: University of Pittsburgh – sequence: 10 givenname: Liangbing orcidid: 0000-0002-9456-9315 surname: Hu fullname: Hu, Liangbing email: binghu@umd.edu organization: University of Maryland |
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