Adsorption Studies of Heavy Metal Ions on Mesoporous Aluminosilicate, Novel Cation Exchanger

Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They have been characterized by XRD, nitrogen adsorption/desorption measurements, FT-IR and thermogravimetry. Adsorption behavior of heavy metal ions on this adsorbent have b...

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Published inJournal of hazardous materials Vol. 176; no. 1; pp. 252 - 256
Main Authors Sepehrian, H., Ahmadi, S.J., Waqif-Husain, S., Faghihian, H., Alighanbari, H.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier B.V 15.04.2010
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Abstract Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They have been characterized by XRD, nitrogen adsorption/desorption measurements, FT-IR and thermogravimetry. Adsorption behavior of heavy metal ions on this adsorbent have been studied and discussed. The results show that incorporation of aluminum ions in the framework of the mesoporous MCM-41 has transformed it into an effective cation exchanger. The K d values of several metal ions have been increased. Separation of Sr(II)–Ce(III), Sr(II)–U(VI) and Cd(II)–Ce(III) has been developed on columns of this novel mesoporous cation exchanger.
AbstractList Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They have been characterized by XRD, nitrogen adsorption/desorption measurements, FT-IR and thermogravimetry. Adsorption behavior of heavy metal ions on this adsorbent have been studied and discussed. The results show that incorporation of aluminum ions in the framework of the mesoporous MCM-41 has transformed it into an effective cation exchanger. The K d values of several metal ions have been increased. Separation of Sr(II)-Ce(III), Sr(II)-U(VI) and Cd(II)-Ce(III) has been developed on columns of this novel mesoporous cation exchanger.
Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They have been characterized by XRD, nitrogen adsorption/desorption measurements, FT-IR and thermogravimetry. Adsorption behavior of heavy metal ions on this adsorbent have been studied and discussed. The results show that incorporation of aluminum ions in the framework of the mesoporous MCM-41 has transformed it into an effective cation exchanger. The K d values of several metal ions have been increased. Separation of Sr(II)–Ce(III), Sr(II)–U(VI) and Cd(II)–Ce(III) has been developed on columns of this novel mesoporous cation exchanger.
Author Ahmadi, S.J.
Alighanbari, H.
Sepehrian, H.
Faghihian, H.
Waqif-Husain, S.
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  surname: Sepehrian
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  surname: Waqif-Husain
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  organization: Faculty of Nuclear Engineering, University of Shahid Beheshti, Tehran, Iran
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Issue 1
Keywords Heavy metal ions
Aluminosilicate
Radionuclides
Adsorption
Mesoporous
Radioactive pollution
Thermogravimetry
Metal ion
Desorption
Radioisotope
Nitrogen
Heavy metal
Cation exchanger
Language English
License CC BY 4.0
2009 Elsevier B.V. All rights reserved.
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Elsevier
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Snippet Mesoporous aluminosilicates, have been prepared with various mole ratios of Si/Al and Cethyltrimethylammonium bromide (CTAB). They have been characterized by...
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SubjectTerms Adsorbents
Adsorption
Aluminosilicate
Aluminosilicates
Aluminum
Aluminum silicates
Aluminum Silicates - chemistry
Applied sciences
Cadmium
Cation exchanging
Chemical engineering
Exact sciences and technology
Heavy metal ions
Heavy metals
Ion Exchange
Ion exchangers
Mesoporous
Metals, Heavy - isolation & purification
Pollution
Porosity
Radionuclides
Strontium
Uranium
Title Adsorption Studies of Heavy Metal Ions on Mesoporous Aluminosilicate, Novel Cation Exchanger
URI https://dx.doi.org/10.1016/j.jhazmat.2009.11.020
https://www.ncbi.nlm.nih.gov/pubmed/19954883
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Volume 176
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