Vanadium pentoxide nanochains for high-performance electrochemical supercapacitors
[Display omitted] •Synthesis of V2O5 nanochains for charge storage applications.•Hydrothermal medium with CTAB surfactant is crucial to obtain V2O5 nanochains.•Capacitance of bulk V2O5<agglomerated V2O5 particles<V2O5 nanochains. We have synthesized unique hierarchical one dimensional (1D) nan...
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| Published in | Journal of colloid and interface science Vol. 472; pp. 210 - 219 |
|---|---|
| Main Authors | , |
| Format | Journal Article |
| Language | English |
| Published |
United States
Elsevier Inc
15.06.2016
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| Subjects | |
| Online Access | Get full text |
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| Abstract | [Display omitted]
•Synthesis of V2O5 nanochains for charge storage applications.•Hydrothermal medium with CTAB surfactant is crucial to obtain V2O5 nanochains.•Capacitance of bulk V2O5<agglomerated V2O5 particles<V2O5 nanochains.
We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631Fg−1 at a current density of 0.5Ag−1 and retain 300Fg−1 even at high current density of 15Ag−1. In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160Fg−1)<agglomerated V2O5 particles (395Fg−1)<V2O5 nanochains (631Fg−1). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li+ ions during the charge-discharge processes. |
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| AbstractList | We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631Fg⁻¹ at a current density of 0.5Ag⁻¹ and retain 300Fg⁻¹ even at high current density of 15Ag⁻¹. In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160Fg⁻¹)<agglomerated V2O5 particles (395Fg⁻¹)<V2O5 nanochains (631Fg⁻¹). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li⁺ ions during the charge-discharge processes. We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631 F g(-1) at a current density of 0.5 A g(-1) and retain 300 F g(-1) even at high current density of 15 A g(-1). In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160 F g(-1))<agglomerated V2O5 particles (395 F g(-1))<V2O5 nanochains (631 F g(-1)). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li(+) ions during the charge-discharge processes. [Display omitted] •Synthesis of V2O5 nanochains for charge storage applications.•Hydrothermal medium with CTAB surfactant is crucial to obtain V2O5 nanochains.•Capacitance of bulk V2O5<agglomerated V2O5 particles<V2O5 nanochains. We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631Fg−1 at a current density of 0.5Ag−1 and retain 300Fg−1 even at high current density of 15Ag−1. In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160Fg−1)<agglomerated V2O5 particles (395Fg−1)<V2O5 nanochains (631Fg−1). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li+ ions during the charge-discharge processes. We have synthesized unique hierarchical one dimensional (1D) nanochains of V sub(2)O sub(5) by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V sub(2)O sub(5) electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V sub(2)O sub(5) nanochains (V sub(2)O sub(5)-ctab) show maximum specific capacitance of 631 F g super(-1) at a current density of 0.5 A g super(-1) and retain 300 F g super(-1) even at high current density of 15 A g super(-1). In addition the V sub(2)O sub(5) nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V sub(2)O sub(5) (160 F g super(-1)) < agglomerated V sub(2)O sub(5) particles (395 F g super(-1)) < V sub(2)O sub(5) nanochains (631 F g super(-1)). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V sub(2)O sub(5) nanochains and promote facile exchange of Li super(+) ions during the charge-discharge processes. We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631 F g(-1) at a current density of 0.5 A g(-1) and retain 300 F g(-1) even at high current density of 15 A g(-1). In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160 F g(-1))<agglomerated V2O5 particles (395 F g(-1))<V2O5 nanochains (631 F g(-1)). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li(+) ions during the charge-discharge processes.We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide (CTAB) as a soft template. The electrochemical performance of resulting V2O5 electrode materials was evaluated by cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy techniques. The V2O5 nanochains (V2O5-ctab) show maximum specific capacitance of 631 F g(-1) at a current density of 0.5 A g(-1) and retain 300 F g(-1) even at high current density of 15 A g(-1). In addition the V2O5 nanochains show good cyclic stability with 75% capacitance retention after 1200 charge-discharge cycles. The order of specific capacitance is commercial bulk-V2O5 (160 F g(-1))<agglomerated V2O5 particles (395 F g(-1))<V2O5 nanochains (631 F g(-1)). The interconnected nanochain-like morphology and high specific surface area are the main factors which contribute to higher electrochemical performance to V2O5 nanochains and promote facile exchange of Li(+) ions during the charge-discharge processes. |
| Author | Ranga Rao, G. Umeshbabu, Ediga |
| Author_xml | – sequence: 1 givenname: Ediga surname: Umeshbabu fullname: Umeshbabu, Ediga – sequence: 2 givenname: G. surname: Ranga Rao fullname: Ranga Rao, G. email: grrao@iitm.ac.in |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/27038783$$D View this record in MEDLINE/PubMed |
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| Keywords | Vanadium oxide Hydrothermal synthesis Nanochains morphology CTAB Pseudocapacitive behavior |
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•Synthesis of V2O5 nanochains for charge storage applications.•Hydrothermal medium with CTAB surfactant is crucial to obtain V2O5... We have synthesized unique hierarchical one dimensional (1D) nanochains of V2O5 by employing simple hydrothermal method using cetyltrimethylammonium bromide... We have synthesized unique hierarchical one dimensional (1D) nanochains of V sub(2)O sub(5) by employing simple hydrothermal method using... |
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| SubjectTerms | Capacitance cetyltrimethylammonium bromide CTAB Current density dielectric spectroscopy Electrochemical analysis Electrochemical impedance spectroscopy electrochemistry electrodes hot water treatment Hydrothermal synthesis Ion exchangers ions lithium Nanochains morphology Nanostructure Pseudocapacitive behavior Specific surface surface area vanadium Vanadium oxide Vanadium pentoxide |
| Title | Vanadium pentoxide nanochains for high-performance electrochemical supercapacitors |
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