Nickel cobaltite@nanocarbon hybrid materials as efficient cathode catalyst for oxygen reduction in microbial fuel cells
The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air–catho...
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Published in | Journal of materials science Vol. 52; no. 12; pp. 7539 - 7545 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
New York
Springer US
01.06.2017
Springer Springer Nature B.V |
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Abstract | The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air–cathode MFCs. Impressively, the achieved maximum power density of the MFCs equipped with NiCo
2
O
4
@MWCNTs cathode was about 356 mW m
−2
, which is significantly higher than that of the MFCs with other cathodic catalysts. This work may provide not only the fundamental studies on nanocarbon-supported mixed-valent transition-metal oxides but also a new kind of promising alternative electrode in the technology of power generation from MFCs. |
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AbstractList | The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air–cathode MFCs. Impressively, the achieved maximum power density of the MFCs equipped with NiCo₂O₄@MWCNTs cathode was about 356 mW m⁻², which is significantly higher than that of the MFCs with other cathodic catalysts. This work may provide not only the fundamental studies on nanocarbon-supported mixed-valent transition-metal oxides but also a new kind of promising alternative electrode in the technology of power generation from MFCs. The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air–cathode MFCs. Impressively, the achieved maximum power density of the MFCs equipped with NiCo2O4@MWCNTs cathode was about 356 mW m−2, which is significantly higher than that of the MFCs with other cathodic catalysts. This work may provide not only the fundamental studies on nanocarbon-supported mixed-valent transition-metal oxides but also a new kind of promising alternative electrode in the technology of power generation from MFCs. The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air–cathode MFCs. Impressively, the achieved maximum power density of the MFCs equipped with NiCo 2 O 4 @MWCNTs cathode was about 356 mW m −2 , which is significantly higher than that of the MFCs with other cathodic catalysts. This work may provide not only the fundamental studies on nanocarbon-supported mixed-valent transition-metal oxides but also a new kind of promising alternative electrode in the technology of power generation from MFCs. The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work, two novel nickel cobaltite@nanocarbon hybrids were rationally designed and successfully prepared as efficient cathode catalysts in air-cathode MFCs. Impressively, the achieved maximum power density of the MFCs equipped with NiCo.sub.2O.sub.4@MWCNTs cathode was about 356 mW m.sup.-2, which is significantly higher than that of the MFCs with other cathodic catalysts. This work may provide not only the fundamental studies on nanocarbon-supported mixed-valent transition-metal oxides but also a new kind of promising alternative electrode in the technology of power generation from MFCs. |
Audience | Academic |
Author | Li, Nan Li, Jie-Cheng Lai, Shao-Hao Tan, Liang Xia, Wei-Yan |
Author_xml | – sequence: 1 givenname: Wei-Yan surname: Xia fullname: Xia, Wei-Yan organization: School of Chemistry and Chemical Engineering, Guangzhou University, The Experimental School Affiliated to Guangzhou College – sequence: 2 givenname: Liang surname: Tan fullname: Tan, Liang organization: School of Chemistry and Chemical Engineering, Guangzhou University – sequence: 3 givenname: Nan orcidid: 0000-0002-8148-1891 surname: Li fullname: Li, Nan email: nanli@gzhu.edu.cn organization: School of Chemistry and Chemical Engineering, Guangzhou University – sequence: 4 givenname: Jie-Cheng surname: Li fullname: Li, Jie-Cheng organization: School of Chemistry and Chemical Engineering, Guangzhou University – sequence: 5 givenname: Shao-Hao surname: Lai fullname: Lai, Shao-Hao organization: School of Chemistry and Chemical Engineering, Guangzhou University |
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Cites_doi | 10.1016/j.nantod.2014.05.003 10.1016/j.jpowsour.2012.08.034 10.1016/j.bios.2013.11.044 10.1016/j.bios.2013.12.015 10.1039/b806498a 10.1021/ez4000324 10.1039/C3EE43106A 10.1016/j.electacta.2014.02.111 10.1002/anie.201504830 10.1039/C5TA03985A 10.1039/C6MH00093B 10.1016/j.ijhydene.2015.01.119 10.1016/j.ijhydene.2015.04.030 10.1016/j.biortech.2015.03.131 10.1021/acsami.5b05273 10.1016/j.bios.2015.05.035 10.1039/C5CS00414D 10.1039/C4CS00484A 10.1039/C3TA14043A 10.1021/es5047765 10.1016/j.electacta.2016.07.099 10.1039/C4TA01672F 10.1039/C6TA02891H 10.1002/adma.201506197 10.1002/adma.201205332 10.1002/cplu.201500347 10.1016/S1452-3981(23)06572-0 10.1002/aenm.201501497 |
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Keywords | Oxygen Reduction Reaction Oxygen Reduction Reaction Activity Microbial Fuel Cell Maximum Power Density NiCo2O4 |
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Snippet | The high efficiency of cathode catalyst used in the oxygen reduction reaction is a vital factor guaranteeing for the microbial fuel cells (MFCs). In this work,... |
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SubjectTerms | Biochemical fuel cells Catalysis Catalysts Cathodes Characterization and Evaluation of Materials Chemistry and Materials Science Classical Mechanics Cobalt ores Crystallography and Scattering Methods Electric power generation Fuel cell industry Fuel cells Materials Science Maximum power density microbial fuel cells Microorganisms nickel Nickel compounds Original Paper oxides oxygen Oxygen reduction reactions Polymer Sciences power generation Solid Mechanics Transition metal oxides Transition metals |
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Title | Nickel cobaltite@nanocarbon hybrid materials as efficient cathode catalyst for oxygen reduction in microbial fuel cells |
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