Carbon nanotubes and silver flakes filled epoxy resin for new hybrid conductive adhesives
Combining conductive micro and nanofillers is a new way to improve electrical conductivity. Micrometric silver flakes and nanometric carbon nanotubes (CNTs) exhibit high electrical conductivity. A new type of hybrid conductive adhesives filled with silver flakes and carbon nanotubes (DWCNTs or MWCNT...
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Published in | Microelectronics and reliability Vol. 51; no. 7; pp. 1230 - 1234 |
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Main Authors | , , , , , , , |
Format | Journal Article Conference Proceeding |
Language | English |
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Elsevier Ltd
01.07.2011
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Abstract | Combining conductive micro and nanofillers is a new way to improve electrical conductivity. Micrometric silver flakes and nanometric carbon nanotubes (CNTs) exhibit high electrical conductivity. A new type of hybrid conductive adhesives filled with silver flakes and carbon nanotubes (DWCNTs or MWCNTs) were investigated. High electrical conductivity is measured as well as improved mechanical properties at room temperature. Small agglomerates and free MWCNTs dispersed in the silver/epoxy composites improve the electrical conductivity and a synergistic effect between MWCNTs and micro sized silver flakes is observed in hybrid composites. Glassy and rubbery storage moduli of the hybrid composites increase with increasing silver loading at fixed CNTs volume fraction. High value of the storage modulus, measured in DWCNTs/μAg hybrid composites at rubbery state, is caused by strong agglomeration of DWCNTs bundles. The electrical and mechanical properties are consistent with the morphologies of the hybrid composites characterized by SEM. |
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AbstractList | Combining conductive micro and nanofillers is a new way to improve electrical conductivity. Micrometric silver flakes and nanometric carbon nanotubes (CNTs) exhibit high electrical conductivity. A new type of hybrid conductive adhesives filled with silver flakes and carbon nanotubes (DWCNTs or MWCNTs) were investigated. High electrical conductivity is measured as well as improved mechanical properties at room temperature. Small agglomerates and free MWCNTs dispersed in the silver/epoxy composites improve the electrical conductivity and a synergistic effect between MWCNTs and micro sized silver flakes is observed in hybrid composites. Glassy and rubbery storage moduli of the hybrid composites increase with increasing silver loading at fixed CNTs volume fraction. High value of the storage modulus, measured in DWCNTs/μAg hybrid composites at rubbery state, is caused by strong agglomeration of DWCNTs bundles. The electrical and mechanical properties are consistent with the morphologies of the hybrid composites characterized by SEM. Combining conductive micro and nanofillers is a new way to improve electrical conductivity. Micrometric silver flakes and nanometric carbon nanotubes (CNTs) exhibit high electrical conductivity. A new type of hybrid conductive adhesives filled with silver flakes and carbon nanotubes (DWCNTs or MWCNTs) were investigated. High electrical conductivity is measured as well as improved mechanical properties at room temperature. Small agglomerates and free MWCNTs dispersed in the silver/epoxy composites improve the electrical conductivity and a synergistic effect between MWCNTs and micro sized silver flakes is observed in hybrid composites. Glassy and rubbery storage moduli of the hybrid composites increase with increasing silver loading at fixed CNTs volume fraction. High value of the storage modulus, measured in DWCNTs/[micro]Ag hybrid composites at rubbery state, is caused by strong agglomeration of DWCNTs bundles. The electrical and mechanical properties are consistent with the morphologies of the hybrid composites characterized by SEM. |
Author | Peigney, A. Marcq, F. Monfraix, P. Falat, T. Laurent, Ch Jamin, T. Demont, P. Courtade, F. |
Author_xml | – sequence: 1 givenname: F. surname: Marcq fullname: Marcq, F. email: marcq@cict.fr organization: Université de Toulouse, Institut Carnot CIRIMAT, Université Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 09, France – sequence: 2 givenname: P. surname: Demont fullname: Demont, P. organization: Université de Toulouse, Institut Carnot CIRIMAT, Université Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 09, France – sequence: 3 givenname: P. surname: Monfraix fullname: Monfraix, P. organization: Thalès Alenia Space 26 Avenue J.-F. Champollion B.P. 33787 31037 Toulouse Cedex 1, France – sequence: 4 givenname: A. surname: Peigney fullname: Peigney, A. organization: Université de Toulouse, Institut Carnot CIRIMAT, Université Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 09, France – sequence: 5 givenname: Ch surname: Laurent fullname: Laurent, Ch organization: Université de Toulouse, Institut Carnot CIRIMAT, Université Paul Sabatier, 118 route de Narbonne 31062 Toulouse Cedex 09, France – sequence: 6 givenname: T. surname: Falat fullname: Falat, T. organization: Wroclaw University of Technology, Faculty of Microsystem Electronics and Photonics, Janiszewskiego 11/17, 50-372 Wroclaw, Poland – sequence: 7 givenname: F. surname: Courtade fullname: Courtade, F. organization: Centre National d’Etudes Spatiales 18 Av. E. Belin 31401 Toulouse Cedex 9, France – sequence: 8 givenname: T. surname: Jamin fullname: Jamin, T. organization: Centre National d’Etudes Spatiales 18 Av. E. Belin 31401 Toulouse Cedex 9, France |
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Keywords | Silver Electrical conductivity Composite materials Ambient temperature Hybrid material Epoxy resin Carbon nanotubes Mechanical properties Conducting materials Electrical characteristic Adhesive material MWCNTs SEM DWCNTs |
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Snippet | Combining conductive micro and nanofillers is a new way to improve electrical conductivity. Micrometric silver flakes and nanometric carbon nanotubes (CNTs)... |
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SubjectTerms | Carbon nanotubes Chemical Sciences Cross-disciplinary physics: materials science; rheology Electrical conductivity Electrical resistivity Exact sciences and technology Flakes Hybrid composites Material chemistry Materials science Nanoscale materials and structures: fabrication and characterization Nanostructure Nanotubes Physics Resistivity Silver |
Title | Carbon nanotubes and silver flakes filled epoxy resin for new hybrid conductive adhesives |
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