Lignin composite ionic liquid lubricants with excellent anti-corrosion, anti-oxidation, and tribological properties
A new type of lubricating material (BTA-P 4444 -Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P 4444 -Lig as a lubricant were investigated. The lubricating material exhibit...
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| Abstract | A new type of lubricating material (BTA-P
4444
-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P
4444
-Lig as a lubricant were investigated. The lubricating material exhibits excellent friction reduction and wear resistance, as well as good thermal stability and excellent oxidation resistance. Mechanistic analysis reveals that the active elements N and P in the lubricating material react with the metal substrate, and the reaction film effectively blocks direct contact between the friction pairs, affording excellent friction reduction and wear resistance. At the same time, the phenolic hydroxyl group in lignin reacts with oxygen free radicals to form a resonance-stable semi-quinone free radical, which interrupts the chain reaction and affords good anti-oxidant activity. |
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| AbstractList | A new type of lubricating material (BTA-P4444-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P4444-Lig as a lubricant were investigated. The lubricating material exhibits excellent friction reduction and wear resistance, as well as good thermal stability and excellent oxidation resistance. Mechanistic analysis reveals that the active elements N and P in the lubricating material react with the metal substrate, and the reaction film effectively blocks direct contact between the friction pairs, affording excellent friction reduction and wear resistance. At the same time, the phenolic hydroxyl group in lignin reacts with oxygen free radicals to form a resonance-stable semi-quinone free radical, which interrupts the chain reaction and affords good anti-oxidant activity. Abstract A new type of lubricating material (BTA-P4444-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P4444-Lig as a lubricant were investigated. The lubricating material exhibits excellent friction reduction and wear resistance, as well as good thermal stability and excellent oxidation resistance. Mechanistic analysis reveals that the active elements N and P in the lubricating material react with the metal substrate, and the reaction film effectively blocks direct contact between the friction pairs, affording excellent friction reduction and wear resistance. At the same time, the phenolic hydroxyl group in lignin reacts with oxygen free radicals to form a resonance-stable semi-quinone free radical, which interrupts the chain reaction and affords good anti-oxidant activity. A new type of lubricating material (BTA-P 4444 -Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological properties, corrosion resistance, and anti-oxidation properties of BTA-P 4444 -Lig as a lubricant were investigated. The lubricating material exhibits excellent friction reduction and wear resistance, as well as good thermal stability and excellent oxidation resistance. Mechanistic analysis reveals that the active elements N and P in the lubricating material react with the metal substrate, and the reaction film effectively blocks direct contact between the friction pairs, affording excellent friction reduction and wear resistance. At the same time, the phenolic hydroxyl group in lignin reacts with oxygen free radicals to form a resonance-stable semi-quinone free radical, which interrupts the chain reaction and affords good anti-oxidant activity. |
| Author | Huang, Qing Zhou, Feng Yu, Qiangliang Yang, Wufang Zhou, Chunyu Yu, Bo Wang, Xingwei Yang, Zhiquan Cai, Meirong Zhang, Chaoyang |
| AuthorAffiliation | State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China%PetroChina Lanzhou Lubricating Oil R&D Institute,Lanzhou 730060,China%Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing,Yantai 264006,China%State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing,Yantai 264006,China;Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering,Yantai 264006,China%Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering,Yantai 264006,China |
| AuthorAffiliation_xml | – name: State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China%PetroChina Lanzhou Lubricating Oil R&D Institute,Lanzhou 730060,China%Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing,Yantai 264006,China%State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing,Yantai 264006,China;Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering,Yantai 264006,China%Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering,Yantai 264006,China |
| Author_xml | – sequence: 1 givenname: Chaoyang surname: Zhang fullname: Zhang, Chaoyang organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 2 givenname: Zhiquan surname: Yang fullname: Yang, Zhiquan organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences – sequence: 3 givenname: Qing surname: Huang fullname: Huang, Qing organization: PetroChina Lanzhou Lubricating Oil R&D Institute – sequence: 4 givenname: Xingwei surname: Wang fullname: Wang, Xingwei organization: Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing – sequence: 5 givenname: Wufang surname: Yang fullname: Yang, Wufang organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering – sequence: 6 givenname: Chunyu surname: Zhou fullname: Zhou, Chunyu organization: Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering – sequence: 7 givenname: Bo surname: Yu fullname: Yu, Bo organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering – sequence: 8 givenname: Qiangliang surname: Yu fullname: Yu, Qiangliang email: yql@licp.cas.cn organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering – sequence: 9 givenname: Meirong surname: Cai fullname: Cai, Meirong email: caimr@licp.cas.cn organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Shandong Laboratory of Yantai Advanced Materials and Green Manufacturing, Yantai Zhongke Research Institute of Advanced Materials and Green Chemical Engineering – sequence: 10 givenname: Feng surname: Zhou fullname: Zhou, Feng organization: State Key Laboratory of Solid Lubrication, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences |
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| Snippet | A new type of lubricating material (BTA-P
4444
-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological... A new type of lubricating material (BTA-P4444-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological... A new type of lubricating material(BTA-P4444-Lig)was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole.The tribological... Abstract A new type of lubricating material (BTA-P4444-Lig) was synthesized by combining lignin with tetrabutylphosphorus and benzotriazole. The tribological... |
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| SubjectTerms | anti-oxidant Benzotriazole Composite materials Corrosion Corrosion and Coatings Corrosion prevention Corrosion resistance Design Engineering Free radicals Friction Friction reduction Green chemistry Hydroxyl groups ionic liquid Ionic liquids Ions Kinematics Laboratories Lignin Lubricants Lubricants & lubrication Lubrication Mechanical Engineering Mechanical properties Molecular structure Nanotechnology Oxidation Oxidation resistance Oxidizing agents Physical Chemistry Pollution Polyethylene glycol Quinones Research Article Rheology Stability analysis Substrates Surfaces and Interfaces Thermal stability Thin Films Tribology Vacuum distillation Viscosity Wear resistance |
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| Title | Lignin composite ionic liquid lubricants with excellent anti-corrosion, anti-oxidation, and tribological properties |
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