Support Effect of Palladium Catalysts for Naphthalene Hydrogenation as Model Hydrogen Storage Process Using Low Grade Hydrogen Containing CO

The organic hydride method utilizes the reversible hydrogenation-dehydrogenation cycle of aromatic hydrocarbons for the storage and transportation of hydrogen. If low-grade hydrogen containing CO impurity is used in the hydrogenation process, storage and purification of hydrogen can be attained simu...

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Published inJournal of the Japan Petroleum Institute Vol. 52; no. 1; pp. 10 - 15
Main Authors Ezuka, Koji, Ohshima, Masaaki, Kurokawa, Hideki, Miura, Hiroshi
Format Journal Article
LanguageEnglish
Published Tokyo The Japan Petroleum Institute 2009
Japan Science and Technology Agency
Subjects
Carbon monoxide
Carbon monoxide poisoning
Catalysis
Catalysts
Hydrogen storage
Hydrogenation
Naphthalene
Naphthalene hydrogenation
Organic hydride method
Palladium
Silica-alumina support
Silicon dioxide
Spectra
Supported palladium catalyst
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Abstract The organic hydride method utilizes the reversible hydrogenation-dehydrogenation cycle of aromatic hydrocarbons for the storage and transportation of hydrogen. If low-grade hydrogen containing CO impurity is used in the hydrogenation process, storage and purification of hydrogen can be attained simultaneously. This study investigated the effect of Pd on SiO2, Al2O3 and SiO2-Al2O3 catalyst supports on the hydrogenation of naphthalene in the presence of CO. Pd/Al2O3 catalyst had the highest activity for hydrogenation using pure hydrogen. However, Pd/SiO2-Al2O3 showed the highest activity using 2%CO/H2. All catalysts allowed only the hydrogenation of naphthalene to proceed and no CO hydrogenation was observed. CO probe FT-IR spectra were observed at elevated temperatures. Desorption behavior was dependent on the catalysts and, especially on the lower wavenumber side, strongly adsorbed CO changed more significantly with the catalyst. CO desorption behavior of Pd/SiO2-Al2O3 indicated weak Pd-CO bond. Deconvolution of the IR spectra showed that the acidity of the SiO2-Al2O3 support decreased the electron density of Pd, resulting in weakening of the Pd-CO bond, which promoted the high hydrogenation activity in the presence of CO.
AbstractList The organic hydride method utilizes the reversible hydrogenation-dehydrogenation cycle of aromatic hydrocarbons for the storage and transportation of hydrogen. If low-grade hydrogen containing CO impurity is used in the hydrogenation process, storage and purification of hydrogen can be attained simultaneously. This study investigated the effect of Pd on SiO2, Al2O3 and SiO2-Al2O3 catalyst supports on the hydrogenation of naphthalene in the presence of CO. Pd/Al2O3 catalyst had the highest activity for hydrogenation using pure hydrogen. However, Pd/SiO2-Al2O3 showed the highest activity using 2%CO/H2. All catalysts allowed only the hydrogenation of naphthalene to proceed and no CO hydrogenation was observed. CO probe FT-IR spectra were observed at elevated temperatures. Desorption behavior was dependent on the catalysts and, especially on the lower wavenumber side, strongly adsorbed CO changed more significantly with the catalyst. CO desorption behavior of Pd/SiO2-Al2O3 indicated weak Pd-CO bond. Deconvolution of the IR spectra showed that the acidity of the SiO2-Al2O3 support decreased the electron density of Pd, resulting in weakening of the Pd-CO bond, which promoted the high hydrogenation activity in the presence of CO.
The organic hydride method utilizes the reversible hydrogenation-dehydrogenation cycle of aromatic hydrocarbons for the storage and transportation of hydrogen. If low-grade hydrogen containing CO impurity is used in the hydrogenation process, storage and purification of hydrogen can be attained simultaneously. This study investigated the effect of Pd on SiO sub(2), Al sub(2)O sub(3) and SiO sub(2)-Al sub(2)O sub(3) catalyst supports on the hydrogenation of naphthalene in the presence of CO. Pd/Al sub(2)O sub(3) catalyst had the highest activity for hydrogenation using pure hydrogen. However, Pd/SiO sub(2)-Al sub(2)O sub(3) showed the highest activity using 2%CO/H sub(2). All catalysts allowed only the hydrogenation of naphthalene to proceed and no CO hydrogenation was observed. CO probe FT-IR spectra were observed at elevated temperatures. Desorption behavior was dependent on the catalysts and, especially on the lower wavenumber side, strongly adsorbed CO changed more significantly with the catalyst. CO desorption behavior of Pd/SiO sub(2)-Al sub(2)O sub(3) indicated weak Pd-CO bond. Deconvolution of the IR spectra showed that the acidity of the SiO sub(2)-Al sub(2)O sub(3) support decreased the electron density of Pd, resulting in weakening of the Pd-CO bond, which promoted the high hydrogenation activity in the presence of CO.
Author Miura, Hiroshi
Kurokawa, Hideki
Ezuka, Koji
Ohshima, Masaaki
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crossref_primary_10_1627_jpi_53_239
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crossref_primary_10_1016_j_ijhydene_2019_10_018
crossref_primary_10_1016_j_ijhydene_2014_07_158
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Snippet The organic hydride method utilizes the reversible hydrogenation-dehydrogenation cycle of aromatic hydrocarbons for the storage and transportation of hydrogen....
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SubjectTerms Carbon monoxide
Carbon monoxide poisoning
Catalysis
Catalysts
Hydrogen storage
Hydrogenation
Naphthalene
Naphthalene hydrogenation
Organic hydride method
Palladium
Silica-alumina support
Silicon dioxide
Spectra
Supported palladium catalyst
Title Support Effect of Palladium Catalysts for Naphthalene Hydrogenation as Model Hydrogen Storage Process Using Low Grade Hydrogen Containing CO
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