A single-stranded coordination copolymer affords heterostructure observation and photoluminescence intensification
A single-stranded coordination copolymer is subject to copolymer structure visualization by ambient AFM and photoluminescence enhancement. Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a co...
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| Published in | Science advances Vol. 5; no. 1; p. eaau0637 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
United States
American Association for the Advancement of Science
01.01.2019
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| Subjects | |
| Online Access | Get full text |
| ISSN | 2375-2548 2375-2548 |
| DOI | 10.1126/sciadv.aau0637 |
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| Abstract | A single-stranded coordination copolymer is subject to copolymer structure visualization by ambient AFM and photoluminescence enhancement.
Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a copolymer structure; this is in contrast with biopolymers such as single-strand DNAs. Here, we create a set of one-dimensional coordination copolymers featuring bis(dipyrrinato)zinc complex motifs in the main chain. A series of random copolymers is synthesized from two types of bridging dipyrrin proligand and zinc acetate, with various molar ratios between the proligands. Sonication of the bulk solid copolymer in organic solvent exfoliates single strands with lengths of 1.4 to 3.0 μm. Atomic force microscopy at ambient conditions visualizes the copolymer structure as height distributions. The copolymer structure improves its photoluminescence (up to 32%) relative to that of the corresponding homopolymers (3 and 10%). Numerical simulation based on a restricted random walk model reproduces the photoluminescence intensification, suggesting at the same time the existence of fast intrawire exciton hopping. |
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| AbstractList | A single-stranded coordination copolymer is subject to copolymer structure visualization by ambient AFM and photoluminescence enhancement.
Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a copolymer structure; this is in contrast with biopolymers such as single-strand DNAs. Here, we create a set of one-dimensional coordination copolymers featuring bis(dipyrrinato)zinc complex motifs in the main chain. A series of random copolymers is synthesized from two types of bridging dipyrrin proligand and zinc acetate, with various molar ratios between the proligands. Sonication of the bulk solid copolymer in organic solvent exfoliates single strands with lengths of 1.4 to 3.0 μm. Atomic force microscopy at ambient conditions visualizes the copolymer structure as height distributions. The copolymer structure improves its photoluminescence (up to 32%) relative to that of the corresponding homopolymers (3 and 10%). Numerical simulation based on a restricted random walk model reproduces the photoluminescence intensification, suggesting at the same time the existence of fast intrawire exciton hopping. Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a copolymer structure; this is in contrast with biopolymers such as single-strand DNAs. Here, we create a set of one-dimensional coordination copolymers featuring bis(dipyrrinato)zinc complex motifs in the main chain. A series of random copolymers is synthesized from two types of bridging dipyrrin proligand and zinc acetate, with various molar ratios between the proligands. Sonication of the bulk solid copolymer in organic solvent exfoliates single strands with lengths of 1.4 to 3.0 μm. Atomic force microscopy at ambient conditions visualizes the copolymer structure as height distributions. The copolymer structure improves its photoluminescence (up to 32%) relative to that of the corresponding homopolymers (3 and 10%). Numerical simulation based on a restricted random walk model reproduces the photoluminescence intensification, suggesting at the same time the existence of fast intrawire exciton hopping.Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a copolymer structure; this is in contrast with biopolymers such as single-strand DNAs. Here, we create a set of one-dimensional coordination copolymers featuring bis(dipyrrinato)zinc complex motifs in the main chain. A series of random copolymers is synthesized from two types of bridging dipyrrin proligand and zinc acetate, with various molar ratios between the proligands. Sonication of the bulk solid copolymer in organic solvent exfoliates single strands with lengths of 1.4 to 3.0 μm. Atomic force microscopy at ambient conditions visualizes the copolymer structure as height distributions. The copolymer structure improves its photoluminescence (up to 32%) relative to that of the corresponding homopolymers (3 and 10%). Numerical simulation based on a restricted random walk model reproduces the photoluminescence intensification, suggesting at the same time the existence of fast intrawire exciton hopping. Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a copolymer structure; this is in contrast with biopolymers such as single-strand DNAs. Here, we create a set of one-dimensional coordination copolymers featuring bis(dipyrrinato)zinc complex motifs in the main chain. A series of random copolymers is synthesized from two types of bridging dipyrrin proligand and zinc acetate, with various molar ratios between the proligands. Sonication of the bulk solid copolymer in organic solvent exfoliates single strands with lengths of 1.4 to 3.0 μm. Atomic force microscopy at ambient conditions visualizes the copolymer structure as height distributions. The copolymer structure improves its photoluminescence (up to 32%) relative to that of the corresponding homopolymers (3 and 10%). Numerical simulation based on a restricted random walk model reproduces the photoluminescence intensification, suggesting at the same time the existence of fast intrawire exciton hopping. |
| Author | Fukui, Naoya Tsuchiya, Mizuho Sakamoto, Ryota Matsuoka, Ryota Nishihara, Hiroshi Toyoda, Ryojun |
| Author_xml | – sequence: 1 givenname: Ryojun orcidid: 0000-0002-0168-0533 surname: Toyoda fullname: Toyoda, Ryojun organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan – sequence: 2 givenname: Ryota orcidid: 0000-0002-8702-1378 surname: Sakamoto fullname: Sakamoto, Ryota organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan., JST-PRESTO, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan – sequence: 3 givenname: Naoya surname: Fukui fullname: Fukui, Naoya organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan – sequence: 4 givenname: Ryota orcidid: 0000-0002-2658-9322 surname: Matsuoka fullname: Matsuoka, Ryota organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan – sequence: 5 givenname: Mizuho surname: Tsuchiya fullname: Tsuchiya, Mizuho organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan – sequence: 6 givenname: Hiroshi orcidid: 0000-0002-6568-5640 surname: Nishihara fullname: Nishihara, Hiroshi organization: Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30613768$$D View this record in MEDLINE/PubMed |
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| CitedBy_id | crossref_primary_10_1002_chem_201806330 crossref_primary_10_1038_s41467_025_56381_0 crossref_primary_10_1246_bcsj_20200362 crossref_primary_10_1016_j_ccr_2022_214735 crossref_primary_10_1515_ncrs_2022_0307 crossref_primary_10_1016_j_cocr_2025_100006 crossref_primary_10_1002_asia_202100670 crossref_primary_10_1016_j_ccr_2022_214787 crossref_primary_10_1038_s41467_022_33177_0 crossref_primary_10_1126_sciadv_abd9887 crossref_primary_10_1063_5_0197941 crossref_primary_10_1016_j_ccr_2020_213661 |
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| Snippet | A single-stranded coordination copolymer is subject to copolymer structure visualization by ambient AFM and photoluminescence enhancement.
Few artificial... Few artificial systems can be exfoliated into, and observed as, single wires with lengths of more than several micrometers, and no previous example features a... |
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| Title | A single-stranded coordination copolymer affords heterostructure observation and photoluminescence intensification |
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