Specific ion effects directed noble metal aerogels: Versatile manipulation for electrocatalysis and beyond

Noble metal foams (NMFs) are a new class of functional materials featuring properties of both noble metals and monolithic porous materials, providing impressive prospects in diverse fields. Among reported synthetic methods, the sol-gel approach manifests overwhelming advantages for versatile synthes...

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Published inScience advances Vol. 5; no. 5; p. eaaw4590
Main Authors Du, Ran, Hu, Yue, Hübner, René, Joswig, Jan-Ole, Fan, Xuelin, Schneider, Kristian, Eychmüller, Alexander
Format Journal Article
LanguageEnglish
Published United States American Association for the Advancement of Science 01.05.2019
Subjects
Chemistry
Materials Science
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Abstract Noble metal foams (NMFs) are a new class of functional materials featuring properties of both noble metals and monolithic porous materials, providing impressive prospects in diverse fields. Among reported synthetic methods, the sol-gel approach manifests overwhelming advantages for versatile synthesis of nanostructured NMFs (i.e., noble metal aerogels) under mild conditions. However, limited gelation methods and elusive formation mechanisms retard structure/composition manipulation, hampering on-demand design for practical applications. Here, highly tunable NMFs are fabricated by activating specific ion effects, enabling various single/alloy aerogels with adjustable composition (Au, Ag, Pd, and Pt), ligament sizes (3.1 to 142.0 nm), and special morphologies. Their superior performance in programmable self-propulsion devices and electrocatalytic alcohol oxidation is also demonstrated. This study provides a conceptually new approach to fabricate and manipulate NMFs and an overall framework for understanding the gelation mechanism, paving the way for on-target design of NMFs and investigating structure-performance relationships for versatile applications.
AbstractList Specific ion effects are demonstrated to create and flexibly manipulate noble metal aerogels for versatile applications. Noble metal foams (NMFs) are a new class of functional materials featuring properties of both noble metals and monolithic porous materials, providing impressive prospects in diverse fields. Among reported synthetic methods, the sol-gel approach manifests overwhelming advantages for versatile synthesis of nanostructured NMFs (i.e., noble metal aerogels) under mild conditions. However, limited gelation methods and elusive formation mechanisms retard structure/composition manipulation, hampering on-demand design for practical applications. Here, highly tunable NMFs are fabricated by activating specific ion effects, enabling various single/alloy aerogels with adjustable composition (Au, Ag, Pd, and Pt), ligament sizes (3.1 to 142.0 nm), and special morphologies. Their superior performance in programmable self-propulsion devices and electrocatalytic alcohol oxidation is also demonstrated. This study provides a conceptually new approach to fabricate and manipulate NMFs and an overall framework for understanding the gelation mechanism, paving the way for on-target design of NMFs and investigating structure-performance relationships for versatile applications.
Noble metal foams (NMFs) are a new class of functional materials featuring properties of both noble metals and monolithic porous materials, providing impressive prospects in diverse fields. Among reported synthetic methods, the sol-gel approach manifests overwhelming advantages for versatile synthesis of nanostructured NMFs (i.e., noble metal aerogels) under mild conditions. However, limited gelation methods and elusive formation mechanisms retard structure/composition manipulation, hampering on-demand design for practical applications. Here, highly tunable NMFs are fabricated by activating specific ion effects, enabling various single/alloy aerogels with adjustable composition (Au, Ag, Pd, and Pt), ligament sizes (3.1 to 142.0 nm), and special morphologies. Their superior performance in programmable self-propulsion devices and electrocatalytic alcohol oxidation is also demonstrated. This study provides a conceptually new approach to fabricate and manipulate NMFs and an overall framework for understanding the gelation mechanism, paving the way for on-target design of NMFs and investigating structure-performance relationships for versatile applications.
Author Du, Ran
Joswig, Jan-Ole
Eychmüller, Alexander
Hübner, René
Fan, Xuelin
Hu, Yue
Schneider, Kristian
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  organization: College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325000, China
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  surname: Hübner
  fullname: Hübner, René
  organization: Helmholtz-Zentrum Dresden-Rossendorf, Institute of Ion Beam Physics and Materials Research, Bautzner Landstrasse 400, 01328 Dresden, Germany
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  givenname: Jan-Ole
  orcidid: 0000-0002-8296-4924
  surname: Joswig
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  organization: Theoretische Chemie, Fakultät für Chemie und Lebensmittelchemie, Technische Universität Dresden, 01062 Dresden, Germany
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  givenname: Kristian
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  organization: Physical Chemistry, Technische Universität Dresden, Bergstr. 66b, 01062 Dresden, Germany
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  givenname: Alexander
  orcidid: 0000-0001-9926-6279
  surname: Eychmüller
  fullname: Eychmüller, Alexander
  organization: Physical Chemistry, Technische Universität Dresden, Bergstr. 66b, 01062 Dresden, Germany
BackLink https://www.ncbi.nlm.nih.gov/pubmed/31139750$$D View this record in MEDLINE/PubMed
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Snippet Noble metal foams (NMFs) are a new class of functional materials featuring properties of both noble metals and monolithic porous materials, providing...
Specific ion effects are demonstrated to create and flexibly manipulate noble metal aerogels for versatile applications. Noble metal foams (NMFs) are a new...
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Title Specific ion effects directed noble metal aerogels: Versatile manipulation for electrocatalysis and beyond
URI https://www.ncbi.nlm.nih.gov/pubmed/31139750
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