Construction of Crosslink-System-Materials Utilizing Designed Network-Polymer-Precursor Modules
For a long time, we have been concerned with the elucidation of network formation mechanism of free‐radical crosslinking (co)polymerization of multivinyl monomers. We have pursued two extreme network structures formation such as ideal and nanogel‐like NPP formation. During the course of these invest...
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| Published in | Macromolecular Symposia Vol. 306-307; no. 1; pp. 89 - 98 |
|---|---|
| Main Author | |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
WILEY-VCH Verlag
01.09.2011
Wiley WILEY‐VCH Verlag |
| Subjects | |
| Online Access | Get full text |
| ISSN | 1022-1360 1521-3900 1521-3900 |
| DOI | 10.1002/masy.201000123 |
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| Abstract | For a long time, we have been concerned with the elucidation of network formation mechanism of free‐radical crosslinking (co)polymerization of multivinyl monomers. We have pursued two extreme network structures formation such as ideal and nanogel‐like NPP formation. During the course of these investigations, we recognized that a network polymer may be reconsidered as a crosslink‐system‐material (CSM) or a giant system consisting of network polymer precursor (NPP) modules. The network polymer is not a giant molecule as a smallest unit of matter which could behave as one molecule. According to this definition, our subject may be changed from the molecular design of network polymer to the molecular design of NPP based on the free‐radical crosslinking multivinyl polymerization mechanism. Then, we could construct a variety of CSMs utilizing designed NPP modules. A variety of CSM constructions are exemplified. |
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| AbstractList | For a long time, we have been concerned with the elucidation of network formation mechanism of free‐radical crosslinking (co)polymerization of multivinyl monomers. We have pursued two extreme network structures formation such as ideal and nanogel‐like NPP formation. During the course of these investigations, we recognized that a network polymer may be reconsidered as a crosslink‐system‐material (CSM) or a giant system consisting of network polymer precursor (NPP) modules. The network polymer is not a giant molecule as a smallest unit of matter which could behave as one molecule. According to this definition, our subject may be changed from the molecular design of network polymer to the molecular design of NPP based on the free‐radical crosslinking multivinyl polymerization mechanism. Then, we could construct a variety of CSMs utilizing designed NPP modules. A variety of CSM constructions are exemplified. |
| Author | Matsumoto, Akira |
| Author_xml | – sequence: 1 givenname: Akira surname: Matsumoto fullname: Matsumoto, Akira email: amatsu@kansai-u.ac.jp organization: Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, 3-3-35 Yamate-cho, Suita-shi, Osaka 564-8680, Japan |
| BackLink | https://cir.nii.ac.jp/crid/1870865117758871424$$DView record in CiNii |
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Bartlett, R. Altschul, J. Am. Chem. Soc. 1945, 67, 812. A. Matsumoto, H. Yamasaki, M. Katsumoto, H. Aota, Y. Takayama, A. Kameyama, T. Nakanishi, Eur. Polym. J. 2000, 36, 1741. A. Matsumoto, S. Nakatani, S. Shitatani, H. Aota, J. Ikeda, Nettowaku Porima 2008, 29, 2. 1941; 63 2009; 47 2002; 14 1991; 12 2004; 7 2000; 41 1975; 13 1983; 10 2003; 15 2007; 28 2003; 90 1948; 1 2008; 29 2004; 37 1983; 21 1995; 123 2005; 38 1935; 68 2003; 41 1989 1973; 166 1946; 65 2004; 42 1995; 93 2000; 25 1954; 22 2010 1998; A35 2002; 34 1969; 10 1980; 21 1981; 4 2003; 36 2007 2003; 39 1998; 136 2004 1963; C3 1996; 240 1989; 27 2007; 58 1944; 12 2010; 43 2004; 94 2000; 38 1977; 15 1990; 26 2000; 36 2000; 78 1984; 7 1980; 3 1945; 67 1999; 32 1999; 31 2008; 41 1998; 7 e_1_2_3_50_2 Matsumoto A. (e_1_2_3_12_2) 2007; 28 e_1_2_3_4_2 e_1_2_3_16_2 e_1_2_3_37_2 e_1_2_3_2_2 e_1_2_3_18_2 e_1_2_3_39_2 Matsumoto A. (e_1_2_3_52_2) 2008; 29 e_1_2_3_56_2 e_1_2_3_8_2 e_1_2_3_6_2 e_1_2_3_35_2 Matsumoto A. (e_1_2_3_53_2) 2007 e_1_2_3_54_2 e_1_2_3_10_2 e_1_2_3_31_2 (e_1_2_3_15_2) 1989 e_1_2_3_26_2 e_1_2_3_49_2 e_1_2_3_28_2 e_1_2_3_22_2 e_1_2_3_24_2 e_1_2_3_47_2 e_1_2_3_41_2 e_1_2_3_20_2 e_1_2_3_43_2 Odian G. (e_1_2_3_45_2) 2004 e_1_2_3_19_2 e_1_2_3_1_2 e_1_2_3_5_2 Keutgen W. A. (e_1_2_3_14_2) 1969 e_1_2_3_38_2 e_1_2_3_3_2 e_1_2_3_17_2 e_1_2_3_9_2 e_1_2_3_11_2 e_1_2_3_34_2 e_1_2_3_55_2 e_1_2_3_7_2 e_1_2_3_13_2 e_1_2_3_57_2 e_1_2_3_30_2 e_1_2_3_51_2 e_1_2_3_32_2 Matsumoto A. (e_1_2_3_36_2) 1991; 12 Erath E. H. (e_1_2_3_33_2) 1963; 3 e_1_2_3_27_2 e_1_2_3_48_2 e_1_2_3_29_2 e_1_2_3_23_2 e_1_2_3_44_2 e_1_2_3_25_2 e_1_2_3_46_2 e_1_2_3_40_2 e_1_2_3_21_2 e_1_2_3_42_2 |
| References_xml | – reference: C. Walling, J. Am. Chem. Soc. 1945, 67, 441. – reference: A. Matsumoto, T. Ohashi, H. Oe, H. Aota, J. Ikeda, J. Polym. Sci.: Part A: Polym. Chem. 2000, 38, 4396. – reference: A. Matsumoto, A. Okamoto, S. Okuno, H. Aota, Angew. Makromol. Chem. 1996, 240, 275. – reference: T. Kiguchi, H. Aota, A. Matsumoto, Macromolecules 2004, 37, 8249. – reference: A. Matsumoto, H. Hayashi, H. Aota, Polymeric Microsperes, Kyoto Univ. Press, Kyoto 2007, p. 147. – reference: A. Matsumoto, K. Aoki, M. Oiwa, M. Ochi, M. Shimbo, Polym. Bull. 1983, 10, 438. – reference: M. Doura, Y. Naka, H. Aota, A. Matsumoto, Macromolecules 2005, 38, 5955. – reference: A. Matsumoto, H. Sasaki, M. Oiwa, Makromol. Chem. 1973, 166, 179. – reference: A. Matsumoto, Y. Ogasawara, S. Nishikawa, T. Aso, M. Oiwa, J. Polym. Sci.: Part A: Polym. Chem. 1989, 27, 839. – reference: K. Dusek, H. Galina, J. Mikes, Polym. Bull. 1980, 3, 19. – reference: A. Matsumoto, K. Watanabe, H. Aota, Y. Takayama, A. Kameyama, T. Nakanishi, Polymer, 2000, 41, 3883. – reference: A. Matsumoto, Y. Kitaguchi, O. Sonoda, Macromolecules 1999, 32, 8336. – reference: A. Matsumoto, Adv. Polym. Sci. 1995, 123, 41. – reference: P. J. Flory, J. Am. Chem. Soc. 1941, 63, 3083. – reference: A. Matsumoto, M. Fujihashi, H. Aota, Eur. Polym. J. 2003, 39, 2023. – reference: A. Matsumoto, K. Yokoyama, H. Aota, J. Appl. Polym. Sci. 2000, 78, 692. – reference: T. Kiguchi, H. Aota, A. Matsumoto, J. Appl. Polym. Sci. 2004, 94, 1198. – reference: A. Matsumoto, Y. Miwa, S. Inoue, T. Enomoto, H. Aota, Macromolecules 2010, 43, 6834. – reference: W. H. Stockmayer, J. Chem. Phys. 1944, 12, 125. – reference: T. Kiguchi, H. Aota, A. Matsumoto, J. Polym. Sci., Part A: Polym. Chem. 2003, 41, 606. – reference: A. Matsumoto, H. Aota, Designed Monomers and Polymers 2004, 7, 687. – reference: J. Ikeda, H. Oe, H. Aota, A. Matsumoto, J. Appl. Polym. Sci. 2003, 90, 577. – reference: P. D. Bartlett, R. Altschul, J. Am. Chem. 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| Snippet | For a long time, we have been concerned with the elucidation of network formation mechanism of free‐radical crosslinking (co)polymerization of multivinyl... For a long time, we have been concerned with the elucidation of network formation mechanism of free-radical crosslinking (co)polymerization of multivinyl... |
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| SubjectTerms | Construction crosslink-system-material Crosslinking Design engineering free-radical polymerization Modules multiallyl monomer multivinyl monomer Nanocomposites Nanomaterials Nanostructure network polymer precursor Networks |
| Title | Construction of Crosslink-System-Materials Utilizing Designed Network-Polymer-Precursor Modules |
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