Preparation and characterization of foamed polyurethane/silicone rubber/graphite nanocomposite as radio frequency wave absorbing material: The role of interfacial compatibilization

A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of th...

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Published inComposites science and technology Vol. 72; no. 3; pp. 382 - 389
Main Authors Shafieizadegan Esfahani, A.R., Katbab, A.A., Dehkhoda, P., Karami, H.R., Barikani, M., Sadeghi, S.H.H., Ghorbani, A.
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 07.02.2012
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Abstract A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of the GNs dispersion was optimized by the incorporation of a specific type of bifunctional compatibilizer. Insulator to conductive transition threshold as well as electromagnetic wave absorption characteristics of the fabricated nanocomposites was shown to be dependent upon the compatibilizer functionality. All PU/SR/GN nanocomposites generated from bifunctional compatibilizer exhibited higher electrical conductivity with enhanced permittivity implying enhanced formation of conductive networks by GN platelets. Permittivity of the PU/SR/GN nanocomposite based on bifunctional compatibilizer showed to be higher than uncompatibilized counterpart. Electromagnetic reflection loss behavior of the PU/SR/GN nanocomposites exhibited a non-linear correlation with the electrical conductivity. Although all PU/SR/GN prepared nanocomposites exhibited electromagnetic wave reflection loss behavior, but this revealed to be affected by the GN level as well as the size and dispersion state of the graphite nanosheets.
AbstractList A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of the GNs dispersion was optimized by the incorporation of a specific type of bifunctional compatibilizer. Insulator to conductive transition threshold as well as electromagnetic wave absorption characteristics of the fabricated nanocomposites was shown to be dependent upon the compatibilizer functionality. All PU/SR/GN nanocomposites generated from bifunctional compatibilizer exhibited higher electrical conductivity with enhanced permittivity implying enhanced formation of conductive networks by GN platelets. Permittivity of the PU/SR/GN nanocomposite based on bifunctional compatibilizer showed to be higher than uncompatibilized counterpart. Electromagnetic reflection loss behavior of the PU/SR/GN nanocomposites exhibited a non-linear correlation with the electrical conductivity. Although all PU/SR/GN prepared nanocomposites exhibited electromagnetic wave reflection loss behavior, but this revealed to be affected by the GN level as well as the size and dispersion state of the graphite nanosheets.
Author Sadeghi, S.H.H.
Ghorbani, A.
Dehkhoda, P.
Barikani, M.
Karami, H.R.
Katbab, A.A.
Shafieizadegan Esfahani, A.R.
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Issue 3
Keywords B. Electrical properties
A. Functional composites
Nanographite
A. Coupling agents
B. Surface treatment
Electrical conductivity
Polymer blends
Electrical properties
Dielectric properties
Thermoplastic rubber
Experimental study
Cellular plastic
Compatibilizer
Composite material
Surface treatment
Coupling agent
Microwave absorption
Vulcanizate
Preparation
Graphite
Nanocomposite
Plastics
Permittivity
Silicone elastomer
Language English
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Snippet A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane...
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SubjectTerms A. Coupling agents
A. Functional composites
Applied sciences
B. Electrical properties
B. Surface treatment
Cellular
Compatibility
Composites
Exact sciences and technology
Forms of application and semi-finished materials
Graphite
Nanocomposites
Nanographite
Nanomaterials
Nanostructure
Plutonium
Polymer industry, paints, wood
Polyurethane foam
Radio frequencies
Technology of polymers
Title Preparation and characterization of foamed polyurethane/silicone rubber/graphite nanocomposite as radio frequency wave absorbing material: The role of interfacial compatibilization
URI https://dx.doi.org/10.1016/j.compscitech.2011.11.030
https://search.proquest.com/docview/1010897335
https://search.proquest.com/docview/1701033594
Volume 72
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