Preparation and characterization of foamed polyurethane/silicone rubber/graphite nanocomposite as radio frequency wave absorbing material: The role of interfacial compatibilization
A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of th...
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Published in | Composites science and technology Vol. 72; no. 3; pp. 382 - 389 |
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Main Authors | , , , , , , |
Format | Journal Article |
Language | English |
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07.02.2012
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Abstract | A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of the GNs dispersion was optimized by the incorporation of a specific type of bifunctional compatibilizer. Insulator to conductive transition threshold as well as electromagnetic wave absorption characteristics of the fabricated nanocomposites was shown to be dependent upon the compatibilizer functionality. All PU/SR/GN nanocomposites generated from bifunctional compatibilizer exhibited higher electrical conductivity with enhanced permittivity implying enhanced formation of conductive networks by GN platelets. Permittivity of the PU/SR/GN nanocomposite based on bifunctional compatibilizer showed to be higher than uncompatibilized counterpart. Electromagnetic reflection loss behavior of the PU/SR/GN nanocomposites exhibited a non-linear correlation with the electrical conductivity. Although all PU/SR/GN prepared nanocomposites exhibited electromagnetic wave reflection loss behavior, but this revealed to be affected by the GN level as well as the size and dispersion state of the graphite nanosheets. |
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AbstractList | A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane solution of room temperature vulcanizing (RTV) silicone rubber (SR) hybridized with graphite nanosheets (GNs) called doping solution. Extent of the GNs dispersion was optimized by the incorporation of a specific type of bifunctional compatibilizer. Insulator to conductive transition threshold as well as electromagnetic wave absorption characteristics of the fabricated nanocomposites was shown to be dependent upon the compatibilizer functionality. All PU/SR/GN nanocomposites generated from bifunctional compatibilizer exhibited higher electrical conductivity with enhanced permittivity implying enhanced formation of conductive networks by GN platelets. Permittivity of the PU/SR/GN nanocomposite based on bifunctional compatibilizer showed to be higher than uncompatibilized counterpart. Electromagnetic reflection loss behavior of the PU/SR/GN nanocomposites exhibited a non-linear correlation with the electrical conductivity. Although all PU/SR/GN prepared nanocomposites exhibited electromagnetic wave reflection loss behavior, but this revealed to be affected by the GN level as well as the size and dispersion state of the graphite nanosheets. |
Author | Sadeghi, S.H.H. Ghorbani, A. Dehkhoda, P. Barikani, M. Karami, H.R. Katbab, A.A. Shafieizadegan Esfahani, A.R. |
Author_xml | – sequence: 1 givenname: A.R. surname: Shafieizadegan Esfahani fullname: Shafieizadegan Esfahani, A.R. organization: Department of Polymer Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 2 givenname: A.A. surname: Katbab fullname: Katbab, A.A. email: katbab@aut.ac.ir organization: Department of Polymer Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 3 givenname: P. surname: Dehkhoda fullname: Dehkhoda, P. organization: Institute of Telecommunications Technology and Applied Electromagnetics, Amirkabir University of Technology, Tehran, Iran – sequence: 4 givenname: H.R. surname: Karami fullname: Karami, H.R. organization: Department of Electrical Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 5 givenname: M. surname: Barikani fullname: Barikani, M. organization: Department of Polyurethanes & Advanced Materials, Faculty of Polymer Science, Iran Polymer & Petrochemical Institute, Tehran, Iran – sequence: 6 givenname: S.H.H. surname: Sadeghi fullname: Sadeghi, S.H.H. organization: Department of Electrical Engineering, Amirkabir University of Technology, Tehran, Iran – sequence: 7 givenname: A. surname: Ghorbani fullname: Ghorbani, A. organization: Department of Electrical Engineering, Amirkabir University of Technology, Tehran, Iran |
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Keywords | B. Electrical properties A. Functional composites Nanographite A. Coupling agents B. Surface treatment Electrical conductivity Polymer blends Electrical properties Dielectric properties Thermoplastic rubber Experimental study Cellular plastic Compatibilizer Composite material Surface treatment Coupling agent Microwave absorption Vulcanizate Preparation Graphite Nanocomposite Plastics Permittivity Silicone elastomer |
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Snippet | A novel method for the preparation of radio frequency (RF) wave absorber polyurethane foam (PU) has been developed by impregnation of PU foam in n-hexane... |
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SubjectTerms | A. Coupling agents A. Functional composites Applied sciences B. Electrical properties B. Surface treatment Cellular Compatibility Composites Exact sciences and technology Forms of application and semi-finished materials Graphite Nanocomposites Nanographite Nanomaterials Nanostructure Plutonium Polymer industry, paints, wood Polyurethane foam Radio frequencies Technology of polymers |
Title | Preparation and characterization of foamed polyurethane/silicone rubber/graphite nanocomposite as radio frequency wave absorbing material: The role of interfacial compatibilization |
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