Porphyrin-based systems containing polyaromatic fragments: decoupling the synergistic effects in aromatic-porphyrin-fullerene systems

• Published in: RSC advances Vol. 1; no. 59; pp. 36164 - 36173
• Main Authors: Ferrero, Sergio, Barbero, Héctor, Miguel, Daniel, García-Rodríguez, Raúl, Álvarez, Celedonio M
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 01.10.2020; The Royal Society of Chemistry
• Subjects: Binding sites; Buckminsterfullerene; Chemistry; Decoupling; Derivatives; Fragments; Fullerenes; NMR; Nuclear magnetic resonance; Porphyrins

In this work, we report a two-step synthesis that allows the introduction of four pyrene or corannulene fragments at the para position of meso -tetraarylporphyrins using a microwave-assisted quadruple Suzuki-Miyaura reaction. Placing the PAHs at this position, further from the porphyrin core, avoids...