Alloys of the Ti-Si-Sn system (titanium corner): phase equilibria, structure, and mechanical properties
The joint effect of Si (5, 7, and 10 at.%) and Sn (3–15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the (β*) + Ti 5 Si 3 ....
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Published in | Powder metallurgy and metal ceramics Vol. 50; no. 7-8; pp. 452 - 461 |
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Main Authors | , , , , , , , |
Format | Journal Article |
Language | English |
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01.10.2011
Springer Springer Nature B.V |
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Abstract | The joint effect of Si (5, 7, and 10 at.%) and Sn (3–15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the (β*) + Ti
5
Si
3
. eutectic. It is shown that the dependence of strength and hardness of Ti-Si-Sn alloys on Sn content is nonmonotonic. The properties improve with increasing tin content to 7–10 at.% due to the solid-solution hardening mechanism. The elastic modulus and plasticity of all the alloys decrease with increasing Sn content. The elastic modulus for the alloys with 7–15 at.% Sn almost halves, decreasing to 65–60 GPa. The level of long-term hot hardness of the alloys at different temperatures depends on Si and Sn content. In general, tin additions increase heat resistance of all the alloys studied. The deviation from the dependence for individual alloys results from variation in their phase composition. The mechanical behavior of Ti-rich Ti-Si-Sn alloys depending on Sn content is determined by the formation of the intermetallic Ti
3
Sn phase. |
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AbstractList | The joint effect of Si (5, 7, and 10 at.%) and Sn (3-15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the ( beta *)+Ti sub(5)Si sub(3). eutectic. It is shown that the dependence of strength and hardness of Ti-Si-Sn alloys on Sn content is nonmonotonic. The properties improve with increasing tin content to 7-10 at.% due to the solid-solution hardening mechanism. The elastic modulus and plasticity of all the alloys decrease with increasing Sn content. The elastic modulus for the alloys with 7-15 at.% Sn almost halves, decreasing to 65-60 GPa. The level of long-term hot hardness of the alloys at different temperatures depends on Si and Sn content. In general, tin additions increase heat resistance of all the alloys studied. The deviation from the dependence for individual alloys results from variation in their phase composition. The mechanical behavior of Ti-rich Ti-Si-Sn alloys depending on Sn content is determined by the formation of the intermetallic Ti sub(3)Sn phase. The joint effect of Si (5, 7, and 10 at.%) and Sn (3-15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the (β*)+Ti^sub 5^Si^sub 3^. eutectic. It is shown that the dependence of strength and hardness of Ti-Si-Sn alloys on Sn content is nonmonotonic. The properties improve with increasing tin content to 7-10 at.% due to the solid-solution hardening mechanism. The elastic modulus and plasticity of all the alloys decrease with increasing Sn content. The elastic modulus for the alloys with 7-15 at.% Sn almost halves, decreasing to 65-60 GPa. The level of long-term hot hardness of the alloys at different temperatures depends on Si and Sn content. In general, tin additions increase heat resistance of all the alloys studied. The deviation from the dependence for individual alloys results from variation in their phase composition. The mechanical behavior of Ti-rich Ti-Si-Sn alloys depending on Sn content is determined by the formation of the intermetallic Ti^sub 3^Sn phase.[PUBLICATION ABSTRACT] The joint effect of Si (5, 7, and 10 at.%) and Sn (3–15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the (β*) + Ti 5 Si 3 . eutectic. It is shown that the dependence of strength and hardness of Ti-Si-Sn alloys on Sn content is nonmonotonic. The properties improve with increasing tin content to 7–10 at.% due to the solid-solution hardening mechanism. The elastic modulus and plasticity of all the alloys decrease with increasing Sn content. The elastic modulus for the alloys with 7–15 at.% Sn almost halves, decreasing to 65–60 GPa. The level of long-term hot hardness of the alloys at different temperatures depends on Si and Sn content. In general, tin additions increase heat resistance of all the alloys studied. The deviation from the dependence for individual alloys results from variation in their phase composition. The mechanical behavior of Ti-rich Ti-Si-Sn alloys depending on Sn content is determined by the formation of the intermetallic Ti 3 Sn phase. The joint effect of Si (5, 7, and 10 at.%) and Sn (3-15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied. Hypoeutectic alloys with 10 at.% Si are shown to possess the highest level of properties due to a greater volume fraction of the (([[beta].sup.*]) + [Ti.sub.5][Si.sub.3]. eutectic. It is shown that the dependence of strength and hardness of Ti-Si-Sn alloys on Sn content is nonmonotonic. The properties improve with increasing tin content to 7-10 at.% due to the solid-solution hardening mechanism. The elastic modulus and plasticity of all the alloys decrease with increasing Sn content. The elastic modulus for the alloys with 7-15 at.% Sn almost halves, decreasing to 65-60 GPa. The level of long-term hot hardness of the alloys at different temperatures depends on Si and Sn content. In general, tin additions increase heat resistance of all the alloys studied. The deviation from the dependence for individual alloys results from variation in their phase composition. The mechanical behavior of Ti-rich Ti-Si-Sn alloys depending on Sn content is determined by the formation of the intermetallic [Ti.sub.3]Sn phase. Keywords: titanium alloys, doping, silicon, tin, eutectic, [Ti.sub.5][Si.sub.3], [Ti.sub.3]Sn, structure, mechanical properties. |
Audience | Academic |
Author | Bulanova, M. V. Bega, M. D. Firstov, S. O. Valuiska, K. O. Koval’, O. Yu Gorna, I. D. Evich, Ya. I. Kotko, A. V. |
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Cites_doi | 10.1007/1-4020-2112-7_22 10.1016/j.scriptamat.2010.01.036 10.1016/j.jallcom.2011.02.062 10.1016/S0925-8388(02)00971-4 10.1016/j.calphad.2008.08.001 |
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Keywords | silicon eutectic Ti Si doping tin Sn titanium alloys structure mechanical properties |
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References | Vdovychenko, Bulanova, Fartushna (CR10) 2010; 62 Bulanova, Tretyachenko, Meleshevich (CR13) 2003; 350 She, Zhan (CR11) 2011; 528 CR4 Bulanova, Firstov, Kulak, Senkov (CR3) 2004 CR6 CR5 CR8 CR7 CR17 CR9 CR16 Zhan, Yang, Xu (CR14) 2011; 509 Collings (CR19) 1984 Colinet, Tedenak, Fries (CR15) 2009; 33 Zwicker (CR18) 1979 Firstov (CR2) 2005; 17 Bulanova, Soroka, Zheltov (CR12) 1999; 90 Firstov (CR1) 2004 EW Collings (9349_CR19) 1984 SA Firstov (9349_CR2) 2005; 17 Jia She (9349_CR11) 2011; 528 9349_CR7 9349_CR8 9349_CR9 S Firstov (9349_CR1) 2004 9349_CR4 9349_CR5 9349_CR6 M Bulanova (9349_CR13) 2003; 350 9349_CR17 Yongzhong Zhan (9349_CR14) 2011; 509 9349_CR16 W Zwicker (9349_CR18) 1979 M Bulanova (9349_CR12) 1999; 90 M Bulanova (9349_CR3) 2004 OV Vdovychenko (9349_CR10) 2010; 62 C Colinet (9349_CR15) 2009; 33 |
References_xml | – start-page: 217 year: 2004 end-page: 228 ident: CR3 article-title: Multicomponent Ti-Si-based systems publication-title: Metallic Materials with High Structural Efficiency doi: 10.1007/1-4020-2112-7_22 contributor: fullname: Senkov – start-page: 511 year: 1979 ident: CR18 publication-title: [Russian translation] contributor: fullname: Zwicker – volume: 90 start-page: 505 issue: 7 year: 1999 end-page: 507 ident: CR12 article-title: Phase equilibria in the Ti-rich corner of the Ti-Si-Sn system publication-title: Z. Metallkd. contributor: fullname: Zheltov – volume: 17 start-page: 33 year: 2005 end-page: 37 ident: CR2 article-title: Titanium cast irons and titanium steels publication-title: Titan contributor: fullname: Firstov – volume: 62 start-page: 758 year: 2010 end-page: 761 ident: CR10 article-title: Dynamic mechanical behavior of intermetallic Ti Sn publication-title: Scripta Mater. doi: 10.1016/j.scriptamat.2010.01.036 contributor: fullname: Fartushna – ident: CR4 – ident: CR16 – ident: CR17 – volume: 509 start-page: 5269 issue: 17 year: 2011 end-page: 5273 ident: CR14 article-title: Experimental phase diagram of the Ti-Si-Sn ternary system at 473 K publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2011.02.062 contributor: fullname: Xu – ident: CR9 – volume: 528 start-page: 3871 issue: 10–11 year: 2011 end-page: 3875 ident: CR11 article-title: High volume intermetallics reinforced Ti-based composite in situ synthesized from Ti-Si-Sn ternary system publication-title: Mater. Sci. Eng. A contributor: fullname: Zhan – ident: CR6 – ident: CR5 – ident: CR7 – ident: CR8 – volume: 350 start-page: 164 year: 2003 end-page: 173 ident: CR13 article-title: Influence of tin on the structure and properties of as-cast Ti-rich Ti-Si alloys publication-title: J. Alloys Compd. doi: 10.1016/S0925-8388(02)00971-4 contributor: fullname: Meleshevich – volume: 33 start-page: 250 year: 2009 end-page: 259 ident: CR15 article-title: Structural stability of intermetallic phases in the Sn-Ti system publication-title: Calphad doi: 10.1016/j.calphad.2008.08.001 contributor: fullname: Fries – start-page: 217 year: 2004 end-page: 228 ident: CR1 article-title: Main tendencies in elaboration of materials with high specific strength publication-title: Metallic Materials with High Structural Efficiency contributor: fullname: Firstov – year: 1984 ident: CR19 publication-title: The Physical Metallurgy of Titanium Alloys contributor: fullname: Collings – volume: 509 start-page: 5269 issue: 17 year: 2011 ident: 9349_CR14 publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2011.02.062 contributor: fullname: Yongzhong Zhan – ident: 9349_CR6 – ident: 9349_CR5 – ident: 9349_CR7 – ident: 9349_CR8 – ident: 9349_CR9 – volume: 528 start-page: 3871 issue: 10–11 year: 2011 ident: 9349_CR11 publication-title: Mater. Sci. Eng. A contributor: fullname: Jia She – volume: 90 start-page: 505 issue: 7 year: 1999 ident: 9349_CR12 publication-title: Z. Metallkd. contributor: fullname: M Bulanova – volume: 33 start-page: 250 year: 2009 ident: 9349_CR15 publication-title: Calphad doi: 10.1016/j.calphad.2008.08.001 contributor: fullname: C Colinet – ident: 9349_CR4 – volume: 350 start-page: 164 year: 2003 ident: 9349_CR13 publication-title: J. Alloys Compd. doi: 10.1016/S0925-8388(02)00971-4 contributor: fullname: M Bulanova – volume: 17 start-page: 33 year: 2005 ident: 9349_CR2 publication-title: Titan contributor: fullname: SA Firstov – start-page: 511 volume-title: Titanium and Its Alloys [Russian translation] year: 1979 ident: 9349_CR18 contributor: fullname: W Zwicker – start-page: 217 volume-title: Metallic Materials with High Structural Efficiency year: 2004 ident: 9349_CR1 contributor: fullname: S Firstov – start-page: 217 volume-title: Metallic Materials with High Structural Efficiency year: 2004 ident: 9349_CR3 doi: 10.1007/1-4020-2112-7_22 contributor: fullname: M Bulanova – volume: 62 start-page: 758 year: 2010 ident: 9349_CR10 publication-title: Scripta Mater. doi: 10.1016/j.scriptamat.2010.01.036 contributor: fullname: OV Vdovychenko – volume-title: The Physical Metallurgy of Titanium Alloys year: 1984 ident: 9349_CR19 contributor: fullname: EW Collings – ident: 9349_CR17 – ident: 9349_CR16 |
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Snippet | The joint effect of Si (5, 7, and 10 at.%) and Sn (3–15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied.... The joint effect of Si (5, 7, and 10 at.%) and Sn (3-15 at.%) on the structure and mechanical properties of Ti-rich as-cast Ti-Si-Sn alloys is studied.... |
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SubjectTerms | Alloys Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Elastic modulus Glass Hardness Intermetallic compounds Materials Science Mechanical properties Metallic Materials Natural Materials Silicon Specialty metals industry Tin Tin base alloys Titanium Titanium alloys Titanium base alloys |
Title | Alloys of the Ti-Si-Sn system (titanium corner): phase equilibria, structure, and mechanical properties |
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