Chelate Silylene–Silyl Ligand Can Boost Rhodium‐Catalyzed C−H Bond Functionalization Reactions - Mo, Zhenbo; Kostenko, Arseni; Zhou, Yu‐Peng; Yao, Shenglai; Driess, Matthias (Chemistry : a European journal, 2018)
Keywords: agostic complexes; alkenylation; atoms in molecules; Catalysts; Chelates; Chemical reactions; Chemistry; Chemistry, Multidisciplinary; density functional calculations; Ligands; N-heterocyclic silylenes; Physical Sciences; Rhodium; Science & Technology; Substrates; X-ray diffraction; ALKANE COMPLEXES; ACTIVATION; (9,9-DIMETHYLXANTHENE-4,5-DIYL)BIS(DIMETHYLSILYL); AGOSTIC INTERACTIONS; N-heterocyclic silylenes; N-H; RUTHENIUM(II) COMPLEX; CARBON-HYDROGEN BONDS; agostic complexes; MOLECULES; alkenylation; density functional calculations; atoms in molecules; INTERMEDIATE; METAL-COMPLEXES